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Asymmetric organocatalysis: from proline to highly efficient immobilized organocatalystsChemo- and regioselective C(sp³)-H arylation of unactivated allylarenes by deprotonative cross-couplingThe ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Highly stereoselective and scalable anti-aldol reactions using N-(p-dodecylphenylsulfonyl)-2-pyrrolidinecarboxamide: scope and origins of stereoselectivities.Direct β-functionalization of cyclic ketones with aryl ketones via the merger of photoredox and organocatalysis.ProPhenol-catalyzed asymmetric additions by spontaneously assembled dinuclear main group metal complexes.Development of the enantioselective addition of ethyl diazoacetate to aldehydes: asymmetric synthesis of 1,2-diolsStereoselectivities of histidine-catalyzed asymmetric aldol additions and contrasts with proline catalysis: a quantum mechanical analysisEnantioselective Synthesis of Carbo- and Heterocycles through a CuH-Catalyzed Hydroalkylation Approach.Asymmetric synthesis of 1H-pyrrol-3(2H)-ones from 2,3-diketoesters by combination of aldol condensation with benzilic acid rearrangement.Total synthesis of laulimalide: synthesis of the northern and southern fragmentsBroad Spectrum Enolate Equivalent for Catalytic Chemo-, Diastereo-, and Enantioselective Addition to N-Boc Imines.Base-catalyzed direct aldolization of α-alkyl-α-hydroxy trialkyl phosphonoacetates.Organocatalytic Synthesis of Higher-Carbon Sugars: Efficient Protocol for the Synthesis of Natural Sedoheptulose and d-Glycero-l-galacto-oct-2-uloseDinuclear zinc-ProPhenol-catalyzed enantioselective α-hydroxyacetate aldol reaction with activated ester equivalents.Generation of stereochemically defined tetrasubstituted enolborinates by 1,4-hydroboration of α,β-unsaturated morpholine carboxamides with (diisopinocampheyl)borane.Construction of cyclic enones via gold-catalyzed oxygen transfer reactions.The thiopyran route to polypropionatesOrganocatalytic synthesis of carbohydrates.Construction of contiguous tetrasubstituted chiral carbon stereocenters via direct catalytic asymmetric aldol and Mannich-type reactions.Developing novel organocatalyzed aldol reactions for the enantioselective synthesis of biologically active molecules.α-Hydroxy ketones as useful templates in asymmetric reactions.Recent efforts directed to the development of more sustainable asymmetric organocatalysis.Combining transition metal catalysis and organocatalysis--an update.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Asymmetric organocatalysis mediated by α,α-L-diaryl prolinols: recent advances.Enantioselective aldol reactions catalyzed by chiral phosphine oxides.The Mukaiyama aldol reaction: 40 years of continuous development.Sequential catalysis for stereoselective synthesis of complex polyketides.Adding a functional handle to nature's building blocks: the asymmetric synthesis of β-hydroxy-α-amino acids.Organocatalytic enantioselective tandem aldol-cyclization reaction of α-isothiocyanato imides and activated carbonyl compoundsJourney Heading Towards Enantioselective Synthesis Assisted by Organocatalysis.Self-Assembled Chiral Nanostructures as Scaffolds for Asymmetric Reactions.Nucleophilic and Electrophilic Activation of Non-Heteroaromatic Amides in Atom-Economical Asymmetric Catalysis.Enantioselective Chemo- and Biocatalysis: Partners in Retrosynthesis.Enantioselective magnesium-catalyzed transformations.Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.Continuous proline catalysis via leaching of solid proline.Investigating ionic effects applied to water based organocatalysed aldol reactions.The supersilyl group as a carboxylic acid protecting group: application to highly stereoselective aldol and Mannich reactions.
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description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 17 February 2010
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
The direct catalytic asymmetric aldol reaction.
@en
The direct catalytic asymmetric aldol reaction.
@nl
type
label
The direct catalytic asymmetric aldol reaction.
@en
The direct catalytic asymmetric aldol reaction.
@nl
prefLabel
The direct catalytic asymmetric aldol reaction.
@en
The direct catalytic asymmetric aldol reaction.
@nl
P2860
P356
P1476
The direct catalytic asymmetric aldol reaction.
@en
P2093
Cheyenne S Brindle
P2860
P304
P356
10.1039/B923537J
P50
P577
2010-02-17T00:00:00Z