The development of versatile methods for palladium-catalyzed coupling reactions of aryl electrophiles through the use of P(t-Bu)3 and PCy3 as ligands
about
Fast, greener and scalable direct coupling of organolithium compounds with no additional solventsAlkyne elementometalation-Pd-catalyzed cross-coupling. Toward synthesis of all conceivable types of acyclic alkenes in high yields, efficiently, selectively, economically, and safely: "green" wayPd- and Ni-catalyzed cross-coupling reactions in the synthesis of organic electronic materialsA convenient regioselective synthesis of cyclopentadienones via palladium-catalyzed [2+2+1] cyclocarbonylation of alkynes.Rational exploration of N-heterocyclic carbene (NHC) palladacycle diversity: a highly active and versatile precatalyst for Suzuki-Miyaura coupling reactions of deactivated aryl and alkyl substrates.Highly enantioselective synthesis of γ-, δ-, and ε-chiral 1-alkanols via Zr-catalyzed asymmetric carboalumination of alkenes (ZACA)-Cu- or Pd-catalyzed cross-coupling.Organotrifluoroborates and monocoordinated palladium complexes as catalysts--a perfect combination for Suzuki-Miyaura coupling.Palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions with aryl chloridesA Reactivity-Driven Approach to the Discovery and Development of Gold-Catalyzed Organic Reactions.Pd/P(t-Bu)(3)-Catalyzed Suzuki Cross-Couplings in the Presence of Water.Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link.Nickel-catalyzed cross-couplings involving carbon-oxygen bondsγ-Selective cross-coupling of allylic silanolate salts with aromatic bromides using trialkylphosphonium tetrafluoroborate salts prepared directly from phosphine•borane adducts.Mechanistic significance of the si-o-pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates.Stereocontrolled 1,3-phosphatyloxy and 1,3-halogen migration relay toward highly functionalized 1,3-dienes.Rapid and efficient access to secondary arylmethylamines.Palladium-catalyzed 1,1-difunctionalization of ethylene.Crystal structures of three complexes of zinc chloride with tri-tert-butyl-phosphane.Nickel-Catalyzed Arylation of Heteroaryl-containing Diarylmethanes: Exceptional Reactivity of the Ni(NIXANTPHOS)-based Catalyst.Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles: substrate scope and mechanistic investigation.Suzuki-Miyaura cross-coupling optimization enabled by automated feedback.Highly bulky and stable geometry-constrained iminopyridines: Synthesis, structure and application in Pd-catalyzed Suzuki coupling of aryl chlorides.Development of a Suzuki cross-coupling reaction between 2-azidoarylboronic pinacolate esters and vinyl triflates to enable the synthesis of [2,3]-fused indole heterocycles.A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides.Alkene metathesis - a tool for the synthesis of conjugated polymers.Addressing challenges in palladium-catalyzed cross-coupling reactions through ligand design.Organometallic aspects of transition-metal catalysed regioselective C-H bond functionalisation of arenes and heteroarenes.Copper-catalysed cross-coupling: an untapped potential.Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes.Parameterization of phosphine ligands demonstrates enhancement of nickel catalysis via remote steric effects.tBu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complex As Precatalyst for Pd-Catalyzed Coupling Reactions of Aryl Halides with Polyfluoroarenes via C-H Activation Strategy.Iron(III)-mediated photocatalytic selective substitution of aryl bromine by chlorine with high chloride utilization efficiency.Combined muta- and semisynthesis: a powerful synthetic hybrid approach to access target specific antitumor agents based on ansamitocin P3.NiXantphos: a deprotonatable ligand for room-temperature palladium-catalyzed cross-couplings of aryl chlorides.Palladium- and copper-catalyzed arylation of carbon-hydrogen bonds.t-Bu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complex as a Precatalyst for the Suzuki Cross-coupling Polymerization of Aryl Dibromides with Aryldiboronic AcidsChloro({2-[mesityl(quinolin-8-yl-κN)boryl]-3,5-dimethyl-phenyl}methyl-κC)palladium(II) as a catalyst for Heck reactions.Negishi Cross-Coupling Is Compatible with a Reactive B-Cl Bond: Development of a Versatile Late-Stage Functionalization of 1,2-Azaborines and Its Application to the Synthesis of New BN Isosteres of Naphthalene and Indenyl.Asymmetric catalytic N-phosphonyl imine chemistry: the use of primary free amino acids and Et2AlCN for asymmetric catalytic Strecker reaction.Allylic ethers as educts for Suzuki-Miyaura couplings in water at room temperature
P2860
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P2860
The development of versatile methods for palladium-catalyzed coupling reactions of aryl electrophiles through the use of P(t-Bu)3 and PCy3 as ligands
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年学术文章
@wuu
2008年学术文章
@zh-cn
2008年学术文章
@zh-hans
2008年学术文章
@zh-my
2008年学术文章
@zh-sg
2008年學術文章
@yue
2008年學術文章
@zh
2008年學術文章
@zh-hant
name
The development of versatile m ...... trophiles through the use of P
@nl
The development of versatile m ...... f P(t-Bu)3 and PCy3 as ligands
@en
type
label
The development of versatile m ...... trophiles through the use of P
@nl
The development of versatile m ...... f P(t-Bu)3 and PCy3 as ligands
@en
prefLabel
The development of versatile m ...... trophiles through the use of P
@nl
The development of versatile m ...... f P(t-Bu)3 and PCy3 as ligands
@en
P2860
P356
P1476
The development of versatile m ...... f P(t-Bu)3 and PCy3 as ligands
@en
P2093
Gregory C Fu
P2860
P304
P356
10.1021/AR800148F
P407
P577
2008-11-01T00:00:00Z