Electronic structural changes of Mn in the oxygen-evolving complex of photosystem II during the catalytic cycle
about
Mn4Ca cluster in photosynthesis: where and how water is oxidized to dioxygenMetalloprotein structures at ambient conditions and in real-time: biological crystallography and spectroscopy using X-ray free electron lasersHydration of the oxygen-evolving complex of photosystem II probed in the dark-stable S1 state using proton NMR dispersion profiles.Light-dependent production of dioxygen in photosynthesis.Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis.Structural Changes Correlated with Magnetic Spin State Isomorphism in the S2 State of the Mn4CaO5 Cluster in the Oxygen-Evolving Complex of Photosystem II.Toward models for the full oxygen-evolving complex of photosystem II by ligand coordination to lower the symmetry of the Mn3CaO4 cubane: demonstration that electronic effects facilitate binding of a fifth metal.Substrate-water exchange in photosystem II is arrested before dioxygen formation.K- and L-edge X-ray Absorption Spectroscopy (XAS) and Resonant Inelastic X-ray Scattering (RIXS) Determination of Differential Orbital Covalency (DOC) of Transition Metal Sites.Metal oxidation states in biological water splitting† †Electronic supplementary information (ESI) available: Additional methodological details and discussion, Tables S1–S10, Fig. S1–S16, spin populations, parameters of optimized structures, experimeMetal oxidation states in biological water splitting.What Mn Kβ spectroscopy reveals concerning the oxidation states of the Mn cluster in photosystem II.The first tyrosyl radical intermediate formed in the S2-S3 transition of photosystem II.
P2860
Q26822448-909F08E0-FAC4-4F2F-9CFE-D869853B715DQ30378795-CBA89048-B635-4AD9-82C7-F943682FCDCAQ30792253-41DA9071-275F-42BA-90DA-3BB18EEE7778Q35566246-FF036CA6-F79A-4DFB-9DF3-86FC67DC1569Q35635721-7EA29B87-CBAD-483D-BFCE-A2C01C8B178EQ40356066-FCA3FC8D-6222-4743-98B4-B2622E711D5FQ41871231-F4469DB9-0A35-4EF2-8575-813E8BD1140AQ42065302-4B65C534-F508-4CA1-8D52-CF80D717F361Q46023745-4D91D692-BD2F-4567-B91C-767F4B5605B8Q47116318-8D8AE70D-237D-4BD6-B94C-57F0F5166622Q47196956-CAF5DF10-F991-47BF-AD99-016CB20C6FB0Q47659778-90015D17-EACC-49EB-A68D-A325051531CFQ54173120-68D66025-B6DB-4F40-AF54-E506C72824A8
P2860
Electronic structural changes of Mn in the oxygen-evolving complex of photosystem II during the catalytic cycle
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年論文
@yue
2013年論文
@zh-hant
2013年論文
@zh-hk
2013年論文
@zh-mo
2013年論文
@zh-tw
2013年论文
@wuu
2013年论文
@zh
2013年论文
@zh-cn
name
Electronic structural changes ...... II during the catalytic cycle
@en
type
label
Electronic structural changes ...... II during the catalytic cycle
@en
prefLabel
Electronic structural changes ...... II during the catalytic cycle
@en
P2093
P2860
P356
P1433
P1476
Electronic structural changes ...... II during the catalytic cycle
@en
P2093
George Christou
Henning Schroeder
Johannes Messinger
Junko Yano
Pieter Glatzel
Shreya Mukherjee
Thaddeus Boron
Uwe Bergmann
Vincent L Pecoraro
Vittal K Yachandra
P2860
P304
P356
10.1021/IC4005938
P407
P577
2013-05-06T00:00:00Z