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Enantiodivergent Fluorination of Allylic Alcohols: Data Set Design Reveals Structural Interplay between Achiral Directing Group and Chiral Anion.Asymmetric Strecker Reaction Arising from the Molecular Orientation of an Achiral Imine at the Single-Crystal Face: Enantioenriched l- and d-Amino Acids.BINEPINES: chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis.Catalytic, asymmetric halofunctionalization of alkenes--a critical perspective.Asymmetric cyanation of imines via dipeptide-derived organophosphine dual-reagent catalysis.A new approach to the asymmetric Mannich reaction catalyzed by chiral N,N'-dioxide-metal complexes.Dynamic asymmetric organocatalysis: cooperative effects of weak interactions and conformational flexibility in asymmetric organocatalysts.Contemporary screening approaches to reaction discovery and development.Transmission of chirality through space and across length scales.Mirror Symmetry Breaking by Chirality Synchronisation in Liquids and Liquid Crystals of Achiral Molecules.Asymmetric α-amination of β-keto esters using a guanidine-bisurea bifunctional organocatalyst.Caution in the Use of Nonlinear Effects as a Mechanistic Tool for Catalytic Enantioconvergent Reactions: Intrinsic Negative Nonlinear Effects in the Absence of Higher-Order Species.Perspectives in chemistry--steps towards complex matter.Remarkable levels of enantioswitching in catalytic asymmetric hydroboration.Synthetic scope and DFT analysis of the chiral binap-gold(I) complex-catalyzed 1,3-dipolar cycloaddition of azlactones with alkenes.Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Mechanistic basis for high stereoselectivity and broad substrate scope in the (salen)Co(III)-catalyzed hydrolytic kinetic resolution.Chirality- and sequence-selective successive self-sorting via specific homo- and complementary-duplex formations.On- and Off-Cycle Catalyst Cooperativity in Anion-Binding Catalysis.Highly enantioselective synthesis of alpha-stereogenic esters through catalytic asymmetric michael addition of 4-oxo-4-arylbutenoates.Boronic acid catalysis for mild and selective [3+2] dipolar cycloadditions to unsaturated carboxylic acids.Enantioselective organocatalytic addition of oxazolones to 1,1-bis(phenylsulfonyl)ethylene: a convenient asymmetric synthesis of quaternary alpha-amino acids.Ligand self-sorting and nonlinear effects in dinuclear asymmetric hydrogenation: complexity in catalysis.Mirror-symmetry-breaking in poly[(9,9-di-n-octylfluorenyl- 2,7-diyl)-alt-biphenyl] (PF8P2) is susceptible to terpene chirality, achiral solvents, and mechanical stirring.Can the analyte-triggered asymmetric autocatalytic Soai reaction serve as a universal analytical tool for measuring enantiopurity and assigning absolute configuration?Catalytic Michael/Ring-Closure Reaction of α,β-Unsaturated Pyrazoleamides with Amidomalonates: Asymmetric Synthesis of (-)-Paroxetine.Chiral-Zn(NTf2)2-complex-catalyzed diastereo- and enantioselective direct conjugate addition of arylacetonitriles to alkylidene malonates.Chirality in adsorption on solid surfaces.Asymmetric amplification in the catalytic enantioselective 1,2-addition of Grignard reagents to enones.Intermolecular enantioselective dearomatization reaction of β-naphthol using meso-aziridine: a bifunctional in situ generated magnesium catalyst.Chiral calcium-BINOL phosphate catalyzed diastereo- and enantioselective synthesis of syn-1,2-disubstituted 1,2-diamines: scope and mechanistic studies.Making Fe(BPBP)-catalyzed C-H and C[double bond, length as m-dash]C oxidations more affordable.Self-assembly of a highly organized, hexameric supramolecular architecture: formation, structure and properties.Cobalt-Catalyzed Asymmetric Allylation of Cyclic Ketimines.Azetidine-derived dinuclear zinc catalyzed asymmetric phospha-Michael addition of dialkyl phosphite to α,β-unsaturated carbonyl compounds.Catalytic Enantioselective Double Carbopalladation/C-H Functionalization with Statistical Amplification of Product Enantiopurity: A Convertible Linker Approach.Absolute asymmetric synthesis in enantioselective autocatalytic reaction networks: theoretical games, speculations on chemical evolution and perhaps a synthetic option.Enantioselective Propargylation of Polyols and Desymmetrization of meso 1,2-Diols by Copper/Borinic Acid Dual Catalysis.Highly Enantioselective Ferrocenyl Palladacycle-Acetate Catalysed Arylation of Aldimines and Ketimines with Arylboroxines.
P2860
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P2860
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on January 2009
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Nonlinear effects in asymmetric catalysis.
@en
Nonlinear effects in asymmetric catalysis.
@nl
type
label
Nonlinear effects in asymmetric catalysis.
@en
Nonlinear effects in asymmetric catalysis.
@nl
prefLabel
Nonlinear effects in asymmetric catalysis.
@en
Nonlinear effects in asymmetric catalysis.
@nl
P2093
P356
P1476
Nonlinear effects in asymmetric catalysis.
@en
P2093
Henri B Kagan
Susan Abraham
Tummanapalli Satyanarayana
P304
P356
10.1002/ANIE.200705241
P407
P577
2009-01-01T00:00:00Z