Characterization of a rhodium(I) sigma-methane complex in solution. - Wikidata - wikimedia - TriplyDB

Characterization of a rhodium(I) sigma-methane complex in solution.

Characterization of a rhodium(I) sigma-methane complex in solution.

http://www.wikidata.org/entity/Q35012017

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A Rhodium-Pentane Sigma-Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds Facile C-H bond cleavage via a proton-coupled electron transfer involving a C-H...Cu(II) interaction.Synthesis and Characterization of Iron Complexes based on Bis-Phosphinite PONOP and Bis-Phosphite PONOP Pincer Ligands.High-pressure-low-temperature cryostat designed for use with fourier transform infrared spectrometers and time-resolved infrared spectroscopy.Intramolecular C-C agostic complexes: C-C sigma interactions by another name.C-H bond activation by f-block complexes.Methyl Complexes of the Transition Metals.Ligand K-edge XAS, DFT, and TDDFT analysis of pincer linker variations in Rh(i) PNP complexes: reactivity insights from electronic structure.Detection of σ-alkane complexes of manganese by NMR and IR spectroscopy in solution: (η5-C5H5)Mn(CO)2(ethane) and (η5-C5H5)Mn(CO)2(isopentane)Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates.Potassium-alkane interactions within a rigid hydrophobic pocket.Solvent promoted reversible cyclometalation in a tethered NHC iridium complex.Stepwise degradation of trifluoromethyl platinum(II) compounds.A combined experimental and computational study of fluxional processes in sigma amine-borane complexes of rhodium and iridium.Improved light olefin yield from methyl bromide coupling over modified SAPO-34 molecular sieves.A systematic study on Pt based, subnanometer-sized alloy cluster catalysts for alkane dehydrogenation: effects of intermetallic interaction.Structural snapshots of concerted double E-H bond activation at a transition metal centre.Reactivity of Silanes with (tBu PONOP)Ruthenium Dichloride: Facile Synthesis of Chloro-Silyl Ruthenium Compounds and Formic Acid Decomposition.Methyl-, Ethenyl-, and Ethynyl-Bridged Cationic Digold Complexes Stabilized by Coordination to a Bulky Terphenylphosphine Ligand.Synthesis, structure and dynamics of NHC-based palladium macrocycles.Expanded-ring N-heterocyclic carbenes for the stabilization of highly electrophilic gold(I) cations.Contrasting electronic requirements for C-H binding and C-H activation in d(6) half-sandwich complexes of rhenium and tungsten.A Cobalt(I) Pincer Complex with an η(2) -C(aryl)-H Agostic Bond: Facile C-H Bond Cleavage through Deprotonation, Radical Abstraction, and Oxidative Addition.A Cationic Unsaturated Platinum(II) Complex that Promotes the Tautomerization of Acetylene to Vinylidene.Mechanistic Aspects of Aryl-Halide Oxidative Addition, Coordination Chemistry, and Ring-Walking by Palladium.Methane as raw material in synthetic chemistry: the final frontier.C-H and H-H bond activation via ligand dearomatization/rearomatization of a PN³P-rhodium(I) complex.Relativistic DFT calculations of the NMR properties and reactivity of transition metal methane σ-complexes: insights on C-H bond activation.Rhodium and iridium aminoborane complexes: coordination chemistry of BN alkene analogues.New Routes to a Series of σ-Borane/Borate Complexes of Molybdenum and Ruthenium.The Mo-Mo Quintuple Bond as a Ligand to Stabilize Transition-Metal Complexes.Cleavage of unreactive bonds with pincer metal complexes Organische Chemie 2009 A Cobalt(I) Pincer Complex with an η2 -Caryl −H Agostic Bond: Facile C−H Bond Cleavage through Deprotonation, Radical Abstraction, and Oxidative Addition

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P2860

Characterization of a rhodium(I) sigma-methane complex in solution.

http://www.wikidata.org/entity/Q35012017

description

2009 nî lūn-bûn

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2009 թուականի Հոկտեմբերին հրատարակուած գիտական յօդուած

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2009 թվականի հոտեմբերին հրատարակված գիտական հոդված

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2009年の論文

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2009年論文

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2009年論文

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2009年論文

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2009年論文

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2009年論文

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2009年论文

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Characterization of a rhodium(I) sigma-methane complex in solution.

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Characterization of a rhodium(I) sigma-methane complex in solution.

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Characterization of a rhodium(I) sigma-methane complex in solution.

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Characterization of a rhodium(I) sigma-methane complex in solution.

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Characterization of a rhodium(I) sigma-methane complex in solution.

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Characterization of a rhodium(I) sigma-methane complex in solution.

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Characterization of a rhodium(I) sigma-methane complex in solution.

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Cynthia K Schauer

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Karen I Goldberg

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Maurice Brookhart

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Wesley H Bernskoetter

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P2860

Agostic interactions in transition metal compounds

Understanding and exploiting C-H bond activation.

A delicate balance of complexation vs. activation of alkanes interacting with [Re(Cp)(CO)(PF3)] studied with NMR and time-resolved IR spectroscopy.

Theoretical study of the rhenium-alkane interaction in transition metal-alkane sigma-complexes

Time-resolved infrared (TRIR) study on the formation and reactivity of organometallic methane and ethane complexes in room temperature solution

Reductive elimination/oxidative addition of carbon-hydrogen bonds at Pt(IV)/Pt(II) centers: mechanistic studies of the solution thermolyses of Tp(Me2)Pt(CH3)2H.

Investigations of iridium-mediated reversible C-H bond cleavage: characterization of a 16-electron iridium(III) methyl hydride complex.

Evidence for alkane coordination to an electron-rich uranium center.

Photochemistry of the Group 6 hexacarbonyls in low-temperature matrices. III. Interaction of the pentacarbonyls with noble gases and other matrices

A Rhenium–Cyclohexane Complex with Preferential Binding of Axial CH Bonds: A Probe into the Relative Ability of CH, CD, and CC Bonds as Hyperconjugative Electron Donors?

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