Phenolate hydroxylation in a bis(mu-oxo)dicopper(III) complex: lessons from the guanidine/amine series.
about
Proton-coupled electron transferBis(μ-oxo) dicopper(III) species of the simplest peralkylated diamine: enhanced reactivity toward exogenous substrates.Proton-coupled electron transfer reactions at a heme-propionate in an iron-protoporphyrin-IX model compoundCopper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.Catalytic phenol hydroxylation with dioxygen: extension of the tyrosinase mechanism beyond the protein matrix.A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity.Access to a Cu(II)-O-Cu(II) motif: spectroscopic properties, solution structure, and reactivity.Copper-O2 reactivity of tyrosinase models towards external monophenolic substrates: molecular mechanism and comparison with the enzyme.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.High-valent copper in biomimetic and biological oxidations.Copper-Mediated Selective Hydroxylation of a Non-activated C-H Bond in Steroids: A DFT Study of Schönecker's Reaction.N-Trityl-2-(tritylsulfan-yl)aniline.Donor-driven conformational flexibility in a real-life catalytic dicopper(ii) peroxo complex.Unexpected C(carbene)-X (X: I, Br, Cl) Reductive Elimination From N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions.Effects of electron-deficient beta-diketiminate and formazan supporting ligands on copper(I)-mediated dioxygen activation.Bis(2-{[bis-(dimethyl-amino)-methyl-idene]amino-κN}benzene-sulfonato-κN)copper(II).The mixed-valent copper thiol-ate complex hexa-kis-{μ3-2-[(1,3-dimethyl-imidazol-idene)amino]-benzene-thiol-ato}dicopper(II)tetra-copper(I) bis-(hexa-fluoridophosphate) acetonitrile disolvate dichloro-methane disolvate.Acid/base triggered interconversion of μ-η2:η2-peroxido and bis(μ-oxido) dicopper intermediates capped by proton-responsive ligands.N-[Bis(dimethyl-amino)-methyl-idene]-2-[(triphenyl-meth-yl)sulfan-yl]ethanaminium hexa-fluoro-phosphateFormation of hybrid guanidine-stabilized bis(μ-oxo)dicopper cores in solution: Electronic and steric perturbations.O2 activation and selective phenolate ortho hydroxylation by an unsymmetric dicopper mu-eta1:eta1-peroxido complex.2-[2-(Benzyl-sulfan-yl)phen-yl]-1,1,3,3-tetra-methyl-guanidine.Bis-μ-oxo and μ-η2:η2-peroxo dicopper complexes studied within (time-dependent) density-functional and many-body perturbation theory.Self-assembly of the oxy-tyrosinase core and the fundamental components of phenolic hydroxylation.Record Broken: A Copper Peroxide Complex with Enhanced Stability and Faster Hydroxylation Catalysis.Density functional theory of the CuA -like Cu2 S2 diamond core in Cu 2II(NGuaS)2 Cl2.The Cu2O2 torture track for a real-life system: [Cu2(btmgp)2O2](2+) oxo and peroxo species in density functional calculations.Catalytic aerobic oxidation of phenols to ortho-quinones with air-stable copper precatalysts.Bioinspired copper(I) complexes that exhibit monooxygenase and catechol dioxygenase activity.Selective ortho-hydroxylation-defluorination of 2-fluorophenolates with a bis(μ-oxo)dicopper(III) species.Highly Active N,O Zinc Guanidine