about
Enzyme immunoassays as screening tools for catalysts and reaction discovery.Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols.PREPARATION OF ISOPROPYL 2-DIAZOACETYL(PHENYL)CARBAMATEScope and mechanistic analysis of the enantioselective synthesis of allenes by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and propargylic alcohols.Copper-catalyzed asymmetric [4+1] cycloadditions of enones with diazo compounds to form dihydrofurans.Lewis acid catalyzed indole synthesis via intramolecular nucleophilic attack of phenyldiazoacetates to iminium ions.To protonate or alkylate? Stereoselective Brønsted acid catalysis of C-C bond formation using diazoalkanes.Stereoselective 1,3-insertions of rhodium(II) azavinyl carbenesCatalytic X-H insertion reactions based on carbenoids.Vinylogous aldol products from chiral crotylsilanes obtained by enantioselective Rh(II) and Cu(I) carbenoid Si-H insertionGold-catalyzed oxidative couplings of two indoles with one aryldiazo cyanide under oxidant-free conditions.Palladium-catalyzed α-arylation of zinc enolates of esters: reaction conditions and substrate scope.An efficient palladium-catalyzed C-H alkoxylation of unactivated methylene and methyl groups with cyclic hypervalent iodine (i(3+) ) oxidants.Enantioselective C-H Olefination of α-Hydroxy and α-Amino Phenylacetic Acids by Kinetic Resolution.Enantioselective intramolecular C-H insertion reactions of donor-donor metal carbenoids.Chemoselective carbophilic addition of α-diazoesters through ligand-controlled gold catalysis.Enantioselective copper-catalyzed intramolecular phenolic O-H bond insertion: synthesis of chiral 2-carboxy dihydrobenzofurans, dihydrobenzopyrans, and tetrahydrobenzooxepines.Synthesis of new copper(I) complexes with tris(2-pyridyl) ligands. Applications to carbene and nitrene transfer reactions.Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C-H bond insertion cascades.Copper-Carbene Intermediates in the Copper-Catalyzed Functionalization of O-H Bonds.Gold-catalyzed highly regio- and enantioselective vinylcarbene insertion into O-H bonds of 2-pyridones.(C6 F5 )3 B Catalyzed Chemoselective and ortho-Selective Substitution of Phenols with α-Aryl α-Diazoesters.Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper(I) complexes of binol derivatives.Enantioselective Intramolecular C-H Insertion of Donor and Donor/Donor Carbenes by a Nondiazo Approach.A Cu-catalyzed four-component cascade reaction to construct β-ester-γ-amino ketones.Enantioselective palladium-catalyzed C-H functionalization of indoles using an axially chiral 2,2'-bipyridine ligand.Cu-based carbene involved in a radical process: a new crossover reaction to construct γ-peroxy esters and 1,4-dicarbonyl compounds.Catalytic Enantioselective Protonation/Nucleophilic Addition of Diazoesters with Chiral Oxazaborolidinium Ion Activated Carboxylic Acids.Enantioselective N-H insertion reaction of α-aryl α-diazoketones: an efficient route to chiral α-aminoketones.Enantioselective palladium-catalyzed insertion of α-aryl-α-diazoacetates into the O-H bonds of phenols.Origins of unique gold-catalysed chemo- and site-selective C–H functionalization of phenols with diazo compounds† †Electronic supplementary information (ESI) available: Data for new compounds, experimental procedures and theoretical studies on mecha
P2860
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P2860
description
2006 nî lūn-bûn
@nan
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
2006年论文
@zh
2006年论文
@zh-cn
name
Catalytic enantioselective O-H insertion reactions.
@en
type
label
Catalytic enantioselective O-H insertion reactions.
@en
prefLabel
Catalytic enantioselective O-H insertion reactions.
@en
P356
P1476
Catalytic enantioselective O-H insertion reactions.
@en
P2093
Gregory C Fu
Thomas C Maier
P304
P356
10.1021/JA0607739
P407
P577
2006-04-01T00:00:00Z