An experimental and computational approach to defining structure/reactivity relationships for intramolecular addition reactions to bicyclic epoxonium ions
about
An "aprotic" Tamao oxidation/syn-selective tautomerization reaction for the efficient synthesis of the C1-C9 fragment of fludeloneEpoxide-opening cascades promoted by water.Intramolecular oxamidation of unsaturated O-alkyl hydroxamates: a remarkably versatile entry to hydroxy lactams.Evidence that epoxide-opening cascades promoted by water are stepwise and become faster and more selective after the first cyclization.Zirconium(IV)- and hafnium(IV)-catalyzed highly enantioselective epoxidation of homoallylic and bishomoallylic alcohols.Structurally and stereochemically diverse tetrahydropyran synthesis through oxidative C-H bond activation.Stereoselective synthesis of tertiary ethers through geometric control of highly substituted oxocarbenium ions.Total synthesis of the protein phosphatase 2A inhibitor lactodehydrothyrsiferol.Rhodium-catalyzed endo-selective epoxide-opening cascades: formal synthesis of (-)-brevisin.Cyclopropane compatibility with oxidative carbocation formation: total synthesis of clavosolide AGold(I)-catalyzed cascade cyclization of allenyl epoxides.Oxidative carbocation formation in macrocycles: synthesis of the neopeltolide macrocycle.Cascade approach to stereoselective polycyclic ether formation: epoxides as trapping agents in the transposition of allylic alcohols.Epoxide-opening cascades in the synthesis of polycyclic polyether natural products.The development of endo-selective epoxide-opening cascades in water.A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides.Synthesis of marine polycyclic polyethers via endo-selective epoxide-opening cascadesNew synthetic strategies for the stereocontrolled synthesis of substituted "skipped" diepoxides.A dioxane template for highly selective epoxy alcohol cyclizations.Total syntheses of the squalene-derived halogenated polyethers ent-dioxepandehydrothyrsiferol and armatol A via bromonium- and Lewis acid-initiated epoxide-opening cascades.Total synthesis of ent-dioxepandehydrothyrsiferol via a bromonium-initiated epoxide-opening cascade.Water overcomes methyl group directing effects in epoxide-opening cascades.Studies toward brevisulcenal F via convergent strategies for marine ladder polyether synthesis.meta-Chloroperbenzoic acid (mCPBA): a versatile reagent in organic synthesis
P2860
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P2860
An experimental and computational approach to defining structure/reactivity relationships for intramolecular addition reactions to bicyclic epoxonium ions
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
2007年论文
@zh
2007年论文
@zh-cn
name
An experimental and computatio ...... ons to bicyclic epoxonium ions
@en
type
label
An experimental and computatio ...... ons to bicyclic epoxonium ions
@en
prefLabel
An experimental and computatio ...... ons to bicyclic epoxonium ions
@en
P2093
P2860
P356
P1476
An experimental and computatio ...... ons to bicyclic epoxonium ions
@en
P2093
Hakan Gunaydin
Paul E Floreancig
Shuangyi Wan
P2860
P304
P356
10.1021/JA0709674
P407
P50
P577
2007-06-05T00:00:00Z