Protonation of a peroxodiiron(III) complex and conversion to a diiron(III/IV) intermediate: implications for proton-assisted O-O bond cleavage in nonheme diiron enzymes.
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Conversion of Aldehyde to Alkane by a Peroxoiron(III) Complex: A Functional Model for the Cyanobacterial Aldehyde-Deformylating OxygenaseA 2.8 Å Fe-Fe separation in the Fe2(III/IV) intermediate, X, from Escherichia coli ribonucleotide reductaseEvidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation.Spectroscopic and theoretical investigation of a complex with an [O═Fe(IV)-O-Fe(IV)═O] core related to methane monooxygenase intermediate Q.X-ray absorption spectroscopic characterization of the diferric-peroxo intermediate of human deoxyhypusine hydroxylase in the presence of its substrate eIF5aAn Iron(II)(1,3-bis(2'-pyridylimino)isoindoline) Complex as a Catalyst for Substrate Oxidation with H2O2. Evidence for a Transient Peroxodiiron(III) Species.An unusual peroxo intermediate of the arylamine oxygenase of the chloramphenicol biosynthetic pathway.New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex.Interplay of Electronic Cooperativity and Exchange Coupling in Regulating the Reactivity of Diiron(IV)-oxo Complexes towards C-H and O-H Bond Activation.Functional models of nonheme diiron enzymes: kinetic and computational evidence for the formation of oxoiron(iv) species from peroxo-diiron(iii) complexes, and their reactivity towards phenols and H2O2.New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands.Redox and acid-base properties of asymmetric non-heme (hydr)oxo-bridged diiron complexes.Catalysis and molecular magnetism of dinuclear iron(III) complexes with N-(2-pyridylmethyl)-iminodiethanol/-ate.Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands.Unprecedented (μ-1,1-Peroxo)diferric Structure for the Ambiphilic Orange Peroxo Intermediate of the Nonheme N-Oxygenase CmlI.Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes.Hydrogen-Atom Transfer Oxidation with H2O2 Catalyzed by [FeII(1,2-bis(2,2'-bipyridyl-6-yl)ethane(H2O)2]2+: Likely Involvement of a (μ-Hydroxo)(μ-1,2-peroxo)diiron(III) Intermediate.Diiron monooxygenases in natural product biosynthesis.
P2860
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P2860
Protonation of a peroxodiiron(III) complex and conversion to a diiron(III/IV) intermediate: implications for proton-assisted O-O bond cleavage in nonheme diiron enzymes.
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2012 nî lūn-bûn
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2012年の論文
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name
Protonation of a peroxodiiron( ...... age in nonheme diiron enzymes.
@ast
Protonation of a peroxodiiron( ...... age in nonheme diiron enzymes.
@en
type
label
Protonation of a peroxodiiron( ...... age in nonheme diiron enzymes.
@ast
Protonation of a peroxodiiron( ...... age in nonheme diiron enzymes.
@en
prefLabel
Protonation of a peroxodiiron( ...... age in nonheme diiron enzymes.
@ast
Protonation of a peroxodiiron( ...... age in nonheme diiron enzymes.
@en
P2093
P2860
P356
P1433
P1476
Protonation of a peroxodiiron( ...... age in nonheme diiron enzymes.
@en
P2093
Audria Stubna
Eckard Münck
Jószef Kaizer
Katlyn K Meier
Lawrence Que
Mark P Mehn
Matthew A Cranswick
Xiaopeng Shan
P2860
P304
10417-10426
P356
10.1021/IC301642W
P407
P577
2012-09-12T00:00:00Z