To rebound or dissociate? This is the mechanistic question in C-H hydroxylation by heme and nonheme metal-oxo complexes.
about
Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation.Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex.Oriented electric fields as future smart reagents in chemistry.Spectroscopic analyses of 2-oxoglutarate-dependent oxygenases: TauD as a case study.Structure and spin state of nonheme FeIVO complexes depending on temperature: predictive insights from DFT calculations and experiments.A Mononuclear Nonheme Iron(V)-Imido Complex.Direct Observation of Oxygen Rebound with an Iron-Hydroxide Complex.Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units.Equatorial Ligand Perturbations Influence the Reactivity of Manganese(IV)-Oxo Complexes.Ethane C-H bond activation on the Fe(iv)-oxo species in a Zn-based cluster of metal-organic frameworks: a density functional theory study.Mononuclear Nonheme High-Spin (S=2) versus Intermediate-Spin (S=1) Iron(IV)-Oxo Complexes in Oxidation Reactions.Frontier Molecular Orbital Contributions to Chlorination versus Hydroxylation Selectivity in the Non-Heme Iron Halogenase SyrB2.Selective photocatalytic hydroxylation and epoxidation reactions by an iron complex using water as the oxygen source.Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins.Reactivity of Copper(III)-Oxo Complexes in the Gas Phase.Two-State Reactivity of Histone Demethylases Containing Jumonji-C Active Sites: Different Mechanisms for Different Methylation Degrees.Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex.A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies.High-Valent Iron-Oxo and -Nitrido Complexes: Bonding and Reactivity
P2860
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P2860
To rebound or dissociate? This is the mechanistic question in C-H hydroxylation by heme and nonheme metal-oxo complexes.
description
2015 nî lūn-bûn
@nan
2015年の論文
@ja
2015年論文
@yue
2015年論文
@zh-hant
2015年論文
@zh-hk
2015年論文
@zh-mo
2015年論文
@zh-tw
2015年论文
@wuu
2015年论文
@zh
2015年论文
@zh-cn
name
To rebound or dissociate? This ...... d nonheme metal-oxo complexes.
@en
type
label
To rebound or dissociate? This ...... d nonheme metal-oxo complexes.
@en
prefLabel
To rebound or dissociate? This ...... d nonheme metal-oxo complexes.
@en
P2860
P356
P1476
To rebound or dissociate? This ...... nd nonheme metal-oxo complexes
@en
P2093
Hajime Hirao
Sason Shaik
P2860
P304
P356
10.1039/C5CS00566C
P577
2016-03-01T00:00:00Z