Synthesis of Pd Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions
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Diastereo- and enantioselective copper-catalyzed intramolecular carboamination of alkenes for the synthesis of hexahydro-1H-benz[f]indoles.Polymer [Pd(CH2SO2C6H4Me)2]n, a precursor to remarkably stable Pd organometallics.Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications.Reversible alkene insertion into the Pd-N bond of Pd(II)-sulfonamidates and implications for catalytic amidation reactions.Reconciling the stereochemical course of nucleopalladation with the development of enantioselective wacker-type cyclizations.Mechanistic studies of Wacker-type amidocyclization of alkenes catalyzed by (IMes)Pd(TFA)2(H2O): kinetic and stereochemical implications of proton transfer.Asymmetric palladium-catalyzed hydroarylation of styrenes and dienesStereoselective synthesis of cis-2,5-disubstituted pyrrolidines via Wacker-type aerobic oxidative cyclization of alkenes with tert-butanesulfinamide nucleophiles.Enantioselective Pd(II)-catalyzed aerobic oxidative amidation of alkenes and insights into the role of electronic asymmetry in pyridine-oxazoline ligands.Cascade intramolecular N-arylation/intermolecular carboamination reactions for the construction of tricyclic heterocycles.N-alkyl functionalised expanded ring N-heterocyclic carbene complexes of rhodium(I) and iridium(I): structural investigations and preliminary catalytic evaluation.Iron(II) complexes of ditopic carbanionic carbenes.Expanded ring N-heterocyclic carbenes: a comparative study of ring size in palladium (0) catalysed Mizoroki-Heck coupling.Mechanisms for C(sp2)-Si activation of aryltrimethylsilyl groups in palladium-catalysed couplings.Alkaline earth guests in polyoxopalladate chemistry: from nanocube to nanostar via an open-shell structure.Light induced catalytic intramolecular hydrofunctionalization of allylphenols mediated by porphyrin rhodium(iii) complexes.Asymmetric borylation of α,β-unsaturated esters catalyzed by novel ring expanded N-heterocyclic carbenes based on chiral 3,4-dihydro-quinazolinium compounds.
P2860
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P2860
Synthesis of Pd Complexes Bearing an Enantiomerically-Resolved Seven-Membered N-Heterocyclic Carbene Ligands and Initial Studies of their Use in Asymmetric Wacker-Type Oxidative Cyclization Reactions
description
article científic
@ca
article scientifique
@fr
articolo scientifico
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artigo científico
@pt
bilimsel makale
@tr
scientific article published on June 2009
@en
vedecký článok
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vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
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name
Synthesis of Pd Complexes Bear ...... xidative Cyclization Reactions
@en
Synthesis of Pd Complexes Bear ...... idative Cyclization Reactions.
@nl
type
label
Synthesis of Pd Complexes Bear ...... xidative Cyclization Reactions
@en
Synthesis of Pd Complexes Bear ...... idative Cyclization Reactions.
@nl
prefLabel
Synthesis of Pd Complexes Bear ...... xidative Cyclization Reactions
@en
Synthesis of Pd Complexes Bear ...... idative Cyclization Reactions.
@nl
P2093
P2860
P1433
P1476
Synthesis of Pd Complexes Bear ...... xidative Cyclization Reactions
@en
P2093
Ana Bergant
Christopher C Scarborough
Graham T Sazama
Ilia A Guzei
Lara C Spencer
Shannon S Stahl
P2860
P304
P356
10.1016/J.TET.2009.04.072
P577
2009-06-01T00:00:00Z