Multifunctional chiral phosphine organocatalysts in catalytic asymmetric Morita-Baylis-Hillman and related reactions.
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Scaffolding Catalysis: Expanding the Repertoire of Bifunctional Catalysts.The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Hydroxyproline-derived pseudoenantiomeric [2.2.1] bicyclic phosphines: asymmetric synthesis of (+)- and (-)-pyrrolines.Chiral phosphines in nucleophilic organocatalysisDiscovery of neuritogenic compound classes inspired by natural products.Enantioselective Nazarov Cyclization Catalyzed by a Cinchona Alkaloid Derivative.Chiral multifunctional thiourea-phosphine catalyzed asymmetric [3 + 2] annulation of Morita-Baylis-Hillman carbonates with maleimides.One-pot phosphine-catalyzed syntheses of quinolinesEnantioselective [3 + 2] annulation of α-substituted allenoates with β,γ-unsaturated N-sulfonylimines catalyzed by a bifunctional dipeptide phosphine.Asymmetric catalytic aza-Morita-Baylis-Hillman reaction for the synthesis of 3-substituted-3-aminooxindoles with chiral quaternary carbon centersAdvances in nucleophilic phosphine catalysis of alkenes, allenes, alkynes, and MBHADs.Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric AnnulationsThe Baylis-Hillman reaction: a novel concept for creativity in chemistry.Increasing the reactivity of nitrogen catalysts.The upside of downsizing: asymmetric trifunctional organocatalysts as small enzyme mimics for cooperative enhancement of both rate and enantioselectivity with regulation.Journey Heading Towards Enantioselective Synthesis Assisted by Organocatalysis.Recent developments in the synthesis and utilization of chiral β-aminophosphine derivatives as catalysts or ligands.Cooperative Trifunctional Organocatalysts for Proficient Proton Transfer Reactions.Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.Stereoselective Syntheses of α,β-Unsaturated γ-Amino Esters Through Phosphine-Catalyzed γ-Umpolung Additions of Sulfonamides to γ-Substituted Allenoates.Synthesis of Functionalized Alkylidene Indanes and Indanones through Tandem Phosphine-Palladium CatalysisPhosphine-catalyzed enantioselective [3 + 2] cycloadditions of γ-substituted allenoates with β-perfluoroalkyl enones.Enantioselective one-pot synthesis of α-amino esters by a phosphine-catalyzed [3+2]-cycloaddition reaction.Phosphine/palladium-catalyzed syntheses of alkylidene phthalans, 3-deoxyisoochracinic acid, isoochracinic acid, and isoochracinol.Catalyst-controlled regioselectivity in phosphine catalysis: the synthesis of spirocyclic benzofuranones via regiodivergent [3 + 2] annulations of aurones and an allenoate.Dynamic covalent organocatalysts discovered from catalytic systems through rapid deconvolution screeningPhosphine-Initiated General-Base-Catalyzed Quinolone Synthesis.Phosphine-Catalyzed Intramolecular Cyclizations of α-Nitroethylallenoates Forming (Z)-Furanone Oximes.Phosphine-containing Lewis base catalyzed cyclization of benzofuranone type electron-deficient alkenes with allenoates: a facile synthesis of spirocyclic benzofuranones.Phosphine-catalyzed [3 + 2] cycloaddition of Morita-Baylis-Hillman carbonates with sulfamate-derived cyclic imines.One step synthesis of benzoxazepine derivatives via a PPh(3) catalyzed aza-MBH domino reaction between salicyl N-tosylimines and allenoates.Understanding the directed ortho lithiation of (R)-Ph₂P(=NCO₂Me)NHCH(Me)Ph. NMR spectroscopic and computational study of the structure of the N-lithiated species.Ferrocene Derived Bifunctional Phosphine-Catalyzed Asymmetric Oxa-[4+2] Cycloaddition of α-Substituted Allenones with Enones.Enantioselective Phosphine-Catalyzed Formal [4+4] Annulation of α,β-Unsaturated Imines and Allene Ketones: Construction of Eight-Membered Rings.Morita-Baylis-Hillman Reaction of β,β-Disubstituted Enones: An Enantioselective Organocatalytic Approach for the Synthesis of Cyclopenta[b]annulated Arenes and Heteroarenes.Asymmetric Morita-Baylis-Hillman Reaction: Catalyst Development and Mechanistic Insights Based on Mass Spectrometric Back-Reaction Screening.A computational investigation of the solvent-dependent enantioselective intramolecular Morita-Baylis-Hillman reaction of enones.Enantioselective intermolecular cross Rauhut-Currier reactions of activated alkenes with acrolein.Chiral Sulfinamide Bisphosphine Catalysts: Design, Synthesis, and Application in Highly Enantioselective Intermolecular Cross-Rauhut-Currier Reactions.Design, synthesis, and application of a chiral sulfinamide phosphine catalyst for the enantioselective intramolecular rauhut-currier reaction.
P2860
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P2860
Multifunctional chiral phosphine organocatalysts in catalytic asymmetric Morita-Baylis-Hillman and related reactions.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on July 2010
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Multifunctional chiral phosphi ...... Hillman and related reactions.
@en
Multifunctional chiral phosphi ...... Hillman and related reactions.
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type
label
Multifunctional chiral phosphi ...... Hillman and related reactions.
@en
Multifunctional chiral phosphi ...... Hillman and related reactions.
@nl
prefLabel
Multifunctional chiral phosphi ...... Hillman and related reactions.
@en
Multifunctional chiral phosphi ...... Hillman and related reactions.
@nl
P356
P1476
Multifunctional chiral phosphi ...... -Hillman and related reactions
@en
P2093
P304
P356
10.1021/AR900271G
P407
P50
P577
2010-07-01T00:00:00Z