Electrocatalytic mechanism of reversible hydrogen cycling by enzymes and distinctions between the major classes of hydrogenases.
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Electrochemical insights into the mechanism of NiFe membrane-bound hydrogenasesInvestigations of the efficient electrocatalytic interconversions of carbon dioxide and carbon monoxide by nickel-containing carbon monoxide dehydrogenasesMechanism of hydrogen activation by [NiFe] hydrogenasesStructure, function, and mechanism of the nickel metalloenzymes, CO dehydrogenase, and acetyl-CoA synthaseThe influence of oxygen on [NiFe]-hydrogenase cofactor biosynthesis and how ligation of carbon monoxide precedes cyanationLyophilization protects [FeFe]-hydrogenases against O2-induced H-cluster degradation.ElectrochemistryProbing biological redox chemistry with large amplitude Fourier transformed ac voltammetry.How the oxygen tolerance of a [NiFe]-hydrogenase depends on quaternary structure.Frequency and potential dependence of reversible electrocatalytic hydrogen interconversion by [FeFe]-hydrogenases.The Physiological Functions and Structural Determinants of Catalytic Bias in the [FeFe]-Hydrogenases CpI and CpII of Clostridium pasteurianum Strain W5Accumulating the hydride state in the catalytic cycle of [FeFe]-hydrogenases.Re-engineering a NiFe hydrogenase to increase the H2 production bias while maintaining native levels of O2 tolerance.Discovery of Dark pH-Dependent H(+) Migration in a [NiFe]-Hydrogenase and Its Mechanistic Relevance: Mobilizing the Hydrido Ligand of the Ni-C IntermediateRetuning the Catalytic Bias and Overpotential of a [NiFe]-Hydrogenase via a Single Amino Acid Exchange at the Electron Entry/Exit Site.ArcA and AppY antagonize IscR repression of hydrogenase-1 expression under anaerobic conditions, revealing a novel mode of O2 regulation of gene expression in Escherichia coli.Vibrational spectroscopy reveals the initial steps of biological hydrogen evolution.How light-harvesting semiconductors can alter the bias of reversible electrocatalysts in favor of H2 production and CO2 reduction.Theoretical insights into [NiFe]-hydrogenases oxidation resulting in a slowly reactivating inactive state.Protein Electrochemistry: Questions and Answers.Chalcogenide substitution in the [2Fe] cluster of [FeFe]-hydrogenases conserves high enzymatic activity.Carbon-Nanotube-Supported Bio-Inspired Nickel Catalyst and Its Integration in Hybrid Hydrogen/Air Fuel Cells.The mechanism of inhibition by H2 of H2-evolution by hydrogenases.Fully Oriented Bilirubin Oxidase on Porphyrin-Functionalized Carbon Nanotube Electrodes for Electrocatalytic Oxygen Reduction.The structure of hydrogenase-2 from Escherichia coli: implications for H2-driven proton pumping.Methodologies for wiring redox proteins/enzymes to electrode surfaces.Isotopic fractionation associated with [NiFe]- and [FeFe]-hydrogenases.A unified model for surface electrocatalysis based on observations with enzymes.Comparison of carbon materials as electrodes for enzyme electrocatalysis: hydrogenase as a case study.Influence of the [4Fe-4S] cluster coordinating cysteines on active site maturation and catalytic properties of C. reinhardtii [FeFe]-hydrogenase.Crystallographic and spectroscopic assignment of the proton transfer pathway in [FeFe]-hydrogenasesComprehensive Study of the Enzymatic Catalysis of the Electrochemical Oxygen Reduction Reaction (ORR) by Immobilized Copper Efflux Oxidase (CueO) From
P2860
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P2860
Electrocatalytic mechanism of reversible hydrogen cycling by enzymes and distinctions between the major classes of hydrogenases.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
Electrocatalytic mechanism of ...... major classes of hydrogenases.
@ast
Electrocatalytic mechanism of ...... major classes of hydrogenases.
@en
type
label
Electrocatalytic mechanism of ...... major classes of hydrogenases.
@ast
Electrocatalytic mechanism of ...... major classes of hydrogenases.
@en
prefLabel
Electrocatalytic mechanism of ...... major classes of hydrogenases.
@ast
Electrocatalytic mechanism of ...... major classes of hydrogenases.
@en
P2093
P2860
P356
P1476
Electrocatalytic mechanism of ...... major classes of hydrogenases.
@en
P2093
Felix Grey
Fraser A Armstrong
Suzannah V Hexter
Thomas Happe
Victor Climent
P2860
P304
11516-11521
P356
10.1073/PNAS.1204770109
P407
P577
2012-07-16T00:00:00Z