Does covalency increase or decrease across the actinide series? Implications for minor actinide partitioning.
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The role of the 5f valence orbitals of early actinides in chemical bondingSynthesis and characterization of an f-block terminal parent imido [U═NH] complex: a masked uranium(IV) nitride.Emergence of californium as the second transitional element in the actinide series.Evidence for 5d-σ and 5d-π covalency in lanthanide sesquioxides from oxygen K-edge X-ray absorption spectroscopy.Recent developments in actinide-ligand multiple bonding.4,4'-Di-tert-butyl-6-(1H-tetrazol-5-yl)-2,2'-bipyridine: modification of a highly selective N-donor ligand for the separation of trivalent actinides from lanthanides.New vistas in the molecular chemistry of thorium: low oxidation state complexes.Ligand size dependence of U-N and U-O bond character in a series of uranyl hexaphyrin complexes: quantum chemical simulation and density based analysis.Computational study of An-X bonding (An = Th, U; X = p-block-based ligands) in pyrrolic macrocycle-supported complexes from the quantum theory of atoms in molecules and bond energy decomposition analysis.Directed evolution of the periodic table: probing the electronic structure of late actinides.The roles of 4f- and 5f-orbitals in bonding: a magnetochemical, crystal field, density functional theory, and multi-reference wavefunction study.Covalency hinders AnO2(H2O)(+)→ AnO(OH)2(+) isomerisation (An = Pa-Pu).The selectivity of diglycolamide (TODGA) and bis-triazine-bipyridine (BTBP) ligands in actinide/lanthanide complexation and solvent extraction separation - a theoretical approach.Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding.Hydrophilic sulfonated bis-1,2,4-triazine ligands are highly effective reagents for separating actinides(iii) from lanthanides(iii) via selective formation of aqueous actinide complexes.Unusual structure, bonding and properties in a californium borate.Crown ether complexes of actinyls: a computational assessment of AnO2(15-crown-5)2+ (An = U, Np, Pu, Am, Cm).On structure and bonding of lanthanoid trifluorides LnF3 (Ln = La to Lu).Thorium-ligand multiple bonds via reductive deprotection of a trityl group.Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy.Synthesis, structure and bonding of actinide disulphide dications in the gas phase.Metal-Ligand Multiple Bonding in Thorium Phosphorus and Thorium Arsenic Complexes.Paving the way for the synthesis of a series of divalent actinide complexes: a theoretical perspective.Synthesis of terminal uranium(IV) disulfido and diselenido compounds by activation of elemental sulfur and selenium.Enhanced free energy of extraction of Eu3+ and Am3+ ions towards diglycolamide appended calix[4]arene: insights from DFT-D3 and COSMO-RS solvation models.Seventeen-Coordinate Actinide Helium Complexes.Transuranic Computational Chemistry.An example of unusual pyridine donor Schiff base uranyl (UO22+) complexes.Solid-State Structure of Tris-Cyclopentadienide Uranium(III) and Plutonium(III).The shortest Th-Th distance from a new type of quadruple bond.Protactinium and the intersection of actinide and transition metal chemistry.Variable photon energy photoelectron spectroscopy of tris-cyclopentadienyl lanthanides.A Very Short Uranium(IV)-Rhodium(I) Bond with Net Double-Dative Bonding Character.Quantification of f-element covalency through analysis of the electron density: insights from simulation.Ionic bonding of lanthanides, as influenced by d- and f-atomic orbitals, by core-shells and by relativity.Do QTAIM metrics correlate with the strength of heavy element-ligand bonds?Evidence for covalence in a N-donor complex of americium(III).Chemical structure and bonding in a thorium(iii)-aluminum heterobimetallic complex.Emergence of comparable covalency in isostructural cerium(iv)- and uranium(iv)-carbon multiple bonds.Diglycolamic acid-functionalized multiwalled carbon nanotubes as a highly efficient sorbent for f-block elements: experimental and theoretical investigations
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P2860
Does covalency increase or decrease across the actinide series? Implications for minor actinide partitioning.
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article científic
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article scientifique
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articol științific
@ro
articolo scientifico
@it
artigo científico
@gl
artigo científico
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artigo científico
@pt-br
artikel ilmiah
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artikull shkencor
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artículo científico
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name
Does covalency increase or dec ...... r minor actinide partitioning.
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type
label
Does covalency increase or dec ...... r minor actinide partitioning.
@en
prefLabel
Does covalency increase or dec ...... r minor actinide partitioning.
@en
P356
P1433
P1476
Does covalency increase or dec ...... r minor actinide partitioning.
@en
P2093
Nikolas Kaltsoyannis
P304
P356
10.1021/IC3006025
P407
P577
2012-06-05T00:00:00Z