Chemical analogues relevant to molybdenum and tungsten enzyme reaction centres toward structural dynamics and reaction diversity.
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Proton-coupled electron transferBiochemistry and theory of proton-coupled electron transferNitrate and periplasmic nitrate reductasesMechanism of tungsten-dependent acetylene hydratase from quantum chemical calculations.Monooxomolybdenum(VI) complexes possessing olefinic dithiolene ligands: probing Mo-S covalency contributions to electron transfer in dimethyl sulfoxide reductase family molybdoenzymes.The mononuclear molybdenum enzymes.Influence of the oxygen atom acceptor on the reaction coordinate and mechanism of oxygen atom transfer from the dioxo-Mo(VI) complex, Tp(iPr)MoO(2)(OPh), to tertiary phosphinesRecent developments in the study of molybdoenzyme models.Infrared multiple photon dissociation spectroscopy of a gas-phase oxo-molybdenum complex with 1,2-dithiolene ligands.Chalcogenidobis(ene-1,2-dithiolate)molybdenum(IV) complexes (chalcogenide E = O, S, Se): probing Mo≡E and ene-1,2-dithiolate substituent effects on geometric and electronic structure.Quantitation of the ligand effect in oxo-transfer reactions of dioxo-Mo(VI) trispyrazolyl borate complexes.Dioxomolybdenum(VI) complexes with ene-1,2-dithiolate ligands: synthesis, spectroscopy, and oxygen atom transfer reactivity.A Model for the Active-Site Formation Process in DMSO Reductase Family Molybdenum Enzymes Involving Oxido-Alcoholato and Oxido-Thiolato Molybdenum(VI) Core Structures.Oxo-carboxylato-molybdenum(VI) complexes possessing dithiolene ligands related to the active site of type II DMSOR family molybdoenzymes.Structural and functional models in molybdenum and tungsten bioinorganic chemistry: description of selected model complexes, present scenario and possible future scopes.Converting between the oxides of nitrogen using metal-ligand coordination complexes.Acetylene hydratase: a non-redox enzyme with tungsten and iron-sulfur centers at the active site.Synthesis, characterization and oxygen atom transfer reactivity of a pair of Mo(iv)O- and Mo(vi)O2-enedithiolate complexes - a look at both ends of the catalytic transformation.Significant differences of monooxotungsten(IV) and dioxotungsten(VI) benzenedithiolates containing two intramolecular NHS hydrogen bonds from molybdenum analogues.Theoretical study of the oxidation of phenolates by the [Cu2O2(N,N'-di-tert-butylethylenediamine)2]2+ complex.Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation.A new series of bis(ene-1,2-dithiolato)tungsten(IV), -(V), -(VI) complexes as reaction centre models of tungsten enzymes: preparation, crystal structures and spectroscopic properties.Strong NH···S hydrogen bonds in molybdoenzyme models containing anilide moieties.Activation of molecular oxygen by a molybdenum complex for catalytic oxidation.Comparative studies on the contribution of NHS hydrogen bonds in tungsten and molybdenum benzenedithiolate complexes.A Bioinspired Molybdenum Complex as a Catalyst for the Photo- and Electroreduction of Protons.Recent advances on the chemistry of transition metal complexes of 2-(arylazo)pyridines and its arylamino derivatives.Synthesis and Reactivity of a Bio-inspired Dithiolene Ligand and its Mo Oxo Complex.
P2860
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P2860
Chemical analogues relevant to molybdenum and tungsten enzyme reaction centres toward structural dynamics and reaction diversity.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 30 September 2008
@en
vedecký článok
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vetenskaplig artikel
@sv
videnskabelig artikel
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vědecký článek
@cs
name
Chemical analogues relevant to ...... namics and reaction diversity.
@en
Chemical analogues relevant to ...... namics and reaction diversity.
@nl
type
label
Chemical analogues relevant to ...... namics and reaction diversity.
@en
Chemical analogues relevant to ...... namics and reaction diversity.
@nl
prefLabel
Chemical analogues relevant to ...... namics and reaction diversity.
@en
Chemical analogues relevant to ...... namics and reaction diversity.
@nl
P356
P1476
Chemical analogues relevant to ...... namics and reaction diversity.
@en
P2093
Hideki Sugimoto
Hiroshi Tsukube
P304
P356
10.1039/B610235M
P577
2008-09-30T00:00:00Z