Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes
about
Copper-, Silver-, and Gold-Catalyzed Migratory Cycloisomerizations Leading to Heterocyclic Five-Membered RingsGold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenesStable cyclic carbenes and related species beyond diaminocarbenes.Recent advances in the isolation and reactivity of organogold complexes.Intramolecular hydroamination of alkynic sulfonamides catalyzed by a gold-triethynylphosphine complex: Construction of azepine frameworks by 7-exo-dig cyclizationCharacterization of vinylgold intermediates: gold-mediated cyclization of acetylenic amides.Mechanistic Studies of Azaphilic versus Carbophilic Activation by Gold(I) in the Gold/Palladium Dual-Catalyzed Rearrangement of Alkenyl Vinyl AziridinesA Brief Survey of our Contribution to Stable Carbene Chemistry.Synthesis of a room-temperature-stable dimeric copper(I) hydride.Alkylgold complexes by the intramolecular aminoauration of unactivated alkenes.Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliumsA stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene.Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes.Gold-catalyzed annulations of 1-(2,3-butadienyl)-1H-indole derivatives.Gold carbene or carbenoid: is there a difference?β- and α-Hydride abstraction in Gold(I) alkyl complexes.Merging synthesis and enantioselective functionalization of indoles by a gold-catalyzed asymmetric cascade reaction.Pyridine-based dicarbene ligand: synthesis and structure of a bis-2-pyridylidene palladium complex.Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts.Synthesis and study of cationic, two-coordinate triphenylphosphine-gold-π complexes.Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine.Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine.On the Accessible Reaction Channels of Vinyl Gold(I) Species: π- and σ-Pathways.Intramolecular anti-Phosphinoauration of Alkynes: An FLP-Motivated Approach to Stable Aurated Phosphindolium Complexes.Unexpected migratory insertion reactions of M(alkyl)2 (M=Zn, Cd) and diamidocarbenes.Mechanistic study of gold(I)-catalyzed hydroamination of alkynes: outer or inner sphere mechanism?Gold(I)-Catalyzed N-Desulfonylative Amination versus N-to-O 1,5-Sulfonyl Migration: A Versatile Approach to 1-Azabicycloalkanes.Flexible and practical synthesis of 3-oxyindoles through gold-catalyzed intermolecular oxidation of o-ethynylanilines.σ-π Continuum in Indole-Palladium(II) Complexes.Silver-Catalyzed Amidiniumation of Alkynes: Isolation of a Silver Intermediate, Synthesis of Enamine Amido Carbene Precursors, and an Unprecedented Umpolung of Propiolamide.A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums.Visible-Light-Promoted AuI to AuIII Oxidation in Triazol-5-ylidene Complexes.Rhodium-catalyzed intramolecular cyclization of naphthol- or phenol-linked 1,6-enynes through the cleavage and formation of sp2 C-O bonds.Syntheses, crystal structures, reactivity, and photochemistry of gold(III) bromides bearing N-heterocyclic carbenes.One-pot gold-catalyzed synthesis of azepino[1,2-a]indoles.Dual-role of PtCl2 catalysis in the intramolecular cyclization of (hetero)aryl-allenes for the facile construction of substituted 2,3-dihydropyrroles and polyheterocyclic skeletons.Synthesis of 3-((trifluoromethyl)thio)indoles via a reaction of 2-alkynylaniline with trifluoromethanesulfanylamide.A Cyclization-Rearrangement Cascade for the Synthesis of Structurally Complex Chiral Gold(I)-Aminocarbene ComplexesGold-Catalyzed Cascade Cyclization of 2-Alkynyl-N-Propargylanilines by Rearrangement of a Propargyl Group
P2860
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P2860
Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Serendipitous discovery of the ...... and methylamination of alkynes
@en
type
label
Serendipitous discovery of the ...... and methylamination of alkynes
@en
prefLabel
Serendipitous discovery of the ...... and methylamination of alkynes
@en
P2093
P2860
P356
P1476
Serendipitous discovery of the ...... and methylamination of alkynes
@en
P2093
Bruno Donnadieu
Xiaoming Zeng
P2860
P304
P356
10.1002/ANIE.200905341
P407
P50
P577
2010-01-01T00:00:00Z