Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
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Dioxygen Activation at Non-Heme Diiron Centers: Oxidation of a Proximal Residue in the I100W Variant of Toluene/ o -Xylene Monooxygenase Hydroxylase †Reactivity and O2 Formation by Mn(IV)- and Mn(V)-Hydroxo Species Stabilized within a Polyfluoroxometalate FrameworkMn K-edge X-ray absorption studies of oxo- and hydroxo-manganese(IV) complexes: experimental and theoretical insights into pre-edge properties.Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.Probing 'spin-forbidden' oxygen-atom transfer: gas-phase reactions of chromium-porphyrin complexesManganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways.Oxygen-atom transfer reactivity of axially ligated Mn(V)-oxo complexes: evidence for enhanced electrophilic and nucleophilic pathwaysDetection of different oxidation states of individual manganese porphyrins during their reaction with oxygen at a solid/liquid interface.Dramatic influence of an anionic donor on the oxygen-atom transfer reactivity of a Mn(V) -oxo complex.Characterization and reactivity of a terminal nickel(III)-oxygen adductPreparation and properties of a monomeric high-spin Mn(V)-oxo complex.Reflections on Small Molecule Manganese Models that Seek to Mimic Photosynthetic Water Oxidation ChemistryCopper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases.Chemistry of polyvalent iodine.Trans-dioxo manganese(V) porphyrins.Polarized X-ray absorption spectroscopy of single-crystal Mn(V) complexes relevant to the oxygen-evolving complex of photosystem IIHigh-valent iron and manganese complexes of corrole and porphyrin in atom transfer and dioxygen evolving catalysis.Selective functionalisation of saturated C-H bonds with metalloporphyrin catalysts.How does ammonia bind to the oxygen-evolving complex in the S2 state of photosynthetic water oxidation? Theoretical support and implications for the W1 substitution mechanism.Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges.Prediction of high-valent iron K-edge absorption spectra by time-dependent density functional theory.Molecular recognition in Mn-catalyzed C-H oxidation. Reaction mechanism and origin of selectivity from a DFT perspective.Tuning the Reactivity of Terminal Nickel(III)-Oxygen Adducts for C-H Bond Activation.Hydrogen-atom abstraction reactions by manganese(V)- and manganese(IV)-oxo porphyrin complexes in aqueous solution.Remarkable solvent, porphyrin ligand, and substrate effects on participation of multiple active oxidants in manganese(III) porphyrin catalyzed oxidation reactions.Intramolecular C-H and C-F Bond Oxygenation by Site-Differentiated Tetranuclear Manganese Models of the OEC.Selective C-H Halogenations with a Highly Fluorinated Manganese Porphyrin.Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes.The rebound mechanism in catalytic C-H oxidation by MnO(tpp)Cl from DFT studies: electronic nature of the active species.Mononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions.A nonheme manganese(IV)-oxo species generated in photocatalytic reaction using water as an oxygen source.Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins.Spectroscopic capture and reactivity of S = 1/2 nickel(III)-oxygen intermediates in the reaction of a Ni(II)-salt with mCPBA.Theoretical study of the interaction between molecular oxygen and tetraaza macrocyclic manganese complexes.Robust and efficient amide-based nonheme manganese(III) hydrocarbon oxidation catalysts: substrate and solvent effects on involvement and partition of multiple active oxidants.Isolable iodosylarene and iodoxyarene adducts of Co and their O-atom transfer and C-H activation reactivity.Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complex.Selective C−H Halogenation with a Highly Fluorinated Manganese PorphyrinOxidation of Alkanes by Periodate Using a MnVNitrido Complex as Catalyst
P2860
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P2860
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
description
2007 nî lūn-bûn
@nan
2007 թուականի Փետրուարին հրատարակուած գիտական յօդուած
@hyw
2007 թվականի փետրվարին հրատարակված գիտական հոդված
@hy
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
name
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@ast
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@en
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@nl
type
label
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@ast
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@en
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@nl
prefLabel
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@ast
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@en
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@nl
P2093
P2860
P356
P1476
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
@en
P2093
Mi Sook Seo
Min-Jung Kang
Serena Debeer George
Takehiko Tosha
Takehiro Ohta
Teizo Kitagawa
Wonwoo Nam
Woon Ju Song
P2860
P304
P356
10.1021/JA066460V
P407
P577
2007-02-01T00:00:00Z