Catalysts for the Ring-Opening Polymerization of Lactide.Relativistic effects at the Cu2O2 core - a density functional theory study.Efficient Biomimetic Hydroxylation Catalysis with a Bis(pyrazolyl)imidazolylmethane Copper Peroxide Complex.Selective Aromatic Hydroxylation with Dioxygen and Simple Copper Imine Complexes.Charged behaviour from neutral ligands: synthesis and properties of N-heterocyclic pseudo-amides.Copper Complexes of “Superpodal” Amine Ligands and Reactivity Studies towards DioxygenThe Bioinorganic and Organometallic Chemistry of Copper(III)
P2860
Q24597113-091234F5-1348-4CD6-A36B-6425994329A8Q34361460-3AD6B785-71CF-4827-BF97-7D1D6224138FQ35041238-A944918F-2242-468B-B4D3-C93F38FDED3AQ36253692-576C8548-A6EF-4605-9FBA-1F85F6001780Q37271053-2A51FA36-201C-444F-A96B-6FD805B883B2Q37285003-20AAC97E-69E0-4135-8C26-57AA70078221Q37624554-97FDC35D-0366-41CB-BD9E-17ADD3F03582Q37854485-8A3B5E1D-70D7-4AE8-9BD0-DD1D08FFFBF1Q38867180-534BCD79-556E-4839-8271-FAE1C68975BCQ39026685-DBA7AD23-C58D-42FC-BB9F-0D2ADE54D0D9Q39177186-2950B254-9C18-443E-A580-494F2FF4014BQ40030403-A085ACEE-C22F-4AA4-8DA8-F846A162A329Q40187870-98392FA1-EFE0-4E3A-B1B2-03A1D3EA3085Q41497519-05F76965-4B18-42BE-ABC7-2AC66A4D98D9Q41581041-EA2564D5-4C60-43E6-A4B2-82C0B338E5FAQ41590325-A0603EAD-418B-4864-B06D-E563B0AE11F7Q41605081-8D4B7E43-CEA4-48B9-8DE7-B95579BF0A93Q41825966-2130E89C-C6CB-4EEE-BB8F-3A649EFCB190Q42042355-42F18DBE-ABB1-4CC5-8A25-FE7C90C05FF6Q42139193-5FAD8E32-E785-4362-828A-C2340CA5A2EFQ42542333-ED58308E-14FD-4063-8CD0-EC0E8E51284FQ42727973-6C7D75DB-47AB-4070-BF7F-DC93E383A3FDQ43586764-CAFDF6F6-1725-4A11-8143-7B134F273737Q46153276-B919FEA1-0816-4D27-B927-886973329908Q46380442-39FE0F22-844B-4270-A0C4-71ADD5C7A718Q46605880-DFAFBD2A-8A9B-41DB-B2C9-B88DC7B68A6CQ46703818-A8519FFD-15E8-4300-9F83-DAC5B7D6758AQ46754744-2B27F36B-947C-42B1-BD33-1C8548B18FF9Q46814597-3F86589A-E35B-41F9-881F-A27B9E8AD8E5Q46863887-83A7385B-4F04-4F22-A290-0029102B6093Q48286802-64F0618B-09FD-476A-AF5F-FA10D5A0C6BEQ49791140-CB754875-A905-4445-B9C2-E4CF45BA9E81Q53490388-A50E649B-0BBE-4B5E-B57D-9F64133C6586Q53650376-EB89A372-ABDD-4921-ACC0-573A0B6CF9B7Q53653522-725B04EC-68AB-48F2-92CC-175524DCCB00Q57654073-D95DA8B3-50CE-482F-BF13-1277972AC966Q59287925-02F55CA6-C3D4-4BCD-988C-31BBD9EFA1B4
P2860
Phenolate hydroxylation in a bis(mu-oxo)dicopper(III) complex: lessons from the guanidine/amine series.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on January 2009
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Phenolate hydroxylation in a bis
@nl
Phenolate hydroxylation in a b ...... om the guanidine/amine series.
@en
type
label
Phenolate hydroxylation in a bis
@nl
Phenolate hydroxylation in a b ...... om the guanidine/amine series.
@en
prefLabel
Phenolate hydroxylation in a bis
@nl
Phenolate hydroxylation in a b ...... om the guanidine/amine series.
@en
P2093
P2860
P356
P1476
Phenolate hydroxylation in a b ...... om the guanidine/amine series.
@en
P2093
Christopher T Lyons
Erik C Wasinger
Gerald Henkel
Pratik Verma
Roxana Haase
T Daniel P Stack
Ulrich Flörke
P2860
P304
P356
10.1021/JA807809X
P407
P577
2009-01-01T00:00:00Z