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Copper(I)-catalyzed nucleophilic addition of ynamides to acyl chlorides and activated N-heterocyclesStereoselective additions of thiyl radicals to terminal ynamidesStereoselective synthesis of β-hydroxy enamines, aminocyclopropanes, and 1,3-amino alcohols via asymmetric catalysis.Synthesis of polycyclic benzofused nitrogen heterocycles via a tandem ynamide benzannulation/ring-closing metathesis strategy. Application in a formal total synthesis of (+)-FR900482Synthesis of 2-iodoynamides and regioselective [2+2] cycloadditions with ketene.[2+2+2] Cycloadditions of siloxy alkynes with 1,2-diazines: from reaction discovery to identification of an antiglycolytic chemotype.S3S63 Terminal Ynamides: Synthesis, Coupling Reactions and Additions to Common Electrophiles.Allenamides: a powerful and versatile building block in organic synthesis.AlCl₃-Catalyzed Ring Expansion Cascades of Bicyclic Cyclobutenamides Involving Highly Strained Cis,Trans-Cycloheptadienone Intermediates.A Single-Flask Synthesis of α-Alkylidene and α-Benzylidene Lactones from Ethoxyacetylene, Epoxides/Oxetanes, and Carbonyl Compounds.Efficient Access to Multifunctional Trifluoromethyl Alcohols through Base-Free Catalytic Asymmetric C-C Bond Formation with Terminal Ynamides.Axial preferences in allylation reactions via the Zimmerman-Traxler transition state.Benzannulation via the reaction of ynamides and vinylketenes. application to the synthesis of highly substituted indolesBatch and flow photochemical benzannulations based on the reaction of ynamides and diazo ketones. Application to the synthesis of polycyclic aromatic and heteroaromatic compounds.Catalytic enantioselective nucleophilic addition of ynamides to aldehydes.Recent advances in carbocupration of α-heterosubstituted alkynes.Impact of copper-catalyzed cross-coupling reactions in natural product synthesis: the emergence of new retrosynthetic paradigms.Turning unreactive copper acetylides into remarkably powerful and mild alkyne transfer reagents by oxidative umpolung.Introducing a new class of N-phosphoryl ynamides via Cu(I)-catalyzed amidations of alkynyl bromides.Recent progress towards gold-catalyzed synthesis of N-containing tricyclic compounds based on ynamides.SYNTHESIS OF DE NOVO CHIRAL γ-AMINO-YNAMIDES USING LITHIATED YNAMIDES. OBSERVATION OF A UNIQUE 5-ENDO-DIG CYCLIZATION WITH AN INVERSION OF S-CENTER.Metal-free intermolecular formal cycloadditions enable an orthogonal access to nitrogen heterocycles.Regio- and stereoselective carbometallation reactions of N-alkynylamides and sulfonamides.Divergent C-H Insertion-Cyclization Cascades of N-Allyl Ynamides.A Silver(I)-Catalyzed Intramolecular Ficini's [2 + 2] Cycloaddition Employing Ynamides.Catalytic intramolecular decarbonylative coupling of 3-aminocyclobutenones and alkenes: a unique approach to [3.1.0] bicyclesHarnessing the Electrophilicity of Keteniminium Ions: A Simple and Straightforward Entry to Tetrahydropyridines and Piperidines from Ynamides.A highly stereoselective addition of lithiated ynamides to Ellman-Davis chiral N-tert-butanesulfinyl imines.Torquoselective ring opening of fused cyclobutenamides: evidence for a cis,trans-cyclooctadienone intermediate.Enantioselective allylic alkylation of stereodefined polysubstituted copper enolates as an entry to acyclic quaternary carbon stereocentres.Generation of rhodium(I) carbenes from ynamides and their reactions with alkynes and alkenesAn Efficient Synthesis of de novo Imidates via Aza-Claisen Rearrangements of N-Allyl Ynamides.Alkynylation of Thiols with Ethynylbenziodoxolone (EBX) Reagents: α- or β- π-Addition?Ynamides in ring forming transformations.A Convenient Synthesis of γ-Amino-Ynamides via Additions of Lithiated Ynamides to Aryl Imines. Observation of an Aza-Meyer-Schuster Rearrangement.Fast and highly chemoselective alkynylation of thiols with hypervalent iodine reagents enabled through a low energy barrier concerted mechanism.Synthesis of cyclopentenimines from N-allyl ynamides via a tandem aza-Claisen rearrangement-carbocyclization sequence.1,2-N-migration in a gold-catalysed synthesis of functionalised indenes by the 1,1-carboalkoxylation of ynamides.Why base-catalyzed isomerization of N-propargyl amides yields mostly allenamides rather than ynamides.N-allyl-N-sulfonyl ynamides as synthetic precursors to amidines and vinylogous amidines. An unexpected N-to-C 1,3-sulfonyl shift in nitrile synthesis.
