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Transition metal-catalyzed decarboxylative allylation and benzylation reactions

Transition metal-catalyzed decarboxylative allylation and benzylation reactions

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Decarboxylative fluorination strategies for accessing medicinally- relevant products The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis Palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions with aryl chlorides Rapid synthesis of polyprenylated acylphloroglucinol analogs via dearomative conjunctive allylic annulation Decarboxylative allylation of amino alkanoic acids and esters via dual catalysis.Synthesis of diarylmethylamines via palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions.Evolution of a unified, stereodivergent approach to the synthesis of communesin F and perophoramidine.Deacylative allylation: allylic alkylation via retro-Claisen activation.Copper-catalyzed regioselective synthesis of furan via tandem cycloaddition of ketone with an unsaturated carboxylic acid under air.Nickel-catalyzed decarboxylative cross-coupling of perfluorobenzoates with aryl halides and sulfonates Palladium-catalyzed C3-benzylation of indoles Nickel-Catalyzed Decarboxylative Arylation of Azoles with Perfluoro- and Nitrobenzoates.Palladium-catalyzed α-arylation of aryl acetic acid derivatives via dienolate intermediates with aryl chlorides and bromides.Intercepted Decarboxylative Allylations of Nitroalkanoates.Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones.Palladium-catalyzed substitution of (coumarinyl)methyl acetates with C-, N-, and S-nucleophiles Palladium(II)-catalyzed enantio- and diastereoselective synthesis of pyrrolidine derivatives Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent Mechanisms Installing amino acids and peptides on N-heterocycles under visible-light assistance.Tandem Rh-catalysis: decarboxylative β-keto acid and alkyne cross-coupling.Palladium Catalysis Enables Benzylation of α,α-Difluoroketone Enolates Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketones Development of asymmetric deacylative allylation.Palladium-catalyzed C(sp(3))-H Arylation of N-Boc benzylalkylamines via a deprotonative cross-coupling process.Phosphino-carboxamides: the inconspicuous gems.The cross-dehydrogenative coupling of C(sp3)-H bonds: a versatile strategy for C-C bond formations.Structure and reactivity of late transition metal η³-benzyl complexes.Our Odyssey with Functionalized Chiral Phosphines: From Optical Resolution to Asymmetric Synthesis to Catalysis.Transition metal-free decarboxylative alkylation reactions.Transition metal catalysis-a unique road map in the stereoselective synthesis of 1,3-polyols.Chalcone: A Privileged Structure in Medicinal Chemistry.Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams.A unified approach to the daucane and sphenolobane bicyclo[5.3.0]decane core: enantioselective total syntheses of daucene, daucenal, epoxydaucenal B, and 14-para-anisoyloxydauc-4,8-diene.Decarboxylative palladium(II)-catalyzed synthesis of aryl amidines from aryl carboxylic acids: development and mechanistic investigation.Biosynthetically inspired divergent approach to monoterpene indole alkaloids: total synthesis of mersicarpine, leuconodines B and D, leuconoxine, melodinine E, leuconolam, and rhazinilam.The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation.Ligand-controlled regiodivergent palladium-catalyzed decarboxylative allylation reaction to access α,α-difluoroketones.Palladium-catalyzed asymmetric construction of vicinal all-carbon quaternary stereocenters and its application to the synthesis of cyclotryptamine alkaloids.Fragment Couplings via CO2 Extrusion-Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox.Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation: formal synthesis of aspergillide A.

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P2860

Transition metal-catalyzed decarboxylative allylation and benzylation reactions

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2011 թուականի Յունուարին հրատարակուած գիտական յօդուած

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2011年の論文

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2011年論文

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2011年论文

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Transition metal-catalyzed decarboxylative allylation and benzylation reactions

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Transition metal-catalyzed decarboxylative allylation and benzylation reactions

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Transition metal-catalyzed decarboxylative allylation and benzylation reactions

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Transition metal-catalyzed decarboxylative allylation and benzylation reactions

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Transition metal-catalyzed decarboxylative allylation and benzylation reactions

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Chemical Reviews

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Transition metal-catalyzed decarboxylative allylation and benzylation reactions

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P2093

Alexander J Grenning

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Antonio Recio

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Jimmie D Weaver

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Jon A Tunge

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P2860

Aryl-aryl bond formation one century after the discovery of the Ullmann reaction

Alkyne elementometalation-Pd-catalyzed cross-coupling. Toward synthesis of all conceivable types of acyclic alkenes in high yields, efficiently, selectively, economically, and safely: "green" way

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

C-C bond-forming reactions via Pd-mediated decarboxylative alpha-imino anion generation.

One-pot tandem decarboxylative allylation-Heck cyclization of allyl diphenylglycinate imines: rapid access to polyfunctionalized 1-aminoindanes.

Tandem C-C bond-forming processes: interception of the pd-catalyzed decarboxylative allylation of allyl diphenylglycinate imines with activated olefins.

Palladium-catalyzed decarboxylative benzylation of diphenylglycinate imines.

Palladium-catalyzed cross-coupling reactions in total synthesis.

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.

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1846-1913

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scholarly article

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10.1021/CR1002744

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3

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111

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21235271

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3116714

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