Chiral NHC-catalyzed oxodiene Diels-Alder reactions with alpha-chloroaldehyde bisulfite salts
about
Chiral N-heterocyclic carbene-catalyzed generation of ester enolate equivalents from {alpha},{beta}-unsaturated aldehydes for enantioselective Diels-Alder reactionsLate-stage diversification of chiral N-heterocyclic-carbene precatalysts for enantioselective homoenolate additions.Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes.α-Haloaldehydes: versatile building blocks for natural product synthesis.Catalytic Asymmetric Inverse-Electron-Demand Hetero-Diels-Alder Reactions.N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids.N-heterocyclic-carbene-catalyzed asymmetric oxidative hetero-Diels-Alder reactions with simple aliphatic aldehydes.Formal synthesis of salinosporamide A via NHC-catalyzed intramolecular lactonizationMetal-free catalytic C-Si bond formation in an aqueous medium. Enantioselective NHC-catalyzed silyl conjugate additions to cyclic and acyclic α,β-unsaturated carbonyls.NHC-mediated enantioselective formal [4 + 2] cycloadditions of alkylarylketenes and β,γ-unsaturated α-ketocarboxylic esters and amides.Assembly of spirooxindole derivatives containing four consecutive stereocenters by using cascade reactions catalyzed by an N-heterocyclic carbene.NHC-catalyzed [4+2] cycloaddition reactions for the synthesis of 3'-spirocyclic oxindoles via a C-F bond cleavage protocol.Cooperative catalysis of N-heterocyclic carbene and Brønsted acid for a highly enantioselective route to unprotected spiro-indoline-pyrans.
P2860
Q34375767-E944DCE3-72EE-46A1-845E-1EE05DDD00B6Q35231395-F0EA4343-E16E-4A94-99D9-8FAF47ADDA6AQ36714193-F8EA5DF8-FCD0-4E5F-80FB-F025A0C7BD6CQ38069124-B5965186-5C92-44A8-914C-8CE7C4F01B71Q39309202-334CFDC6-A5E0-4E6A-87E0-03283CF93134Q39644073-5AB72235-937F-4C5B-99FD-50AC28791316Q39645724-26BE9322-7E50-4657-B12B-89901BED84EFQ42094207-C4FAB667-3488-4CFA-A7D5-83AC9BE0E32EQ42735961-88AFF7A1-923E-4943-B434-686044C2AD59Q46069735-93767546-4743-49BB-9A4E-8449E3178D77Q46117880-99BFDE0B-8A57-4B47-822E-56BE508A4B9CQ47241134-6A36D466-5647-4210-BB84-AB9BFC924424Q53260876-D3234DDD-B999-4B3A-9B6B-11893B0156D2
P2860
Chiral NHC-catalyzed oxodiene Diels-Alder reactions with alpha-chloroaldehyde bisulfite salts
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 26 July 2008
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Chiral NHC-catalyzed oxodiene ...... chloroaldehyde bisulfite salts
@en
Chiral NHC-catalyzed oxodiene ...... hloroaldehyde bisulfite salts.
@nl
type
label
Chiral NHC-catalyzed oxodiene ...... chloroaldehyde bisulfite salts
@en
Chiral NHC-catalyzed oxodiene ...... hloroaldehyde bisulfite salts.
@nl
prefLabel
Chiral NHC-catalyzed oxodiene ...... chloroaldehyde bisulfite salts
@en
Chiral NHC-catalyzed oxodiene ...... hloroaldehyde bisulfite salts.
@nl
P2093
P2860
P356
P1433
P1476
Chiral NHC-catalyzed oxodiene ...... chloroaldehyde bisulfite salts
@en
P2093
Brendan J Beahm
Jeffrey W Bode
P2860
P304
P356
10.1021/OL801502H
P407
P577
2008-07-26T00:00:00Z