Comparison of high-spin and low-spin nonheme Fe(III)-OOH complexes in O-O bond homolysis and H-atom abstraction reactivities
about
Spectroscopic characterization and reactivity studies of a mononuclear nonheme Mn(III)-hydroperoxo complex.Differences and comparisons of the properties and reactivities of iron(III)-hydroperoxo complexes with saturated coordination sphereSc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate.Geometric and electronic structure contributions to function in non-heme iron enzymes.Synthesis, characterization, and reactivity of cobalt(III)-oxygen complexes bearing a macrocyclic N-tetramethylated cyclam ligand.Reactivity of a Cobalt(III)-Hydroperoxo Complex in Electrophilic Reactions.Mono- and binuclear non-heme iron chemistry from a theoretical perspective.Nuclear Resonance Vibrational Spectroscopic Definition of Peroxy Intermediates in Nonheme Iron Sites.Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O2 at Fe(ii) centers.Rate-Determining Attack on Substrate Precedes Rieske Cluster Oxidation during Cis-Dihydroxylation by Benzoate DioxygenaseMechanism and Catalytic Diversity of Rieske Non-Heme Iron-Dependent Oxygenases.Dioxygen Activation and O-O Bond Formation Reactions by Manganese Corroles.Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds.Fine Control of the Redox Reactivity of a Nonheme Iron(III)-Peroxo Complex by Binding Redox-Inactive Metal Ions.A structural and functional model for the 1-aminocyclopropane-1-carboxylic acid oxidase.Structural characterization of a hydroperoxo nickel complex and its autoxidation: mechanism of interconversion between peroxo, superoxo, and hydroperoxo species.Non-heme iron hydroperoxo species in superoxide reductase as a catalyst for oxidation reactions.Demonstration of the heterolytic O-O bond cleavage of putative nonheme iron(II)-OOH(R) complexes for Fenton and enzymatic reactions.A DFT and ONIOM study of C-H hydroxylation catalyzed by nitrobenzene 1,2-dioxygenase.ortho-Hydroxylation of aromatic acids by a non-heme Fe(V)=O species: how important is the ligand design?Peroxide Activation for Electrophilic Reactivity by the Binuclear Non-heme Iron Enzyme AurF.Spin-State-Controlled Photodissociation of Iron(III) Azide to an Iron(V) Nitride Complex.A mononuclear manganese(iii)-hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions.A structurally-characterized peroxomanganese(iv) porphyrin from reversible O2 binding within a metal-organic framework.Insights into the mechanism of the reaction between tetrachloro-p-benzoquinone and hydrogen peroxide and their implications in the catalytic role of water molecules in producing the hydroxyl radial.NRVS Studies of the Peroxide Shunt Intermediate in a Rieske Dioxygenase and Its Relation to the Native FeII O2 Reaction.
P2860
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P2860
Comparison of high-spin and low-spin nonheme Fe(III)-OOH complexes in O-O bond homolysis and H-atom abstraction reactivities
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年論文
@yue
2013年論文
@zh-hant
2013年論文
@zh-hk
2013年論文
@zh-mo
2013年論文
@zh-tw
2013年论文
@wuu
2013年论文
@zh
2013年论文
@zh-cn
name
Comparison of high-spin and lo ...... -atom abstraction reactivities
@ast
Comparison of high-spin and lo ...... -atom abstraction reactivities
@en
type
label
Comparison of high-spin and lo ...... -atom abstraction reactivities
@ast
Comparison of high-spin and lo ...... -atom abstraction reactivities
@en
prefLabel
Comparison of high-spin and lo ...... -atom abstraction reactivities
@ast
Comparison of high-spin and lo ...... -atom abstraction reactivities
@en
P2093
P2860
P356
P1476
Comparison of high-spin and lo ...... -atom abstraction reactivities
@en
P2093
Edward I Solomon
Jaeheung Cho
P2860
P304
P356
10.1021/JA400183G
P407
P577
2013-02-14T00:00:00Z