Experimental and theoretical investigations into the unusual regioselectivity of 4,5-, 5,6-, and 6,7-indole aryne cycloadditions
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CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS-ALDER (HDDA) REACTIONApplication of 6,7-indole aryne cycloaddition and Pd(0)-catalyzed Suzuki-Miyaura and Buchwald-Hartwig cross-coupling reactions for the preparation of annulated indole libraries.Antitumor effects of synthetic 6,7-annulated-4-substituted indole compounds in L1210 leukemic cells in vitro.Total Synthesis of (±)-Cis-Trikentrin B via Intermolecular 6,7-Indole Aryne Cycloaddition and Stille Cross-CouplingRegioselectivity of Diels-Alder Reactions Between 6,7-Dehydrobenzofuran and 2-Substituted FuransMechanism of the reactions of alcohols with o-benzynes.Tactics for Probing Aryne Reactivity: Mechanistic Studies of Silicon-oxygen Bond Cleavage During the Trapping of (HDDA-generated) Benzynes by Silyl Ethers.Indolyne experimental and computational studies: synthetic applications and origins of selectivities of nucleophilic additions.A Practical, Multi-gram Synthesis of (±)-Herbindole A, (±)-Herbindole B, and (±)-Herbindole C from a Common Intermediate via 6,7-Indole Aryne Cycloaddition and Pd(0)-Catalyzed Cross-Coupling Reactions.Mechanisms by which synthetic 6,7-annulated-4-substituted indole compounds with anti-proliferative activity disrupt mitosis and block cytokinesis in human HL-60 tumor cells in vitro.The hexadehydro-Diels-Alder reactionNucleophilic addition to 2,3-pyridyne and synthesis of benzonaphthyridinonesCycloaddition of Arynes and Cyclic Enol Ethers as a Platform for Access to Stereochemically Defined 1,2-Disubstituted BenzocyclobutenesReactions of HDDA-Derived Benzynes with Sulfides: Mechanism, Modes, and Three-Component Reactions.Total synthesis of (-)-N-methylwelwitindolinone C isothiocyanate.Insertion of arynes into N-halo bonds: a direct approach to o-haloaminoarenes.An efficient computational model to predict the synthetic utility of heterocyclic arynes.Overturning indolyne regioselectivities and synthesis of indolactam VThe Phenol-Ene Reaction: Biaryl Synthesis via Trapping Reactions between HDDA-Generated Benzynes and Phenolics.Reactions of hexadehydro-Diels-Alder benzynes with structurally complex multifunctional natural products.Total syntheses of the elusive welwitindolinones with bicyclo[4.3.1] cores.Mechanistic Duality in Tertiary Amine Additions to Thermally Generated Hexadehydro-Diels-Alder Benzynes.A study on an unusual SN2 mechanism in the methylation of benzyne through nickel-complexation.Hexadehydro-Diels-Alder (HDDA)-Enabled Carbazolyne Chemistry: Single Step, de Novo Construction of the Pyranocarbazole Core of Alkaloids of the Murraya koenigii (Curry Tree) Family.Reactions of Hexadehydro-Diels-Alder (HDDA)-Derived Benzynes with Thioamides: Synthesis of Dihydrobenzothiazino-Heterocyclics.Computational organic chemistry
P2860
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P2860
Experimental and theoretical investigations into the unusual regioselectivity of 4,5-, 5,6-, and 6,7-indole aryne cycloadditions
description
2010 nî lūn-bûn
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2010 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2010 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
name
Experimental and theoretical i ...... ,7-indole aryne cycloadditions
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Experimental and theoretical i ...... ,7-indole aryne cycloadditions
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Experimental and theoretical i ...... ,7-indole aryne cycloadditions
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label
Experimental and theoretical i ...... ,7-indole aryne cycloadditions
@ast
Experimental and theoretical i ...... ,7-indole aryne cycloadditions
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Experimental and theoretical i ...... ,7-indole aryne cycloadditions
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prefLabel
Experimental and theoretical i ...... ,7-indole aryne cycloadditions
@ast
Experimental and theoretical i ...... ,7-indole aryne cycloadditions
@en
Experimental and theoretical i ...... ,7-indole aryne cycloadditions
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P2093
P2860
P356
P1433
P1476
Experimental and theoretical i ...... ,7-indole aryne cycloadditions
@en
P2093
Ashley N Garr
Diheng Luo
Keith R Buszek
Neil Brown
P2860
P356
10.1021/OL902415S
P407
P577
2010-01-01T00:00:00Z