Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.
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An efficient method for the preparation of styrene derivatives via Rh(III)-catalyzed direct C-H vinylation.Mechanistic and Kinetic Studies of the Direct Alkylation of Benzylic Amines: A Formal C(sp(3))-H Activation Proceeds Actually via a C(sp(2))-H Activation Pathway.The synthesis and reactivity of 16-electron half-sandwich iridium complexes bearing a carboranylthioamide ligand.Computational Investigation of the Role Played by Rhodium(V) in the Rhodium(III)-Catalyzed ortho-Bromination of Arenes.Comparative Study of Bifunctional Mononuclear and Dinuclear Amidoiridium Complexes with Chiral C-N Chelating Ligands for the Asymmetric Transfer Hydrogenation of Ketones.Cp*Co(IPr): synthesis and reactivity of an unsaturated Co(i) complex.Controllable Coordination Self-Assembly Based on Flexible Tripodal Ligands: From Finite Metallocages to Infinite Polycatenanes Step by Step.A new copper species based on an azo-compound utilized as a homogeneous catalyst for water oxidation.Protic NNN and NCN Pincer-Type Ruthenium Complexes Featuring (Trifluoromethyl)pyrazole Arms: Synthesis and Application to Catalytic Hydrogen Evolution from Formic Acid.Facile Synthesis of Size-Tunable Functional Polyimidazolium Macrocycles through a Photochemical Closing Strategy.Efficient synthesis of carborane azo derivatives and their reactivity.B-H functionalization of the monocarba-closo-dodecaborate anion by rhodium and iridium catalysis.Sequential Reactions of Alkynes on an Iridium(III) Single Site.Fusing Carborane Carboxylic Acids with Alkynes: 3D Analogues of Isocoumarins via Regioselective B-H Activation.Construction of Alkynylplatinum(II) Bzimpy-Functionalized Metallacycles and Their Hierarchical Self-Assembly Behavior in Solution Promoted by Pt⋅⋅⋅Pt and π-π Interactions.Recent advances in the construction of fluorescent metallocycles and metallocages via coordination-driven self-assembly.Water oxidation catalysts and pH sensors based on azo-conjugated iridium/rhodium motifs.Iridacycles for hydrogenation and dehydrogenation reactions.The C-H activation/1,3-diyne strategy: highly selective direct synthesis of diverse bisheterocycles by Rh(III) catalysis.Construction of tetranuclear metallacycles based on half-sandwich Ir, Rh fragments and pyridyl-substituted ligands with different coordinate vectors.Ir(III)-Catalyzed Carbocarbation of Alkynes through Undirected Double C-H Bond Activation of Anisoles.Synthesis and full characterization of an iridium B-H activation intermediate of the monocarba-closo-dodecaborate anion.Enantiopure Ferrocene-Based Planar-Chiral Iridacycles: Stereospecific Control of Iridium-Centred Chirality.Intermolecular C-H activation with an Ir-METAMORPhos piano-stool complex--multiple reaction steps at a reactive ligand.Dihydrogen Catalysis of the Reversible Formation and Cleavage of CH and NH Bonds of Aminopyridinate Ligands Bound to (η5-C5Me5)IrIIIReactivity of Cationic Agostic and Carbene Structures Derived from Platinum(II) MetallacyclesRhodium-catalyzed ortho-heteroarylation of phenols: directing group-enabled switching of the electronic bias for heteroaromatic coupling partnerRuthenium-Catalyzed Oxidative Coupling of Primary Amines with Internal Alkynes through CH Bond Activation: Scope and Mechanistic StudiesIridium(III)-Catalyzed Benzylic Amine Directed CH Sulfonamidation of Arenes with Sulfonyl AzidesA comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistryCoordination-driven self-assembly vs dynamic covalent chemistry: versatile methods for the synthesis of molecular metallarectangles
P2860
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P2860
Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.
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Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.
@en
type
label
Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.
@en
prefLabel
Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.
@en
P2860
P356
P1476
Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.
@en
P2093
Guo-Xin Jin
Ying-Feng Han
P2860
P304
P356
10.1039/C3CS60343A
P577
2014-02-05T00:00:00Z