Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks.
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Persistent Dialkylsilanone Generated by Dehydrobromination of Dialkylbromosilanol.Synthetic chemistry with nitrous oxide.An Isolable Silicon Dicarbonate Complex from Carbon Dioxide Activation with a Silylone.[4-tBu-2,6-{P(O)(OiPr)2}2C6H2SnL]+: an NHC-stabilized organotin(II) cation and related derivatives.Stable Four-Coordinate Guanidinatosilicon(IV) Complexes with SiN3El Skeletons (El = S, Se, Te) and Si=El Double Bonds.Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene.Synthesis, structure and a nucleophilic coordination reaction of Germanetellurones.Synthesis of a Metallo-Iminosilane via a Silanone-Metal π-Complex.From an Isolable Acyclic Phosphinosilylene Adduct to Donor-Stabilized Si=E Compounds (E=O, S, Se).Reactivity of an amidinato silylene and germylene toward germanium(ii), tin(ii) and lead(ii) halides.An Intramolecular Silylene Borane Capable of Facile Activation of Small Molecules, Including Metal-Free Dehydrogenation of Water.Cyclic (Amino)(Phosphonium Bora-Ylide)Silanone: A Remarkable Room-Temperature-Persistent Silanone.One-Electron Oxidation of a Disilicon(0) Compound: An Experimental and Theoretical Study of [Si2](+) Trapped by N-Heterocyclic Carbenes.Isolation of a Cyclic (Alkyl)(amino)germylene.A Stable Monomeric SiO2 Complex with Donor-Acceptor Ligands.Synthesis and DFT Study of a Diphenylsilanone-Bridged Dimolybdenum Complex.Silicon-oxygen double bonds: a stable silanone with a trigonal-planar coordinated silicon center.NHC-stabilized silagermenylidene: a heavier analogue of vinylidene.A Stable Silanone with a Three-Coordinate Silicon Atom: A Century-Long Wait is Over
P2860
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P2860
Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks.
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article científic
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article scientifique
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articol științific
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articolo scientifico
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artigo científico
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artigo científico
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artigo científico
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artikel ilmiah
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artículo científico
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name
Chemical tricks to stabilize s ...... s to isolable building blocks.
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type
label
Chemical tricks to stabilize s ...... s to isolable building blocks.
@en
prefLabel
Chemical tricks to stabilize s ...... s to isolable building blocks.
@en
P2860
P356
P1476
Chemical tricks to stabilize s ...... s to isolable building blocks.
@en
P2093
Shenglai Yao
P2860
P304
P356
10.1002/ANIE.201209766
P407
P577
2013-03-01T00:00:00Z