Ligand-enabled γ-C-H olefination and carbonylation: construction of β-quaternary carbon centers.
about
Ligand-enabled meta-C-H activation using a transient mediator.General method for the synthesis of salicylic acids from phenols through palladium-catalyzed silanol-directed C-H carboxylationStereoselective alkoxycarbonylation of unactivated C(sp3)-H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis.A Simple and Versatile Amide Directing Group for C-H Functionalizations.N-Heterocyclic Carbene Ligand-Enabled C(sp(3))-H Arylation of Piperidine and Tetrahydropyran Derivatives.Palladium-Catalyzed Transformations of Alkyl C-H Bonds.Ligand-Enabled γ-C(sp(3))-H Olefination of Amines: En Route to PyrrolidinesLigand-Enabled Arylation of γ-C-H Bonds.γ,δ,ε-C(sp(3))-H Functionalization through Directed Radical H-Abstraction.Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes.Ligand-promoted alkylation of C(sp3)-H and C(sp2)-H bonds.Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and aminationLigand-Promoted C(sp(3) )-H Olefination en Route to Multi-functionalized Pyrazoles.Ligand-Enabled Pd(II)-Catalyzed Bromination and Iodination of C(sp3)-H Bonds.Highly Versatile β-C(sp3)-H Iodination of Ketones Using a Practical Auxiliary.Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.A general approach to intermolecular carbonylation of arene C-H bonds to ketones through catalytic aroyl triflate formation.Ligand-Enabled β-C-H Arylation of α-Amino Acids Without Installing Exogenous Directing Groups.A steric tethering approach enables palladium-catalysed C-H activation of primary amino alcohols.Selective Palladium(II)-Catalyzed Carbonylation of Methylene β-C-H Bonds in Aliphatic Amines.Copper-Catalyzed Bromination of C(sp3 )-H Bonds Distal to Functional Groups.Directed γ-C(sp3)-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis.C8-H bond activation vs. C2-H bond activation: from naphthyl amines to lactams.Pd/Cu-Catalyzed aerobic oxidative aromatic C-H bond activation/N-dealkylative carbonylation towards the synthesis of phenanthridinones.Palladium catalyzed direct aliphatic γC(sp3)-H alkenylation with alkenes and alkenyl iodides.Readily Removable Directing Group Assisted Chemo- and Regioselective C(sp(3))-H Activation by Palladium Catalysis.Ligand-Enabled γ-C(sp3)-H Activation of Ketones.γ-Functionalizations of Amines through Visible-Light-Mediated, Redox-Neutral C-C Bond Cleavage.Synthesis of quinolines via copper-catalyzed domino reactions of enaminones.Metal-free radical oxidative alkoxycarbonylation and imidation of alkanes.Copper-Catalyzed Alkoxycarbonylation of Alkanes with Alcohols.Oxalyl amide assisted palladium-catalyzed synthesis of pyrrolidones via carbonylation of γ-C(sp3)-H bonds of aliphatic amine substrates.
P2860
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P2860
Ligand-enabled γ-C-H olefination and carbonylation: construction of β-quaternary carbon centers.
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh
2014年學術文章
@zh-hant
name
Ligand-enabled γ-C-H olefinati ...... f β-quaternary carbon centers.
@en
type
label
Ligand-enabled γ-C-H olefinati ...... f β-quaternary carbon centers.
@en
prefLabel
Ligand-enabled γ-C-H olefinati ...... f β-quaternary carbon centers.
@en
P2093
P2860
P356
P1476
Ligand-enabled γ-C-H olefinati ...... f β-quaternary carbon centers.
@en
P2093
P2860
P304
P356
10.1021/JA501689J
P407
P50
P577
2014-03-28T00:00:00Z