Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.
about
Powerful Bispyridinylidene Organic Reducing Agents with Iminophosphorano π-Donor Substituents.Straightforward and Controlled Shape Access to Efficient Macrocyclic Imidazolylboronium Anion Receptors.Hydrogenations at room temperature and atmospheric pressure with mesoionic carbene-stabilized borenium catalysts.Formation of N-heterocyclic, donor-stabilized borenium ions.Cationic 1,2-Azaborine Adducts of Trimethylphosphine, Triphenylphosphine oxide, and Pyridine-N-oxide.Borenium ion catalyzed hydroboration of alkenes with N-heterocyclic carbene-boranesThermal Dehydrogenation of Base-Stabilized B2H5(+) Complexes and Its Role in C-H BorylationFacile Arylation of Four-Coordinate Boron Halides by Borenium Cation Mediated Boro-desilylation and -destannylation.Electrophilic Activation of Lewis Base Complexes of Borane with Trityl Tetrakis(pentafluorophenyl)borate.Electrophilic C-H Borylation and Related Reactions of B-H Boron CationsLewis Base Activation of Lewis Acids - Group 13. In Situ Generation and Reaction of Borenium Ions.Superelectrophilic intermediates in nitrogen-directed aromatic borylation.Frustrated Lewis pair chemistry: development and perspectives.Reactive p-block cations stabilized by weakly coordinating anions.Synthetic and structural studies of phosphine coordinated boronium salts.Versatile coordination of a reactive P,N-ligand toward boron, aluminum and gallium and interconversion reactivity.Boron-mediated sequential alkyne insertion and C-C coupling reactions affording extended π-conjugated molecules.Lewis Acidic Ionic LiquidsThe Simplest Amino-borane H2 B=NH2 Trapped on a Rhodium Dimer: Pre-Catalysts for Amine-Borane Dehydropolymerization.A boronium ion with exceptional electrophilicityCationic tricoordinate boron intermediates: borenium chemistry from the organic perspective.Using Ylide Functionalization to Stabilize Boron Cations.Haloboration of internal alkynes with boronium and borenium cations as a route to tetrasubstituted alkenes.Weakly stabilized primary borenium cations and their dicationic dimersOxoboryl complexes: boron-oxygen triple bonds stabilized in the coordination sphere of platinum.Synthesis of cyclic amine boranes through triazole-gold(I)-catalyzed alkyne hydroboration.Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines.A di-substituted boron dication and its hydride-induced transformation to an NHC-stabilized borabenzene.Post-Synthesis Amine Borane Functionalization of a Metal-Organic Framework and Its Unusual Chemical Hydrogen Release Phenomenon.Diverse reactivity of borenium cations with >N-H compounds.Fine-Tuning of Lewis Acidity: The Case of Borenium Hydride Complexes Derived from Bis(phosphinimino)amide Boron Precursors.Carbene-induced synthesis of the first borironium cations using the [(η(5)-C5Me5)Fe(CO)2](-) anion as an unlikely leaving group.Reactivity of a dihydroboron species: synthesis of a hydroborenium complex and an expedient entry into stable thioxo- and selenoxo-boranes.Activation of Strong Boron-Fluorine and Silicon-Fluorine σ-Bonds: Theoretical Understanding and Prediction.The hydride-ion affinity of borenium cations and their propensity to activate H2 in frustrated Lewis pairs.Generation of aminoborane monomers RR'N=BH2 from amine-boronium cations [RR'NH-BH2L](+): metal catalyst-free formation of polyaminoboranes at ambient temperature.Metal-free reduction of CO2 with hydroboranes: two efficient pathways at play for the reduction of CO2 to methanol.Crystalline Neutral Allenic Diborene.Catalytic Friedel-Crafts C-H Borylation of Electron-Rich Arenes: Dramatic Rate Acceleration by Added Alkenes.Metal-Free Arene and Heteroarene Borylation Catalyzed by Strongly Electrophilic Bis-boranes.
P2860
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P2860
Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.
description
2005 nî lūn-bûn
@nan
2005年の論文
@ja
2005年論文
@yue
2005年論文
@zh-hant
2005年論文
@zh-hk
2005年論文
@zh-mo
2005年論文
@zh-tw
2005年论文
@wuu
2005年论文
@zh
2005年论文
@zh-cn
name
Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.
@ast
Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.
@en
type
label
Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.
@ast
Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.
@en
prefLabel
Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.
@ast
Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.
@en
P2093
P356
P1476
Borinium, borenium, and boronium ions: synthesis, reactivity, and applications.
@en
P2093
Korey D Conroy
Sara C Bourke
Warren E Piers
P304
P356
10.1002/ANIE.200500402
P407
P577
2005-08-01T00:00:00Z