Metal-catalyzed 1,2-shift of diverse migrating groups in allenyl systems as a new paradigm toward densely functionalized heterocycles.
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Highly substituted lactone/ester-containing furan library by the palladium-catalyzed carbonylation of hydroxyl-substituted 3-iodofurans.Solution-phase synthesis of a highly substituted furan library.1,2-boryl migration empowers regiodivergent synthesis of borylated furans.Copper-, Silver-, and Gold-Catalyzed Migratory Cycloisomerizations Leading to Heterocyclic Five-Membered RingsOn the validity of Au-vinylidenes in the gold-catalyzed 1,2-migratory cycloisomerization of skipped propargylpyridines.Synthesis of furans and pyrroles via migratory and double migratory cycloisomerization reactions of homopropargylic aldehydes and imines.Stereocontrolled 1,3-phosphatyloxy and 1,3-halogen migration relay toward highly functionalized 1,3-dienes.Efficient Synthesis of Chiral Trisubstituted 1,2-Allenyl Ketones by Catalytic Asymmetric Conjugate Addition of Malonic Esters to Enynes.Highly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates.Transition metal-mediated synthesis of monocyclic aromatic heterocyclesMetal-catalyzed double migratory cascade reactions of propargylic esters and phosphatesMultisubstituted N-fused heterocycles via transition metal-catalyzed cycloisomerization protocolsLow temperature organocopper-mediated two-component cross coupling/cycloisomerization approach toward N-fused heterocycles.Allylic and allenic halide synthesis via NbCl(5)- and NbBr(5)-mediated alkoxide rearrangements.ORGANOCOPPER-MEDIATED TWO-COMPONENT SN2'-SUBSTITUTION CASCADE TOWARDS N-FUSED HETEROCYCLES.Brönsted acid-catalyzed one-pot synthesis of indoles from o-aminobenzyl alcohols and furansAllenes and computational chemistry: from bonding situations to reaction mechanisms.New Approaches to the Synthesis of Metal Carbenes.Silver & gold-catalyzed routes to furans and benzofurans.Regiodivergent Catalysis: A Powerful Tool for Selective Catalysis.Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: ligand-controlled regioselectivity.Enzyme- and Ruthenium-Catalyzed Enantioselective Transformation of α-Allenic Alcohols into 2,3-Dihydrofurans.Computation-guided development of Au-catalyzed cycloisomerizations proceeding via 1,2-Si or 1,2-H migrations: regiodivergent synthesis of silylfurans.Gold(I)-catalyzed formation of furans from γ-acyloxyalkynyl ketones.Isotopic labelling studies for a gold-catalysed skeletal rearrangement of alkynyl aziridines.Tetrasubstituted allenes by Pd0-catalyzed three-component tandem Michael addition/cross-coupling reaction.Direct α-vinylidenation of aldehydes and subsequent cascade: gold and amine catalysts work synergistically.Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions.A facile synthesis of 3,4-dimercaptofurans via sulfenylation of (E)-β-chlorovinyl ketones and 1,2-sulfur migration.Gold-catalyzed ring-expansion through acyl migration to afford furan-fused polycyclic compounds.Copper/P(tBu)3 -Mediated Regiospecific Synthesis of Fused Furans and Naphthofurans.Gold(I)-catalyzed regiodivergent rearrangements: 1,2- and 1,2'-alkyl migration in skipped alkynyl ketones.Gold-catalyzed efficient synthesis of 2,4-disubstituted furans from aryloxy-enynes.Palladium(II)-catalyzed stereospecific three-component domino reactions of diyne-enones, nucleophiles, and vinyl ketones.Gold(I)-catalyzed, highly diastereoselective, tandem heterocyclizations/[3+2] cycloadditions: synthesis of highly substituted cyclopenta[c]furans.Pd/Cu-catalyzed cascade Sonogashira coupling/cyclization reactions to highly substituted 3-formyl furans.Gold-catalyzed domino reactions consisting of regio- and stereoselective 1,2-alkyl migration.Facile synthesis of substituted 3-aminofurans through a tandem reaction of N-sulfonyl-1,2,3-triazoles with propargyl alcohols.A [3 + 2]-annulation approach to tetrasubstituted furans from MBH-carbonates of acetylenic aldehydes via sequential substitution/cycloisomerization.Acidic Co-Catalysts in Cationic Gold Catalysis.
P2860
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P2860
Metal-catalyzed 1,2-shift of diverse migrating groups in allenyl systems as a new paradigm toward densely functionalized heterocycles.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年論文
@yue
2008年論文
@zh-hant
2008年論文
@zh-hk
2008年論文
@zh-mo
2008年論文
@zh-tw
2008年论文
@wuu
2008年论文
@zh
2008年论文
@zh-cn
name
Metal-catalyzed 1,2-shift of d ...... y functionalized heterocycles.
@en
type
label
Metal-catalyzed 1,2-shift of d ...... y functionalized heterocycles.
@en
prefLabel
Metal-catalyzed 1,2-shift of d ...... y functionalized heterocycles.
@en
P2093
P2860
P356
P1476
Metal-catalyzed 1,2-shift of d ...... ly functionalized heterocycles
@en
P2093
Alexander V Kel'in
Anna W Sromek
Joseph T Kim
Marina Rubina
Vladimir Gevorgyan
P2860
P304
P356
10.1021/JA0773507
P407
P577
2008-01-04T00:00:00Z