The chemistry of localized singlet 1,3-diradicals (biradicals): from putative intermediates to persistent species and unusual molecules with a π-single bonded character.
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Photochemical Approaches to Complex Chemotypes: Applications in Natural Product SynthesisSubstituent effect on the energy barrier for σ-bond formation from π-single-bonded species, singlet 2,2-dialkoxycyclopentane-1,3-diyls.A Puckered Singlet Cyclopentane-1,3-diyl: Detection of the Third Isomer in Homolysis.Thermally controlling the singlet-triplet energy gap of a diradical in the solid state.Studies in organic and physical photochemistry - an interdisciplinary approach.Kinetic stabilization and reactivity of π single-bonded species: effect of the alkoxy group on the lifetime of singlet 2,2-dialkoxy-1,3-diphenyloctahydropentalene-1,3-diyls.Solid-state photochemistry of crystalline pyrazolines: reliable generation and reactivity control of 1,3-biradicals and their potential for the green chemistry synthesis of substituted cyclopropanes.Direct Detection of a Chemical Equilibrium between a Localized Singlet Diradical and Its σ-Bonded Species by Time-Resolved UV/Vis and IR Spectroscopy.Stable heterocyclopentane-1,3-diyls.Tuning ground states of bis(triarylamine) dications: from a closed-shell singlet to a diradicaloid with an excited triplet state.An Isolable Diboron-Centered Diradical with a Triplet Ground State.Oligotriarylamines with a pyrene core: a multicenter strategy for enhancing radical cation and dication stability and tuning spin distribution.An integral-factorized implementation of the driven similarity renormalization group second-order multireference perturbation theory.Near-IR absorbing nickel(II) porphyrinoids prepared by regioselective insertion of silylenes into antiaromatic nickel(II) norcorrole.Theoretical study on the relationship between diradical character and second hyperpolarizabilities of four-membered-ring diradicals involving heavy main-group elements.Kekulé diradicaloids derived from a classical N-heterocyclic carbene.Nitrogen Analogues of Thiele’s Hydrocarbon
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P2860
The chemistry of localized singlet 1,3-diradicals (biradicals): from putative intermediates to persistent species and unusual molecules with a π-single bonded character.
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article científic
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article scientifique
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articol științific
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articolo scientifico
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artigo científico
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artigo científico
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artigo científico
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The chemistry of localized sin ...... h a π-single bonded character.
@en
The chemistry of localized sin ...... h a π-single bonded character.
@nl
type
label
The chemistry of localized sin ...... h a π-single bonded character.
@en
The chemistry of localized sin ...... h a π-single bonded character.
@nl
prefLabel
The chemistry of localized sin ...... h a π-single bonded character.
@en
The chemistry of localized sin ...... h a π-single bonded character.
@nl
P2093
P2860
P356
P1476
The chemistry of localized sin ...... h a π-single bonded character.
@en
P2093
Jianhuai Ye
Manabu Abe
Megumi Mishima
P2860
P304
P356
10.1039/C2CS00005A
P577
2012-02-29T00:00:00Z