Enantioselective synthesis of an ophiobolin sesterterpene via a programmed radical cascade
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Radicals: Reactive Intermediates with Translational PotentialDirect Assembly of Prenylated Heteroarenes through a Cascade Minisci Reaction/Dehydration Sequence.The Biological Activities of Sesterterpenoid-Type Ophiobolins.Navigating the Chiral Pool in the Total Synthesis of Complex Terpene Natural Products.Ruthenium-Catalyzed Metathesis Cascade Reactions in Natural Products Synthesis.Structural and Chemical Biology of Terpenoid Cyclases.Biomimetic Platinum-Promoted Polyene Polycyclizations: Influence of Alkene Substitution and Pre-cyclization Conformations.Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis.Modulators of 14-3-3 Protein-Protein Interactions.Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis.Enantioselective cyclizations and cyclization cascades of samarium ketyl radicals.Wolff/Cope Approach to the AB Ring of the Sesterterpenoid Variecolin.Total Syntheses of Sesterterpenoid Ansellones A and B, and Phorbadione.Expedient and Diastereodivergent Assembly of Terpenoid Decalin Subunits having Quaternary Stereocenters through Organocatalytic Robinson Annulation of Nazarov Reagent.Total synthesis of complex terpenoids employing radical cascade processes.Enantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C-H Alkylation.Modular access to functionalized 5–8–5 fused ring systems via a photoinduced cycloisomerization reaction† †Electronic supplementary information (ESI) available: Experimental procedures at characterization data. CCDC 1816383–1816390. For ESI and crysEnfumafungin synthase represents a novel lineage of fungal triterpene cyclases
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P2860
Enantioselective synthesis of an ophiobolin sesterterpene via a programmed radical cascade
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article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on May 2016
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Enantioselective synthesis of ...... a a programmed radical cascade
@en
Enantioselective synthesis of ...... a programmed radical cascade.
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type
label
Enantioselective synthesis of ...... a a programmed radical cascade
@en
Enantioselective synthesis of ...... a programmed radical cascade.
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prefLabel
Enantioselective synthesis of ...... a a programmed radical cascade
@en
Enantioselective synthesis of ...... a programmed radical cascade.
@nl
P2093
P2860
P356
P1433
P1476
Enantioselective synthesis of ...... a a programmed radical cascade
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P2093
Huck K Grover
Thomas J Maimone
Zachary G Brill
P2860
P304
P356
10.1126/SCIENCE.AAF6742
P407
P577
2016-05-01T00:00:00Z