Lessons from nature: unraveling biological CH bond activation
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The origin and evolution of ribonucleotide reductionNovel covalent bond in proteins: calculations on model systems question the bond stability.Reaction landscape of a pentadentate N5-ligated Mn(II) complex with O2˙- and H2O2 includes conversion of a peroxomanganese(III) adduct to a bis(μ-oxo)dimanganese(III,IV) species.Role of metal-oxo complexes in the cleavage of C-H bonds.Water-soluble Fe(II)-H2O complex with a weak O-H bond transfers a hydrogen atom via an observable monomeric Fe(III)-OH.Characterization of monomeric Mn(II/III/IV)-hydroxo complexes from X- and Q-band dual mode electron paramagnetic resonance (EPR) spectroscopy.Role of the secondary coordination sphere in metal-mediated dioxygen activation.Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes.Mononuclear-dinuclear equilibrium of grafted copper complexes confined in the nanochannels of MCM-41 silica.
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Lessons from nature: unraveling biological CH bond activation
description
article científic
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article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on February 2009
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
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name
Lessons from nature: unraveling biological CH bond activation
@en
Lessons from nature: unraveling biological CH bond activation.
@nl
type
label
Lessons from nature: unraveling biological CH bond activation
@en
Lessons from nature: unraveling biological CH bond activation.
@nl
prefLabel
Lessons from nature: unraveling biological CH bond activation
@en
Lessons from nature: unraveling biological CH bond activation.
@nl
P2860
P1476
Lessons from nature: unraveling biological CH bond activation
@en
P2093
A S Borovik
Kari L Stone
P2860
P304
P356
10.1016/J.CBPA.2009.02.008
P577
2009-02-01T00:00:00Z