Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.
about
Redox-neutral α-sulfenylation of secondary amines: ring-fused N,S-acetals.Redox-neutral α-oxygenation of amines: reaction development and elucidation of the mechanism.The Rügheimer-Burrows reaction revisited: Facile preparation of 4-alkylisoquinolines and 3,5-dialkylpyridines from (partially) saturated aminesAsymmetric Redox-Annulation of Cyclic Amines.Facile Access to Ring-Fused Aminals via Direct α-Amination of Secondary Amines with ortho-Aminobenzaldehydes. Synthesis of Vasicine, Deoxyvasicine, Deoxyvasicinone, Mackinazolinone and Ruteacarpine.The azomethine ylide route to amine C-H functionalization: redox-versions of classic reactions and a pathway to new transformations.Redox-Annulation of Cyclic Amines and β-Ketoaldehydes.Intramolecular Redox-Mannich Reactions: Facile Access to the Tetrahydroprotoberberine Core.Dual C-H functionalization of N-aryl amines: synthesis of polycyclic amines via an oxidative Povarov approach.The redox-Mannich reaction.The Redox-A(3) Reaction.Redox-neutral α,β-difunctionalization of cyclic amines.Redox-neutral α-C-H bond functionalization of secondary amines with concurrent C-P bond formation/N-alkylation.C-H functionalization of cyclic amines: redox-annulations with α,β-unsaturated carbonyl compounds.Redox-neutral α-arylation of amines.A unified approach to ent-atisane diterpenes and related alkaloids: synthesis of (-)-methyl atisenoate, (-)-isoatisine, and the hetidine skeleton.An Ugi Reaction Incorporating a Redox-Neutral Amine C-H Functionalization StepAcetic Acid Promoted Redox Annulations with Dual C-H Functionalization.Intramolecular [3 + 2]-cycloadditions of azomethine ylides derived from secondary amines via redox-neutral C-H functionalization.Tertiary amines as synthetic equivalents of vinyl cations: zinc bromide promoted coupling of propargylamines with α-isocyanoacetamides to give 2,4,5-trisubstituted oxazoles initiated by an internal redox process.Redox-Neutral Aromatization of Cyclic Amines: Mechanistic Insights and Harnessing of Reactive Intermediates for Amine α- and β-C-H Functionalization.A tandem annulation with a [1,3]-hydride transfer as the key step leading to isochromans.Classical-Reaction-Driven Stereo- and Regioselective C(sp(3) )-H Functionalization of Aliphatic Amines.A General, Concise Strategy that Enables Collective Total Syntheses of over 50 Protoberberine and Five Aporhoeadane Alkaloids within Four to Eight Steps.Hf(OTf)4-Catalyzed highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via benzylic C(sp3)-H bond functionalization.Mild gold-catalyzed three-component dehydrogenative coupling of terminal alkynes to amines and indole-2-carboxaldehyde.Regio- and Diastereoselective and Enantiospecific Metal-Free C(sp(3) )-H Arylation: Facile Access to Optically Active 5-Aryl 2,5-Disubstituted Pyrrolidines.
P2860
Q33894506-1B2A1AFC-FB22-4CD6-8987-192170A0DFD4Q35098651-F81D8F17-AE06-48B4-ABC9-768163F80FEDQ35867192-A9057DBE-5893-42F1-860E-C39538EC83F0Q36142441-755E3A55-C2F7-41AF-9048-206B3D405F1BQ37173920-859AF40F-BAF3-49A2-8992-5FEB73F3CD9EQ38308104-4343699E-1E3B-4C0B-9982-CE73B87A8AD5Q38834644-B11872DE-AD94-4761-9A8C-1AECAD6A6DD6Q39530179-DEFBCF85-154D-450D-84D9-C8430CC5B53AQ39939511-25F21504-1454-45F1-AC3F-D71D57E526BCQ40758581-EDC82CFA-C095-48A4-9165-84FF546F56F8Q40833809-F883CEA0-6082-466E-8D25-50D510077475Q41067116-FEC6D7CB-7DF9-43C2-BC26-B0A8B96F6F30Q41862545-CAB2AB38-786C-402F-90FC-FE9C8C4D1794Q41928386-4FCAF2BA-C37A-4D34-83A8-13435025B7A8Q42008846-9DE62C59-D6ED-4125-9304-C3EEB9C78606Q42038638-3F05EA2F-7C97-4A3B-BA8D-9A210993F65AQ42154026-21CE2DD6-3343-4F34-835C-CEBE9DBD8C57Q42219839-73F09B26-E38B-485C-9C0B-43A9F8EA812CQ43050023-95B581B3-BDFD-4351-95CF-21C9206E7F47Q44383795-C9A4D014-6BD1-4DDB-9ABD-160560D42CB1Q46586475-6A98DFF3-41E9-48C9-A7C4-2FE561A4D8B5Q47678204-2A600F5A-DE2D-4B22-A44E-C1683A69D200Q50227923-A15AC413-2B65-48ED-A8E6-174AF100EF9CQ50868632-2ECF120C-BABA-4716-8DA7-D25809157C9CQ50935939-76454545-2265-4BE0-98E0-E8E2C9933687Q51749025-F99FCDE3-2425-4B05-BE37-59E2205196B3Q53482247-B1D6FB1D-CBC0-4024-B882-CE3FCE7691ED
P2860
Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 25 February 2013
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Redox-neutral copper
@nl
Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.
@en
type
label
Redox-neutral copper
@nl
Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.
@en
prefLabel
Redox-neutral copper
@nl
Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.
@en
P2093
P2860
P356
P1476
Redox-neutral copper(II) carboxylate catalyzed α-alkynylation of amines.
@en
P2093
Aaron X Sun
Daniel Seidel
Deepankar Das
P2860
P304
P356
10.1002/ANIE.201300021
P407
P577
2013-02-25T00:00:00Z