The chemistry of localized singlet 1,3-diradicals (biradicals): from putative intermediates to persistent species and unusual molecules with a π-single bonded character.

The chemistry of localized singlet 1,3-diradicals (biradicals): from putative intermediates to persistent species and unusual molecules with a π-single bonded character.

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http://www.wikidata.org/entity/Q37989308
Photochemical Approaches to Complex Chemotypes: Applications in Natural Product SynthesisSubstituent effect on the energy barrier for σ-bond formation from π-single-bonded species, singlet 2,2-dialkoxycyclopentane-1,3-diyls.A Puckered Singlet Cyclopentane-1,3-diyl: Detection of the Third Isomer in Homolysis.Thermally controlling the singlet-triplet energy gap of a diradical in the solid state.Studies in organic and physical photochemistry - an interdisciplinary approach.Kinetic stabilization and reactivity of π single-bonded species: effect of the alkoxy group on the lifetime of singlet 2,2-dialkoxy-1,3-diphenyloctahydropentalene-1,3-diyls.Solid-state photochemistry of crystalline pyrazolines: reliable generation and reactivity control of 1,3-biradicals and their potential for the green chemistry synthesis of substituted cyclopropanes.Direct Detection of a Chemical Equilibrium between a Localized Singlet Diradical and Its σ-Bonded Species by Time-Resolved UV/Vis and IR Spectroscopy.Stable heterocyclopentane-1,3-diyls.Tuning ground states of bis(triarylamine) dications: from a closed-shell singlet to a diradicaloid with an excited triplet state.An Isolable Diboron-Centered Diradical with a Triplet Ground State.Oligotriarylamines with a pyrene core: a multicenter strategy for enhancing radical cation and dication stability and tuning spin distribution.An integral-factorized implementation of the driven similarity renormalization group second-order multireference perturbation theory.Near-IR absorbing nickel(II) porphyrinoids prepared by regioselective insertion of silylenes into antiaromatic nickel(II) norcorrole.Theoretical study on the relationship between diradical character and second hyperpolarizabilities of four-membered-ring diradicals involving heavy main-group elements.Kekulé diradicaloids derived from a classical N-heterocyclic carbene.Nitrogen Analogues of Thiele’s Hydrocarbon
P2860

The chemistry of localized singlet 1,3-diradicals (biradicals): from putative intermediates to persistent species and unusual molecules with a π-single bonded character.

Item
http://www.wikidata.org/entity/Q37989308
description
article científic
@ca
article scientifique
@fr
articol științific
@ro
articolo scientifico
@it
artigo científico
@gl
artigo científico
@pt
artigo científico
@pt-br
artikel ilmiah
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artikull shkencor
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artículo científico
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name
The chemistry of localized sin ...... h a π-single bonded character.
@en
The chemistry of localized sin ...... h a π-single bonded character.
@nl
type
label
The chemistry of localized sin ...... h a π-single bonded character.
@en
The chemistry of localized sin ...... h a π-single bonded character.
@nl
prefLabel
The chemistry of localized sin ...... h a π-single bonded character.
@en
The chemistry of localized sin ...... h a π-single bonded character.
@nl
P1433
P1476
P2093
P2860
P304
P31
P356
P433
P478
P577
P698
P356
P1433
P1476
The chemistry of localized sin ...... h a π-single bonded character.
@en
P2093
P2860
P304
P31
P356
P433
P478
P577
P698