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Directing Group-Controlled Regioselectivity in an Enzymatic C–H Bond OxygenationRadicals: Reactive Intermediates with Translational PotentialNineteen-step total synthesis of (+)-phorbolInnate and Guided C–H Functionalization LogicTotal Synthesis of Propolisbenzofuran B.The chemical synthesis of tetrodoxin: an ongoing questTotal synthesis of (±)-sorocenol B employing nanoparticle catalysisTotal Synthesis of Verruculogen and Fumitremorgin A Enabled by Ligand-Controlled C-H BorylationSpiroacetal formation through telescoped cycloaddition and carbon-hydrogen bond functionalization: total synthesis of bistramide A.Tuning reactivity and site selectivity of simple arenes in C-H activation: ortho-arylation of anisoles via arene-metal π-complexation.Coordinating activation strategy for C(sp(3))-H/C(sp(3))-H cross-coupling to access β-aromatic α-amino acidsReversed reactivity of anilines with alkynes in the rhodium-catalysed C-H activation/carbonylation tandemTADDOL-based phosphorus(III)-ligands in enantioselective Pd(0)-catalysed C-H functionalisations.Combined C-H functionalization/Cope rearrangement with vinyl ethers as a surrogate for the vinylogous Mukaiyama aldol reaction.The combined C-H functionalization/Cope rearrangement: discovery and applications in organic synthesis.Aromatic cations from oxidative carbon-hydrogen bond cleavage in bimolecular carbon-carbon bond forming reactions.The facile construction of the phthalazin-1(2H)-one scaffold via copper-mediated C-H(sp(2))/C-H(sp) coupling under mild conditions.The palladium-catalyzed anti-Markovnikov hydroalkylation of allylic alcohol derivativesPd(II)-catalyzed enantioselective C-H activation/C-O bond formation: synthesis of chiral benzofuranones.Ru-Catalyzed C-H Arylation of Fluoroarenes with Aryl Halides.Scalable and sustainable electrochemical allylic C-H oxidation.Collaborative Total Synthesis: Routes to (±)-Hippolachnin A Enabled by Quadricyclane Cycloaddition and Late-Stage C-H OxidationBimolecular Coupling Reactions through Oxidatively Generated Aromatic Cations: Scope and Stereocontrol.Catalytic Reductive ortho-C-H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of DioxasilinesCatalytic migratory oxidative coupling of nitrones through an outer-sphere C(sp3)-H activation process.Transition-metal-catalyzed aminations and aziridinations of C-H and C=C bonds with iminoiodinanes.Chemical synthesis of the cardiotonic steroid glycosides and related natural products.Amide-directed tandem C-C/C-N bond formation through C-H activation.C-H activation: a complementary tool in the total synthesis of complex natural products.Unravelling the labyrinth of palladium-catalysed reactions involving isocyanides.Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate.Natural product synthesis in the age of scalability.Organometallic aspects of transition-metal catalysed regioselective C-H bond functionalisation of arenes and heteroarenes.Dimeric pyrrole-imidazole alkaloids: synthetic approaches and biosynthetic hypothesesCatalytic C-H bond functionalisation of purine and pyrimidine nucleosides: a synthetic and mechanistic perspective.Dehydrogenative coupling to enable the enantioselective total synthesis of (-)-simaomicin αRecent Trends in Copper-Catalyzed C-H Amination Routes to Biologically Important Nitrogen Scaffolds.Trends in applying C-H oxidation to the total synthesis of natural products.Applications of C-H functionalization logic to cyclobutane synthesis.Navigating the Chiral Pool in the Total Synthesis of Complex Terpene Natural Products.
P2860
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P2860
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 07 February 2011
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
C-H functionalization logic in total synthesis.
@en
C-H functionalization logic in total synthesis.
@nl
type
label
C-H functionalization logic in total synthesis.
@en
C-H functionalization logic in total synthesis.
@nl
prefLabel
C-H functionalization logic in total synthesis.
@en
C-H functionalization logic in total synthesis.
@nl
P356
P1476
C-H functionalization logic in total synthesis.
@en
P2093
Phil S Baran
Will R Gutekunst
P304
P356
10.1039/C0CS00182A
P577
2011-02-07T00:00:00Z