Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight.
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Vertically π-expanded imidazo[1,2-a]pyridine: the missing link of the puzzle.C-H bonds as ubiquitous functionality: a general approach to complex arylated imidazoles via regioselective sequential arylation of all three C-H bonds and regioselective N-alkylation enabled by SEM-group transposition.Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.A general method for copper-catalyzed arene cross-dimerizationSynthesis of ent-ketorfanol via a C-H alkenylation/torquoselective 6π electrocyclization cascade.Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activationRh(I)-catalyzed direct arylation of pyridines and quinolines.Microwave-Assisted Direct Biaryl Coupling: First Application to the Synthesis of Aporphines.Various difunctionalizations of acrylamide: an efficient approach to synthesize oxindoles.Recent advances in direct C-H arylation: Methodology, selectivity and mechanism in oxazole series.Selective C-H trifluoromethylation of benzimidazoles through photoredox catalysis.A palladium-catalyzed synthesis of (hetero)aryl-substituted imidazoles from aryl halides, imines and carbon monoxide.Palladium-catalyzed indole, pyrrole, and furan arylation by aryl chlorides.A rapid and efficient route to benzazole heterocycles.Carbon-hydrogen bond functionalization approach for the synthesis of fluorenones and ortho-arylated benzonitriles.Cu-catalyzed direct C-H bond functionalization: a regioselective protocol to 5-aryl thiazolo[3,2-b]-1,2,4-triazoles.Rhodium(I)-catalyzed redox-economic cross-coupling of carboxylic acids with arenes directed by N-containing groups.Developments in direct C-H arylation of (hetero)arenes under microwave irradiation.Copper-catalyzed synthesis of indolyl diketones via C-H oxidation/diacylation of indoles with arylglyoxal hydrates.Iodine mediated oxidative cross-coupling of unprotected anilines and heteroarylation of benzothiazoles with 2-methylquinoline.Direct arylation of N-heteroarenes with aryldiazonium salts by photoredox catalysis in water.Nickel-catalyzed sp2 C-H bonds arylation of N-aromatic heterocycles with Grignard reagents at room temperature.Amine-catalyzed direct photoarylation of unactivated arenes.KI-catalyzed arylation of benzothiazoles from the coupling of aryl aldehydes with benzothiazoles in neat water.Linear correlation between the C-H activation barrier and the C-Cu/C-H bond dissociation energy gap in Cu-promoted C-H activation of heteroarenes.C-H arylation and alkenylation of imidazoles by nickel catalysis: solvent-accelerated imidazole C-H activation.In Situ Phosphine Oxide Reduction: A Catalytic Appel Reaction
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Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on 02 February 2008
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Rh(I)-catalyzed arylation of h ...... e through mechanistic insight.
@en
type
label
Rh(I)-catalyzed arylation of h ...... e through mechanistic insight.
@en
prefLabel
Rh(I)-catalyzed arylation of h ...... e through mechanistic insight.
@en
P2093
P2860
P356
P1476
Rh(I)-catalyzed arylation of h ...... e through mechanistic insight.
@en
P2093
Ashley M Berman
Jared C Lewis
Jonathan A Ellman
Robert G Bergman
P2860
P304
P356
10.1021/JA0748985
P407
P577
2008-02-02T00:00:00Z