Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu).
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A soluble phosphorus-centered Keggin polyoxoniobate with bicapping vanadyl groups.Molecular chalcoxides (chalcopolyoxometalates): a family of functional materials with emergent properties.Crown-shaped tungstogermanates as solvent-controlled dual systems in the formation of vesicle-like assemblies.The main progress over the past decade and future outlook on high-nuclear transition-metal substituted polyoxotungstates: from synthetic strategies, structural features to functional properties.Immobilization of polyoxometalates in crystalline solids for highly efficient heterogeneous catalysis.Unprecedented high-nuclear transition-metal-cluster-substituted heteropolyoxoniobates: synthesis by {V8 } ring insertion into the POM matrix and antitumor activities.Nona-copper(II)-containing 18-tungsto-8-arsenate(III) exhibits antitumor activity.Ethyl-enedi-ammonium sodium tetra-kis-[bis-(ethyl-enedi-amine-κ(2) N,N')(oxalato-κ(2) O (1),O (2))cobalt(III)] [penta-hydrogen di(phosphato-octa-deca-tungstate)] tetra-deca-hydrate.Following the Reaction of Heteroanions inside a {W18O56} Polyoxometalate Nanocage by NMR Spectroscopy and Mass Spectrometry.An organo-functionalized metal-oxide cluster, [VO6{(OCH2CH2)2N(CH2CH2OH)}6], with Anderson-like structure.Hexa-substituted polyoxometalates made of trivacant Dawson {P2W15} fragments and {Ni6} clusters under hydrothermal conditions.Highly soluble iron- and nickel-substituted decaniobates with tetramethylammonium countercations.Elimination-fusion self-assembly of a nanometer-scale 72-nucleus silver cluster caging a pair of [EuW10O36]9- polyoxometalates.Insight into the reactivity of in situ formed {(NbO2)3SiW9}: synthesis, structure, and solution properties of a trimeric polytungstosilicate trapping a {MnNb9} core.pH-Controlled assembly of two novel Dawson-sandwiched clusters involving the in situ reorganization of trivacant α-[P2W15O56](12-) into divacant α-[P2W16O57](8.).Sequential Synthesis of 3 d-3 d, 3 d-4 d, and 3 d-5 d Hybrid Polyoxometalates and Application to the Electrocatalytic Oxygen Reduction Reactions.A comparison study of aliphatic and aromatic structure directing agents influencing the crystal and electronic structures, and properties of iodoplumbate hybrids: water induced structure conversion and visible light photocatalytic properties.Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters.Alkoxides of Trivacant Lacunary Polyoxometalates.A wheel-shaped Dy(iii) single-molecule magnet supported by polyoxotungstates.Giant Hollow Heterometallic Polyoxoniobates with Sodalite-Type Lanthanide-Tungsten-Oxide Cages: Discrete Nanoclusters and Extended Frameworks.Anticancer Activity of Polyoxometalate-Bisphosphonate Complexes: Synthesis, Characterization, In Vitro and In Vivo Results.Inhibitory effects of different substituted transition metal-based krebs-type sandwich structures on human hepatocellular carcinoma cells.Dawson-Type Polyoxomolybdate Anions (P2 Mo18 O626- ) Captured by Ionic Liquid on Graphene Oxide as High-Capacity Anode Material for Lithium-Ion Batteries.The homometallic polyoxotungstate archetype {P4W24}.Self-Sorting of Heteroanions in the Assembly of Cross-Shaped Polyoxometalate Clusters.A novel naphthalenediimide-based lanthanide-organic framework with polyoxometalate templates exhibiting reversible photochromism.A series of inorganic-organic hybrid cadmium borates with novel Cd-centred [Cd@B14O20(OH)6](2-) clusters.Polyoxometalate-based entangled coordination networks induced by an extended bis(triazole) ligand.A {Nb6 P2 W12 }-Based Hexameric Manganese Cluster with Single-Molecule Magnet Properties.Construction of polyoxometalates from dynamic lacunary polyoxotungstate building blocks and lanthanide linkers.Designed synthesis of a series of zwitterion-polyoxometalate hybrid materials for selective scavenging and photolysis of dyes.Assembly of cyanometalate-functionalized phosphotungstates with magnetic properties and bifunctional electrocatalytic activities.Hydrothermal combination of trilacunary Dawson phosphotungstates and hexanickel clusters: from an isolated cluster to a 3D framework.Unprecedented {Fe14 }/{Fe10 } Polyoxotungstate-Based Nanoclusters with Efficient Photocatalytic H2 Evolution Activity: Synthesis, Structure, Magnetism, and Electrochemistry.A multifunctional lanthanide metal-organic framework supported by Keggin type polyoxometalates.Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates.A series of Anderson-type polyoxometalate-based metal-organic complexes: their pH-dependent electrochemical behaviour, and as electrocatalysts and photocatalysts.Tetrazine chromophore-based metal-organic frameworks with unusual configurations: synthetic, structural, theoretical, fluorescent, and nonlinear optical studies.Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters.
P2860
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P2860
Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu).
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article científic
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article scientifique
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articol științific
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articolo scientifico
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artigo científico
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artigo científico
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artigo científico
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artikel ilmiah
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artikull shkencor
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artículo científico
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name
Recent advances in paramagneti ...... tes (TM = Mn, Fe, Co, Ni, Cu).
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type
label
Recent advances in paramagneti ...... tes (TM = Mn, Fe, Co, Ni, Cu).
@en
prefLabel
Recent advances in paramagneti ...... tes (TM = Mn, Fe, Co, Ni, Cu).
@en
P2860
P356
P1476
Recent advances in paramagnetic-TM-substituted polyoxometalates (TM = Mn, Fe, Co, Ni, Cu)
@en
P2093
Guo-Yu Yang
P2860
P304
P356
10.1039/C2CS35133A
P577
2012-09-04T00:00:00Z