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Q33597000-402837E8-C5D8-40B1-875B-A0D69DF426A6Q33884736-761C7A62-ADFD-43DD-A7F7-79A50D5B887DQ34458109-2F6D3116-AACD-4C8C-9E91-28232BA99AB2Q34710357-864630F5-3118-4EE8-866A-C031BC79188FQ34769604-A70FD4FC-04F7-43A4-8FD7-88D1CA3417DCQ35068977-5B1DAE2F-4332-491D-8114-A8096D7CA01AQ35733971-54D634B9-718F-4311-93CE-877BA7DCF2E3Q35962723-27017ECC-3C2C-4FD7-8C27-EC3D7351B660Q35966810-6C881F2F-0945-443C-949A-39AEB79F22B1Q36423837-85A96F4F-7441-4EDC-9D2A-E294AC363A6EQ36726199-5E75FDCB-016D-4316-B48B-97DF82D153FEQ37022106-83F51588-42C2-4507-8868-84CE27E9017CQ37320552-DBBDF2C2-9117-4C96-89B7-1CB5B44D9EDAQ37389340-3B723DFE-1B89-4451-97C0-1F3A850FE932Q37688438-8928EC01-2AB0-4238-9776-D69D3D20AA69Q37779491-628A5B10-35E7-49C3-9056-36C64F121EE5Q38155074-8D56BCFA-F630-441E-9F95-17B55B1BFB78Q38218769-91381B70-58EF-486C-8CF6-E090A9D360E0Q38366462-003B3BA3-7923-4E3B-AA76-22BD0C8577D6Q38974599-7D702A45-21C1-4477-B769-B20596A922C5Q39005944-C2B1F7A3-4E9C-4940-AF3E-9FB77C08C177Q39114187-79A33875-E7DB-4BF8-834A-CC4F1EC3C016Q39908226-7BF888C4-4EAB-46BF-AB0C-C617269F807FQ40213790-055DCDFE-3344-41FA-A4D4-331B43B0B8F7Q41087770-35ED5B0B-0759-47C3-B0D3-24BDC404758BQ41357111-631F59DB-20A6-4466-99F9-D61A6AB106DAQ41498294-3DC20B17-39EE-4171-AF73-9FEE4BDED94CQ41790857-0F21946B-0AB7-462E-B50D-CAAF326E10A7Q41825728-1EE4BD2B-5419-4734-ACE1-DC9ABBEA1A89Q41833646-78C55C69-477E-4119-AB96-D6D6BBE32450Q41856941-2368F11B-FAA1-4595-8CD8-678CD37E8572Q41877928-2ADF4663-81FD-455D-944D-970F7BA518F8Q41893377-D3F7E07C-ABA0-4594-B101-C2AC2DF934A0Q42003436-057D2FB5-7D8F-4A84-967D-02E8D597089FQ42096612-00523797-B176-4962-B9B2-55692216E1B8Q42134049-BA3B52A9-48A2-4F30-AEED-4548469E6CC6Q42156714-1C33AA95-E360-450F-B5AF-C0DAA3451802Q42186555-90D85538-48FA-45AF-AD83-58562D8E2F34Q42228430-52502F44-16EC-4643-886B-8ACEC6D1A429Q42243298-0ADF95CD-62FF-4986-8707-1E28A226F14C
P2860
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on April 2010
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Ynamides: versatile tools in organic synthesis.
@en
Ynamides: versatile tools in organic synthesis.
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type
label
Ynamides: versatile tools in organic synthesis.
@en
Ynamides: versatile tools in organic synthesis.
@nl
prefLabel
Ynamides: versatile tools in organic synthesis.
@en
Ynamides: versatile tools in organic synthesis.
@nl
P2093
P2860
P356
P1476
Ynamides: versatile tools in organic synthesis.
@en
P2093
Alexis Coste
Gwilherm Evano
Kévin Jouvin
P2860
P304
P356
10.1002/ANIE.200905817
P407
P577
2010-04-01T00:00:00Z