Enantioselective synthesis of cyclic carbamimidates via a three-component reaction of imines, terminal alkynes, and p-toluenesulfonylisocyanate using a monophosphine gold(I) catalyst().
about
Development of catalysts and ligands for enantioselective gold catalysisChiral (acyclic diaminocarbene)gold(I)-catalyzed dynamic kinetic asymmetric transformation of propargyl estersCationic dirhodium carboxylate-catalyzed synthesis of dihydropyrimidones from propargyl ureas.Chirality transfer and memory of chirality in gold-catalyzed reactions.Intriguing mechanistic labyrinths in gold(I) catalysis.Silver and gold-catalyzed multicomponent reactionsWhen gold meets chiral Brønsted acid catalysts: extending the boundaries of enantioselective gold catalysis.Chiral Brønsted acid from a cationic gold(I) complex: catalytic enantioselective protonation of silyl enol ethers of ketones.Gold-Catalyzed Enantioselective Annulations.Recent advances in reactions of aryl sulfonyl isocyanates.Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.Synthesis of densely functionalised 5-halogen-1,3-oxazin-2-ones by halogen-mediated regioselective cyclisation of N-Cbz-protected propargylic amines: a combined experimental and theoretical study.Organocatalytic asymmetric synthesis of propargylamines with two adjacent stereocenters: mannich-type reactions of in situ generated C-alkynyl imines with β-keto esters.Gold-catalyzed reactions of enynals/enynones with norbornenes: generation and trapping of cyclic o-quinodimethanes (o-QDMs).One pot conversion of benzophenone imine into the relevant 2-aza-allenium.A new type of chiral sulfinamide monophosphine ligands: stereodivergent synthesis and application in enantioselective gold(I)-catalyzed cycloaddition reactions.Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia.Switchable [3+2] and [4+2] Heteroannulation of Primary Propargylamines with Isonitriles to Imidazoles and 1,6-Dihydropyrimidines: Catalyst Loading Enabled Reaction Divergence.Anion-induced enantioselective cyclization of diynamides to pyrrolidines catalyzed by cationic gold complexes.An asymmetric alkynylation/hydrothiolation cascade: an enantioselective synthesis of thiazolidine-2-imines from imines, acetylenes and isothiocyanates.Unexpected regio- and chemoselectivity of cationic gold-catalyzed cycloisomerizations of propargylureas: access to tetrasubstituted 3,4-dihydropyrimidin-2(1H)-ones.Gold-catalyzed tandem reactions of amide-aldehyde-alkyne coupling and cyclization-synthesis of 2,4,5-trisubstituted oxazoles.Cationic Gold- and Silver-Catalyzed Cycloisomerizations of Propargylic Ureas: A Selective Entry to Oxazolidin-2-imines and Imidazolidin-2-ones
P2860
Q34384951-684DE791-FE11-4CB1-86DE-754615B439F9Q36832851-B77A0ABA-86AF-48E9-B23C-7E2609590548Q36950576-A3687763-14C0-4824-B231-B4EFAF25DF38Q38016801-8CBCB61C-D23F-4450-BF17-FE491323DC91Q38157453-782311BC-D3AB-40EF-AB17-A8A7F335F513Q38194137-5E14D6D9-8041-4264-9D9E-9A3B083AD45AQ38245257-8E8C70CF-E4EA-4973-BF73-9966DBE521F7Q38258517-2D70E5CF-758A-49EF-B4FD-2DD531A4CE85Q38977009-25ECCD4C-15A1-4FCD-8190-B5B5C07C452CQ39106048-72B85111-2734-4E26-8845-999F8DF16168Q41962217-F4DF65C5-3C46-4CE4-B467-1E1DB34F1E34Q45911225-38CF1AD4-8664-4582-B6AC-8194A7C27E67Q46141038-484F5A36-07A2-4626-AA3D-22BC6C12C774Q46173904-3BE0A48C-6E3A-4FEC-A749-C56CC4E6767DQ46448247-1DA965A4-8C9D-400D-BE87-6EA8D4652863Q50459109-72269FC0-C555-4B1C-9C1C-6DC2D030A0FDQ50887786-1B2C3A8C-4A59-4F1A-BC3C-F7BA787A74E0Q51346708-B6676AFC-C040-41F8-8902-16E1F41F8BFDQ52886591-2C3A9A9D-C8E4-4316-8564-9A6C031E3967Q53587876-06B46770-E560-48E1-A3B4-63AD3D7EF84FQ53804493-F37D2CEA-DE82-4974-8896-69CC27FBD93FQ55214851-4C0DF6B7-8695-4E8A-97DA-51036686B665Q57551662-20690F34-2A79-4096-B7B9-F25399DFB8AA
P2860
Enantioselective synthesis of cyclic carbamimidates via a three-component reaction of imines, terminal alkynes, and p-toluenesulfonylisocyanate using a monophosphine gold(I) catalyst().
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Enantioselective synthesis of ...... ophosphine gold(I) catalyst().
@en
type
label
Enantioselective synthesis of ...... ophosphine gold(I) catalyst().
@en
prefLabel
Enantioselective synthesis of ...... ophosphine gold(I) catalyst().
@en
P2860
P356
P1433
P1476
Enantioselective synthesis of ...... ophosphine gold(I) catalyst().
@en
P2093
Matthew J Campbell
P2860
P304
P356
10.1039/C1SC00160D
P577
2011-05-12T00:00:00Z