Pyrrolidine and piperidine formation via copper(II) carboxylate-promoted intramolecular carboamination of unactivated olefins: diastereoselectivity and mechanism
about
Intramolecular aminocyanation of alkenes by N-CN bond cleavage.The enantioselective intramolecular aminative functionalization of unactivated alkenes, dienes, allenes and alkynes for the synthesis of chiral nitrogen heterocyclesDiastereo- and enantioselective copper-catalyzed intramolecular carboamination of alkenes for the synthesis of hexahydro-1H-benz[f]indoles.Evolution of copper(II) as a new alkene amination promoter and catalyst.6-Azabicyclo[3.2.1]octanes Via Copper-Catalyzed Enantioselective Alkene Carboamination.Copper-promoted and copper-catalyzed intermolecular alkene diaminationCopper-catalyzed enantioselective intramolecular alkene amination/intermolecular Heck-type coupling cascade.Evidence for alkene cis-aminocupration, an aminooxygenation case study: kinetics, EPR spectroscopy, and DFT calculations.Catalytic enantioselective alkene aminohalogenation/cyclization involving atom transfer.Copper-catalyzed intramolecular alkene carboetherification: synthesis of fused-ring and bridged-ring tetrahydrofurans.Chiral Indoline Synthesis Via Enantioselective Intramolecular Copper-Catalyzed Alkene Hydroamination.Copper-catalyzed aminooxygenation of styrenes with N-fluorobenzenesulfonimide and N-hydroxyphthalimide derivatives.Copper(II) carboxylate promoted intramolecular diamination of terminal alkenes: improved reaction conditions and expanded substrate scope.Mechanistic analysis and optimization of the copper-catalyzed enantioselective intramolecular alkene aminooxygenationLow temperature organocopper-mediated two-component cross coupling/cycloisomerization approach toward N-fused heterocycles.Total synthesis of (S)-(+)-tylophorine via enantioselective intramolecular alkene carboamination.Copper catalyzed enantioselective intramolecular aminooxygenation of alkenesDiastereoselective pyrrolidine synthesis via copper promoted intramolecular aminooxygenation of alkenes: formal synthesis of (+)-monomorine.ORGANOCOPPER-MEDIATED TWO-COMPONENT SN2'-SUBSTITUTION CASCADE TOWARDS N-FUSED HETEROCYCLES.Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process.Synthesis of substituted tetrahydroindoloisoquinoline derivatives via intramolecular Pd-catalyzed alkene carboamination reactionsCopper(II) carboxylate-promoted intramolecular carboamination of alkenes for the synthesis of polycyclic lactams.Copper(II)-catalyzed enantioselective intramolecular carboamination of alkenes.Palladium-catalyzed alkene carboamination reactions for the synthesis of substituted piperazines.Palladium-Catalyzed Alkene Carboamination Reactions of Electron-Poor Nitrogen NucleophilesMild conditions for Pd-catalyzed carboamination of N-protected hex-4-enylamines and 1-, 3-, and 4-substituted pent-4-enylamines. Scope, limitations, and mechanism of pyrrolidine formation.Copper(II)-Catalyzed Aminooxygenation and Carboamination of N-Aryl-2-allylanilines.Mechanistic studies of Wacker-type intramolecular aerobic oxidative amination of alkenes catalyzed by Pd(OAc)2/pyridine.Intermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compoundsA concise asymmetric synthesis of cis-2,6-disubstituted N-aryl piperazines via Pd-catalyzed carboamination reactions.Efficient copper-catalyzed direct intramolecular aminotrifluoromethylation of unactivated alkenes with diverse nitrogen-based nucleophiles.Copper-Catalyzed Intramolecular Oxidative Amination of Unactivated Internal Alkenes.Stereoselective and Regioselective Synthesis of Heterocycles via Copper-Catalyzed Additions of Amine Derivatives and Alcohols to Alkenes.Diastereoselective C-H Bond Amination for Disubstituted Pyrrolidines.Copper-Catalyzed Alkene Aminoazidation as a Rapid Entry to 1,2-Diamines and Installation of an Azide Reporter onto Azahetereocycles.Enantiodivergent Synthesis of (+)- and (-)-Pyrrolidine 197B: Synthesis of trans-2,5-Disubstituted Pyrrolidines by Intramolecular Hydroamination.Iterative direct C(sp3)-H functionalization of amines: diastereoselective divergent syntheses of α,α'-disubstituted alicyclic amines.Copper-Catalyzed Oxy-Alkenylation of Homoallylic Alcohols to Generate Functional syn-1,3-Diol Derivatives.Copper-catalyzed aminoalkynylation of alkenes with hypervalent iodine reagents.Intermolecular Olefin Functionalisation Involving Aryl Radicals Generated from Arenediazonium Salts
P2860
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P2860
Pyrrolidine and piperidine formation via copper(II) carboxylate-promoted intramolecular carboamination of unactivated olefins: diastereoselectivity and mechanism
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
2007年论文
@zh
2007年论文
@zh-cn
name
Pyrrolidine and piperidine for ...... tereoselectivity and mechanism
@en
type
label
Pyrrolidine and piperidine for ...... tereoselectivity and mechanism
@en
prefLabel
Pyrrolidine and piperidine for ...... tereoselectivity and mechanism
@en
P2093
P2860
P356
P1476
Pyrrolidine and piperidine for ...... tereoselectivity and mechanism
@en
P2093
Dhanalakshmi Kasi
Eric S Sherman
Peter H Fuller
Sherry R Chemler
P2860
P304
P356
10.1021/JO070321U
P407
P577
2007-04-12T00:00:00Z