Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox.
about
Gold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition.Exploring the gold mine: [Au]-catalysed transformations of enynals, enynones and enynols.New Approaches to the Synthesis of Metal Carbenes.Recent Advances in Gold-Catalyzed Intermolecular Aryl C-H Functionalization.Recent progress towards gold-catalyzed synthesis of N-containing tricyclic compounds based on ynamides.Gold-catalyzed Intermolecular Oxidations of 2-Ketonyl-1-ethynyl Benzenes with N-Hydoxyanilines to Yield 2-Aminoindenones via Gold Carbene Intermediates.Divergent C-H Insertion-Cyclization Cascades of N-Allyl Ynamides.Gold(I)-catalyzed dearomative Rautenstrauch rearrangement: enantioselective access to cyclopenta[b]indoles.Stereoselective cis-Vinylcyclopropanation via a Gold(I)-Catalyzed Retro-Buchner Reaction under Mild Conditions.Pyridylidene ligand facilitates gold-catalyzed oxidative C-H arylation of heterocycles.α-Diazo oxime ethers for N-heterocycle synthesis.Rhenium-Catalyzed Construction of Polycyclic Hydrocarbon Frameworks by a Unique Cyclization of 1,n-Diynes Initiated by 1,1-Difunctionalization with Carbon Nucleophiles.Formation of Oxazoles from Elusive Gold(I) α-Oxocarbenes: A Mechanistic Study.Palladium-catalyzed carbene/alkyne metathesis with enynones as carbene precursors: synthesis of fused polyheterocycles.Synthesis of α-keto imides through copper-catalyzed oxidation of N-sulfonyl ynamides.Recent advances in transition-metal-catalyzed reactions of alkynes with isoxazoles.Gold-catalyzed para-selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds.Direct and Autocatalytic Reductive Elimination from Gold Complexes ([(Ph3 P)Au(Ar)(CF3 )(X)], X=F, Cl, Br, I): The Key Role of Halide Ligands.Dual gold/photoredox-catalyzed bis-arylative cyclization of chiral homopropargyl sulfonamides with diazonium salts: rapid access to enantioenriched 2,3-dihydropyrroles.A Nucleophilic Gold(III) Carbene Complex.Rapid access to cyclopentadiene derivatives through gold-catalyzed cycloisomerization of ynamides with cyclopropenes by preferential activation of alkenes over alkynes.Isolation of a Reactive Tricoordinate α-Oxo Gold Carbene Complex.Gold Catalysis for Heterocyclic Chemistry: A Representative Case Study on Pyrone Natural Products.Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction.Gold-catalyzed highly regio- and enantioselective vinylcarbene insertion into O-H bonds of 2-pyridones.Experimental Evaluation of (L)Au Electron-Donor Ability in Cationic Gold Carbene Complexes.Divergent synthesis from reactions of 2-trifluoromethyl-1,3-conjugated enynes with N-acetylated 2-aminomalonates.Brønsted Acid Catalyzed Oxygenative Bimolecular Friedel-Crafts-type Coupling of Ynamides.Brønsted acid-catalyzed α-halogenation of ynamides from halogenated solvents and pyridine-N-oxides.Highly para-Selective C-H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl α-Aryl-α-Diazoesters.Synthesis of 3-azabicyclo[3.1.0]hexane derivatives via palladium-catalyzed cyclopropanation of maleimides with N-tosylhydrazones: practical and facile access to CP-866,087.Gold-catalysed facile access to indene scaffolds via sequential C-H functionalization and 5-endo-dig carbocyclization.Gold-Catalyzed Sequential Cyclization of 1-En-3,9-Diyne Esters to Partially Hydrogenated 3H-Dicyclopenta[a,b]naphthalenes.Gold/silver-catalyzed controllable regioselective vinylcarbene insertion into O-H bonds.Highly Site Selective Formal [5+2] and [4+2] Annulations of Isoxazoles with Heterosubstituted Alkynes by Platinum Catalysis: Rapid Access to Functionalized 1,3-Oxazepines and 2,5-Dihydropyridines.Highly enantioselective synthesis of spirocyclopropyloxindoles via a Rh(ii)-catalyzed asymmetric cyclopropanation reaction.Enantioselective Intramolecular C-H Insertion of Donor and Donor/Donor Carbenes by a Nondiazo Approach.Gold-Catalyzed Tandem Cycloisomerization-Halogenation of Chiral Homopropargyl Sulfonamides.Dual catalysis for the redox annulation of nitroalkynes with indoles: enantioselective construction of indolin-3-ones bearing quaternary stereocenters.A gold-catalyzed 1,2-acyloxy migration/intramolecular cyclopropanation/ring enlargement cascade: syntheses of medium-sized heterocycles.
P2860
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P2860
Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox.
description
2015 nî lūn-bûn
@nan
2015年の論文
@ja
2015年学术文章
@wuu
2015年学术文章
@zh-cn
2015年学术文章
@zh-hans
2015年学术文章
@zh-my
2015年学术文章
@zh-sg
2015年學術文章
@yue
2015年學術文章
@zh
2015年學術文章
@zh-hant
name
Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox.
@en
type
label
Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox.
@en
prefLabel
Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox.
@en
P356
P1476
Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox.
@en
P2093
Deyun Qian
Junliang Zhang
P304
P356
10.1039/C4CS00304G
P577
2015-02-01T00:00:00Z