The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.
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Intramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron ComplexesDesign and synthesis of a dinucleating ligand system with varying terminal donor functions that provides no bridging donor and its application to the synthesis of a series of Fe(III)-μ-O-Fe(III) complexes.Targeting iron metabolism in drug discovery and deliveryA high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups.Accelerated Oxygen Atom Transfer and C-H Bond Oxygenation by Remote Redox Changes in Fe3 Mn-Iodosobenzene Adducts.Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups.Isolation and structural and electronic characterization of salts of the decamethylferrocene dication.Structure of the key species in the enzymatic oxidation of methane to methanolTuning the Reactivity of Mononuclear Nonheme Manganese(IV)-Oxo Complexes by Triflic Acid.Synthesis and characterisation of a mesocyclic tripodal triamine ligand.Spectroscopic capture and reactivity of a low-spin cobalt(IV)-oxo complex stabilized by binding redox-inactive metal ions.Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization.Dichotomous hydrogen atom transfer vs proton-coupled electron transfer during activation of X-H bonds (X = C, N, O) by nonheme iron-oxo complexes of variable basicitySynthesis, characterization, and reactivity of cobalt(III)-oxygen complexes bearing a macrocyclic N-tetramethylated cyclam ligand.Indefinitely stable iron(IV) cage complexes formed in water by air oxidation.Enhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions.An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base.Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation.Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex.Applications of density functional theory to iron-containing molecules of bioinorganic interest.Metalloisoporphyrins: from synthesis to applications.Assessment of electronic structure methods for the determination of the ground spin states of Fe(ii), Fe(iii) and Fe(iv) complexes.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Oxygen activation by mononuclear nonheme iron dioxygenases involved in the degradation of aromatics.An Fe-N₂ Complex That Generates Hydrazine and Ammonia via Fe═NNH₂: Demonstrating a Hybrid Distal-to-Alternating Pathway for N₂ Reduction.Direct evidence of Fe(V) and Fe(IV) intermediates during reduction of Fe(VI) to Fe(III): a nuclear forward scattering of synchrotron radiation approach.Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate.Characterization and Reactivity Studies of a Terminal Copper-Nitrene Species.Iron(II) complexes supported by sulfonamido tripodal ligands: endogenous versus exogenous substrate oxidation.A highly oxidizing and isolable oxoruthenium(V) complex [Ru(V)(N4O)(O)]2+: electronic structure, redox properties, and oxidation reactions investigated by DFT calculations.Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size.Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand.Oxidation of ethane to ethanol by N2O in a metal-organic framework with coordinatively unsaturated iron(II) sites.A Mononuclear Nonheme Iron(V)-Imido Complex.The active site for the water oxidising anodic iridium oxide probed through in situ Raman spectroscopy.Nitrogen Fixation via a Terminal Fe(IV) Nitride.Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes.Stabilization of Low-Valent Iron(I) in a High-Valent Vanadium(V) Oxide Cluster.
P2860
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P2860
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.
description
article científic
@ca
article scientifique
@fr
articol științific
@ro
articolo scientifico
@it
artigo científico
@gl
artigo científico
@pt
artigo científico
@pt-br
artikel ilmiah
@id
artikull shkencor
@sq
artículo científico
@es
name
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.
@en
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.
@nl
type
label
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.
@en
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.
@nl
prefLabel
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.
@en
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.
@nl
P356
P1476
The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.
@en
P2093
Johannes Hohenberger
Kallol Ray
P2888
P356
10.1038/NCOMMS1718
P407
P577
2012-03-06T00:00:00Z