Synthesis and application of palladium precatalysts that accommodate extremely bulky di-tert-butylphosphino biaryl ligands.
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N-substituted 2-aminobiphenylpalladium methanesulfonate precatalysts and their use in C-C and C-N cross-couplingsPalladium-catalyzed hydroxylation of aryl and heteroaryl halides enabled by the use of a palladacycle precatalyst.Palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions with aryl chloridesMild Pd-catalyzed aminocarbonylation of (hetero)aryl bromides with a palladacycle precatalystMild and general palladium-catalyzed synthesis of methyl aryl ethers enabled by the use of a palladacycle precatalystStructure and Reactivity of [(L•Pd)n•(1,5-cyclooctadiene)] (n=1-2) Complexes Bearing Biaryl Phosphine LigandsSynthesis of diarylmethylamines via palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions.Mild palladium-catalyzed cyanation of (hetero)aryl halides and triflates in aqueous media.Mild and highly selective palladium-catalyzed monoarylation of ammonia enabled by the use of bulky biarylphosphine ligands and palladacycle precatalysts.A general, practical palladium-catalyzed cyanation of (hetero)aryl chlorides and bromides.An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates.Cascade palladium catalysis: a predictable and selectable regiocontrolled synthesis of N-arylbenzimidazoles.Suzuki-Miyaura cross-coupling optimization enabled by automated feedback.A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides.Design, Synthesis, and Validation of an Effective, Reusable Silicon-Based Transfer Agent for Room-Temperature Pd-Catalyzed Cross-Coupling Reactions of Aryl and Heteroaryl Chlorides with Readily Available Aryl Lithium Reagents.Pd-catalyzed α-arylation of α,α-difluoroketones with aryl bromides and chlorides. A route to difluoromethylarenes.Activity of Fluorine-Containing Analogues of WC-9 and Structurally Related Analogues against Two Intracellular Parasites: Trypanosoma cruzi and Toxoplasma gondii.Applications of Palladium-Catalyzed C-N Cross-Coupling Reactions.NiXantphos: a deprotonatable ligand for room-temperature palladium-catalyzed cross-couplings of aryl chlorides.Development of a Method for the N-Arylation of Amino Acid Esters with Aryl Triflates.Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters.The Evolution of Pd0/PdII-Catalyzed Aromatic Fluorination.Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands.Pd-catalyzed α-arylation of trimethylsilyl enolates of α,α-difluoroacetamides.Synthesis of aza and carbocyclic β-carbolines for the treatment of alcohol abuse. Regiospecific solution to the problem of 3,6-disubstituted β- and aza-β-carboline specificity.Oxidative addition to palladium(0) diphosphine complexes: observations of mechanistic complexity with iodobenzene as reactant.Spectroscopic characterization of (diiodomethyl)zinc iodide: application to the stereoselective synthesis and functionalization of iodocyclopropanes.Synthesis of Polyflourinated Biphenyls; Pushing the Boundaries of Suzuki-Miyaura Cross Coupling with Electron-Poor Substrates.A Stable Heroin Analogue That Can Serve as a Vaccine Hapten to Induce Antibodies That Block the Effects of Heroin and Its Metabolites in Rodents and That Cross-React Immunologically with Related Drugs of Abuse.Phase-Separable Polyisobutylene Palladium-PEPPSI Precatalysts: Synthesis and Application in Buchwald-Hartwig Amination.Enantioselective Crossed Photocycloadditions of Styrenic Olefins by Lewis Acid Catalyzed Triplet Sensitization.Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2.
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Synthesis and application of palladium precatalysts that accommodate extremely bulky di-tert-butylphosphino biaryl ligands.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 15 May 2013
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Synthesis and application of p ...... butylphosphino biaryl ligands.
@en
Synthesis and application of p ...... butylphosphino biaryl ligands.
@nl
type
label
Synthesis and application of p ...... butylphosphino biaryl ligands.
@en
Synthesis and application of p ...... butylphosphino biaryl ligands.
@nl
prefLabel
Synthesis and application of p ...... butylphosphino biaryl ligands.
@en
Synthesis and application of p ...... butylphosphino biaryl ligands.
@nl
P2860
P356
P1433
P1476
Synthesis and application of p ...... butylphosphino biaryl ligands.
@en
P2093
Nicholas C Bruno
Stephen L Buchwald
P2860
P304
P356
10.1021/OL401208T
P407
P577
2013-05-15T00:00:00Z