about
Synthetic models of the active site of catechol oxidase: mechanistic studiesControlled copper-mediated chlorination of phenol rings under mild conditions.Bio-mimicking galactose oxidase and hemocyanin, two dioxygen-processing copper proteins.Anion binding involving pi-acidic heteroaromatic rings.Design of magnetic coordination complexes for quantum computing.Putting anion-π interactions into perspective.DNA cleavage and binding selectivity of a heterodinuclear Pt-Cu(3-Clip-Phen) complex.The effect of potential supramolecular-bond promoters on the DNA-interacting abilities of copper-terpyridine compounds.Histidine-Rich Oligopeptides To Lessen Copper-Mediated Amyloid-β Toxicity.Photoswitching the cytotoxic properties of platinum(II) compounds.Iron spin-crossover compounds: from fundamental studies to practical applications.Structure, cytotoxicity, and DNA-cleavage properties of the complex [Cu(II)(pbt)Br2].Platinated copper(3-clip-phen) complexes as effective DNA-cleaving and cytotoxic agents.New approach for the preparation of efficient DNA cleaving agents: ditopic copper-platinum complexes based on 3-Clip-Phen and cisplatin.The square-planar cytotoxic [Cu(II)(pyrimol)Cl] complex acts as an efficient DNA cleaver without reductant.An unusual open cubane structure in a mu(1,1)-azido- and alkoxo-bridged tetranuclear copper(II) complex, [Cu4L2(mu(1,1)-N3)2].5H2O (H3L = N,N'-(2-Hydroxylpropane-1,3-diyl)bis-salicylideneimine).Magnetic properties of dysprosium cubanes dictated by the M-O-M angles of the [Dy4(mu3-OH)4] core.Praseodymium(III)-based bis-metallacalix[4]arene with host-guest behaviour.Supramolecular assembly of Mg(II) complexes directed by associative lone pair-pi/pi-pi/pi-anion-pi/pi-lone pair interactions.A promising new route towards single-molecule magnets based on the oxalate ligand.Discrete tetrairon(III) cluster exhibiting a square-planar Fe4(mu4-O) core: structural and magnetic properties.Manganese(III)-mediated cyclodimerization of a hydrazinyl derivative generating an unprecedented 1,2,3,5,6-substituted leuco-verdazyl ring.Activation of the C-H bond by electrophilic attack: theoretical study of the reaction mechanism of the aerobic oxidation of alcohols to aldehydes by the Cu(bipy)(2+)/2,2,6,6-tetramethylpiperidinyl-1-oxy cocatalyst system.A mixed-valent pentanuclear Cu(II)(4)Cu(I) compound containing a radical-anion ligand.Designed topology and site-selective metal composition in tetranuclear [MM'...M'M] linear complexes.Robust recognition of malonate and 2-amino-4-picolinium in conjunction with M(II) as a triad (M = Ni/Co/Mn): role of this highly stable hydrogen-bonded motif in driving supramolecular self-assembly.An unprecedented 1D ladder coordination polymer based on a pentanuclear copper(II) 2,4,6-tris(dipyridin-2-ylamino)-1,3,5-triazine building block.Century-known copper salt Cu(OAc)(OMe) proven to be a unique magnetic lattice composed of tetranuclear copper(II) species with a rare binding mode of the acetate anion.Synthesis, crystal structures, magnetic properties and catecholase activity of double phenoxido-bridged penta-coordinated dinuclear nickel(II) complexes derived from reduced Schiff-base ligands: mechanistic inference of catecholase activity.Copper(II)-catalysed aerobic oxidation of primary alcohols to aldehydes.Custom-fit ruthenium(II) metallopeptides: a new twist to DNA binding with coordination compounds.Bis[bis(pyrimidin-2-yl-kappaN)amine](dicyanamido-kappaN1)(trifluoromethanesulfonato-kappaO)copper(II) ethanol hemisolvate forms a hydrogen-bonded chain.Complexes of a novel multinucleating poly-beta-diketonate ligand.Solution-stable trinuclear zinc(II) cluster from 4-methyl-2-N-(2-pyridylmethylene)aminophenol (HPyrimol).Aggregation of [Cu(II)4] building blocks into [Cu(II)8] clusters or a [Cu(II)4]infinity chain through subtle chemical control.Water-chloride and water-bromide hydrogen-bonded networks: influence of the nature of the halide ions on the stability of the supramolecular assemblies.Stabilisation of a very short Cu-F bond within the protected cavity of a copper(ii) compound from a tris(2-aminoethyl)amine derivative.Magnetic coupling between copper(II) ions mediated by hydrogen-bonded (neutral) water molecules.Selective, catalytic aerobic oxidation of alcohols using CuBr(2) and bifunctional triazine-based ligands containing both a bipyridine and a TEMPO group.Two-step spin-transition iron(III) compound with a wide [high spin-low spin] plateau.
P50
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P50
description
hulumtues
@sq
researcher
@en
wetenschapper
@nl
հետազոտող
@hy
name
Patrick Gamez
@ast
Patrick Gamez
@en
Patrick Gamez
@es
Patrick Gamez
@nl
Patrick Gamez
@sl
type
label
Patrick Gamez
@ast
Patrick Gamez
@en
Patrick Gamez
@es
Patrick Gamez
@nl
Patrick Gamez
@sl
prefLabel
Patrick Gamez
@ast
Patrick Gamez
@en
Patrick Gamez
@es
Patrick Gamez
@nl
Patrick Gamez
@sl
P1053
B-3610-2012
P106
P21
P31
P3829
P496
0000-0003-2602-9525