Spectroscopic Evidence for the Two C-H-Cleaving Intermediates of Aspergillus nidulans Isopenicillin N Synthase.

Spectroscopic Evidence for the Two C-H-Cleaving Intermediates of Aspergillus nidulans Isopenicillin N Synthase.

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http://www.wikidata.org/entity/Q37116091
Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation.Go it alone: four-electron oxidations by mononuclear non-heme iron enzymes.O-H Activation by an Unexpected Ferryl Intermediate during Catalysis by 2-Hydroxyethylphosphonate Dioxygenase.Oxidative Cyclization in Natural Product BiosynthesisDivergent mechanisms of iron-containing enzymes for hydrocarbon biosynthesis.Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants.Terminally Truncated Isopenicillin N Synthase Generates a Dithioester Product: Evidence for a Thioaldehyde Intermediate during Catalysis and a New Mode of Reaction for Non-Heme Iron Oxidases.O2 Activation by Non-Heme Iron Enzymes.C-H Activation from Iron(II)-Nitroxido Complexes.Theory and Application of the Relationship Between Steady-State Isotope Effects on Enzyme Intermediate Concentrations and Net Rate Constants.Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes.Installation of the Ether Bridge of Lolines by the Iron- and 2-Oxoglutarate-Dependent Oxygenase, LolO: Regio- and Stereochemistry of Sequential Hydroxylation and Oxacyclization Reactions.The biosynthesis of methanobactin.NRVS Studies of the Peroxide Shunt Intermediate in a Rieske Dioxygenase and Its Relation to the Native FeII O2 Reaction.Roles of 2-oxoglutarate oxygenases and isopenicillin N synthase in β-lactam biosynthesisSpectroscopic and Electronic Structure Study of ETHE1: Elucidating the Factors Influencing Sulfur Oxidation and Oxygenation in Mononuclear Nonheme Iron Enzymes
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Spectroscopic Evidence for the Two C-H-Cleaving Intermediates of Aspergillus nidulans Isopenicillin N Synthase.

Item
http://www.wikidata.org/entity/Q37116091
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on 18 May 2016
@en
vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Spectroscopic Evidence for the ...... lans Isopenicillin N Synthase.
@en
Spectroscopic Evidence for the ...... lans Isopenicillin N Synthase.
@nl
type
label
Spectroscopic Evidence for the ...... lans Isopenicillin N Synthase.
@en
Spectroscopic Evidence for the ...... lans Isopenicillin N Synthase.
@nl
prefLabel
Spectroscopic Evidence for the ...... lans Isopenicillin N Synthase.
@en
Spectroscopic Evidence for the ...... lans Isopenicillin N Synthase.
@nl
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P1476
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Spectroscopic Evidence for the ...... lans Isopenicillin N Synthase.
@en
P2093
P2860
P304
P31
P356
P407
P433
P478
P50
P577
P698
P932