Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights.
about
A Designed Functional Metalloenzyme that Reduces O2 to H2O with Over One Thousand TurnoversHydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel CellNitric oxide generation from heme/copper assembly mediated nitrite reductase activityReactions of a heme-superoxo complex toward a cuprous chelate and •NO(g): CcO and NOD chemistryElectron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water.Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexesLewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflateElectrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a "Bridging Peroxo" Intermediate Involved in Facile 4e(-)/4H(+) O2-Reduction.Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid.Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complexDirect observation of intermediates formed during steady-state electrocatalytic O2 reduction by iron porphyrins.Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group.New heme-dioxygen and carbon monoxide adducts using pyridyl or imidazolyl tailed porphyrins.Direct EPR observation of a tyrosyl radical in a functional oxidase model in myoglobin during both H2O2 and O2 reactions.Cytochrome c oxidase: Intermediates of the catalytic cycle and their energy-coupled interconversion.Mechanisms of metal ion-coupled electron transfer.Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization.Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry.A High-Valent Non-Heme μ-Oxo Manganese(IV) Dimer Generated from a Thiolate-Bound Manganese(II) Complex and Dioxygen.Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins.Pacman Compounds: From Energy Transfer to Cooperative Catalysis.From Enzymes to Functional Materials-Towards Activation of Small Molecules.A water-soluble supramolecular complex that mimics the heme/copper hetero-binuclear site of cytochrome c oxidase.Proton-Coupled Electron Transfer Reactions Catalysed by 3 d Metal Complexes
P2860
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P2860
Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights.
description
2011 nî lūn-bûn
@nan
2011 թուականի Օգոստոսին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի օգոստոսին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Homogeneous catalytic O2 reduc ...... ates and mechanistic insights.
@ast
Homogeneous catalytic O2 reduc ...... ates and mechanistic insights.
@en
type
label
Homogeneous catalytic O2 reduc ...... ates and mechanistic insights.
@ast
Homogeneous catalytic O2 reduc ...... ates and mechanistic insights.
@en
prefLabel
Homogeneous catalytic O2 reduc ...... ates and mechanistic insights.
@ast
Homogeneous catalytic O2 reduc ...... ates and mechanistic insights.
@en
P2093
P2860
P356
P1476
Homogeneous catalytic O2 reduc ...... ates and mechanistic insights.
@en
P2093
Kenneth D Karlin
Zakaria Halime
P2860
P304
13990-13994
P356
10.1073/PNAS.1104698108
P407
P577
2011-08-01T00:00:00Z