A divergent mechanistic course of Pd(0)-catalyzed aza-Claisen rearrangement and aza-Rautenstrauch-type cyclization of N-allyl ynamides.
about
Ynamides: a modern functional group for the new millennium.Unexpected catalytic reactions of silyl-protected enol diazoacetates with nitrile oxides that form 5-arylaminofuran-2(3H)-one-4-carboxylates.The thriving chemistry of ketenimines.Introducing a new class of N-phosphoryl ynamides via Cu(I)-catalyzed amidations of alkynyl bromides.Divergent C-H Insertion-Cyclization Cascades of N-Allyl Ynamides.A serendipitous discovery: nickel catalyst for the cycloaddition of diynes with unactivated nitriles.An Efficient Synthesis of de novo Imidates via Aza-Claisen Rearrangements of N-Allyl Ynamides.Rhodium-catalyzed intra- and intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkyne with concomitant 1,2-acyloxy migrationYnamides in ring forming transformations.A Convenient Synthesis of γ-Amino-Ynamides via Additions of Lithiated Ynamides to Aryl Imines. Observation of an Aza-Meyer-Schuster Rearrangement.Interception of a Rautenstrauch intermediate by alkynes for [5+2] cycloaddition: rhodium-catalyzed cycloisomerization of 3-acyloxy-4-ene-1,9-diynes to bicyclo[5.3.0]decatrienes.Synthesis of cyclopentenimines from N-allyl ynamides via a tandem aza-Claisen rearrangement-carbocyclization sequence.N-allyl-N-sulfonyl ynamides as synthetic precursors to amidines and vinylogous amidines. An unexpected N-to-C 1,3-sulfonyl shift in nitrile synthesis.Copper-catalyzed Ficini [2 + 2] cycloaddition of ynamides.An intramolecular [2 + 2] cycloaddition of ketenimines via palladium-catalyzed rearrangements of N-allyl-ynamides.Carbocyclization cascades of allyl ketenimines via aza-Claisen rearrangements of N-phosphoryl-N-allyl-ynamides.Ketenimines Generated from Ynamides: Versatile Building Blocks for Nitrogen-Containing Scaffolds.Nickel-catalyzed acetamidation and lactamization of arylboronic acids.
P2860
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P2860
A divergent mechanistic course of Pd(0)-catalyzed aza-Claisen rearrangement and aza-Rautenstrauch-type cyclization of N-allyl ynamides.
description
2010 nî lūn-bûn
@nan
2010年の論文
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2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
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2010年论文
@zh-cn
name
A divergent mechanistic course ...... clization of N-allyl ynamides.
@en
type
label
A divergent mechanistic course ...... clization of N-allyl ynamides.
@en
prefLabel
A divergent mechanistic course ...... clization of N-allyl ynamides.
@en
P2093
P2860
P356
P1433
P1476
A divergent mechanistic course ...... clization of N-allyl ynamides.
@en
P2093
Andrew G Lohse
Kyle A Dekorver
Richard P Hsung
P2860
P304
P356
10.1021/OL100446P
P407
P577
2010-04-01T00:00:00Z