High-valent organometallic copper and palladium in catalysis.
about
Computational protein engineering: bridging the gap between rational design and laboratory evolution.Product-Derived Bimetallic Palladium Complex Catalyzes Direct Carbonylation of Sulfonylazides.Synthesis of ethoxy dibenzooxaphosphorin oxides through palladium-catalyzed C(sp(2))-H activation/C-O formation.Design, synthesis, and carbon-heteroatom coupling reactions of organometallic nickel(IV) complexes.Palladium-Catalyzed C8-Selective C-H Arylation of Quinoline N-Oxides: Insights into the Electronic, Steric and Solvation Effects on the Site-Selectivity by Mechanistic and DFT Computational Studies.Stable gold(III) catalysts by oxidative addition of a carbon-carbon bond.Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium SaltsPd(II)-catalyzed enantioselective C-H activation/C-O bond formation: synthesis of chiral benzofuranones.Palladium-catalyzed intermolecular aminoacetoxylation of alkenes and the influence of PhI(OAc)2 on aminopalladation stereoselectivityStereoselective alkoxycarbonylation of unactivated C(sp3)-H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis.Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines.Catalytic functionalization of C(sp2)-H and C(sp3)-H bonds by using bidentate directing groups.Synergy, compatibility, and innovation: merging Lewis acids with stereoselective enamine catalysis.Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV.Synthetic biology for the directed evolution of protein biocatalysts: navigating sequence space intelligently.Transition metal catalyzed meta-C-H functionalization of aromatic compounds.Carbon-Hydrogen (C-H) Bond Activation at Pd(IV): A Frontier in C-H Functionalization Catalysis.A Combined Experimental/Computational Study of the Mechanism of a Palladium-Catalyzed Bora-Negishi Reaction.Various difunctionalizations of acrylamide: an efficient approach to synthesize oxindoles.Mechanistic insights on the Pd-catalyzed addition of C-X bonds across alkynes - a combined experimental and computational study.Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry.Experimental and Theoretical Investigations of the Existence of Cu(II), Cu(III), and Cu(IV) in Copper Corrolato Complexes.Copper-catalyzed recycling of halogen activating groups via 1,3-halogen migration.Mild palladium-catalyzed C-H alkylation using potassium alkyltrifluoroborates in combination with MnF3Copper-catalyzed etherification of arene C-H bonds.Synthesis of Indole-2-carboxylate Derivatives via Palladium-Catalyzed Aerobic Amination of Aryl C-H Bonds.Cobalt-catalyzed, aminoquinoline-directed C(sp²)-H bond alkenylation by alkynes.Aerobic palladium-catalyzed dioxygenation of alkenes enabled by catalytic nitrite.Asymmetric chiral ligand-directed alkene dioxygenation.Copper-catalyzed CuAAC/intramolecular C-H arylation sequence: Synthesis of annulated 1,2,3-triazoles.Pd-catalyzed C-H fluorination with nucleophilic fluoride.Ruthenium(II)-catalysed remote C-H alkylations as a versatile platform to meta-decorated arenesNitrate as a Redox Co-Catalyst for the Aerobic Pd-Catalyzed Oxidation of Unactivated sp(3)-C-H Bonds.Ruthenium-catalyzed cascade C-H functionalization of phenylacetophenonesInvestigations into Transition Metal Catalyzed Arene Trifluoromethylation ReactionsA kinetico-mechanistic study on the C-H bond activation of primary benzylamines; cooperative and solid-state cyclopalladation on dimeric complexes.Cobalt-catalyzed direct carbonylation of aminoquinoline benzamides.Moving Metal-Mediated (18)F-Fluorination from Concept to Clinic.Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate.Palladium Catalyzed Aryl C-H Amination with O2 via In Situ Formation of Peroxide-Based Oxidant(s) from Dioxane.
P2860
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P2860
High-valent organometallic copper and palladium in catalysis.
description
article científic
@ca
article scientifique
@fr
articol științific
@ro
articolo scientifico
@it
artigo científico
@gl
artigo científico
@pt
artigo científico
@pt-br
artikel ilmiah
@id
artikull shkencor
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artículo científico
@es
name
High-valent organometallic copper and palladium in catalysis.
@en
type
label
High-valent organometallic copper and palladium in catalysis.
@en
prefLabel
High-valent organometallic copper and palladium in catalysis.
@en
P2860
P356
P1433
P1476
High-valent organometallic copper and palladium in catalysis.
@en
P2093
Amanda J Hickman
P2860
P2888
P304
P356
10.1038/NATURE11008
P407
P50
P577
2012-04-11T00:00:00Z