Radical SAM catalysis via an organometallic intermediate with an Fe-[5'-C]-deoxyadenosyl bond.
about
Substrate-Dependent Cleavage Site Selection by Unconventional Radical S-Adenosylmethionine Enzymes in Diphthamide Biosynthesis.Organometallic Complex Formed by an Unconventional Radical S-Adenosylmethionine Enzyme.Monovalent Cation Activation of the Radical SAM Enzyme Pyruvate Formate-Lyase Activating Enzyme.ENDOR characterization of an iron-alkene complex provides insight into a corresponding organometallic intermediate of nitrogenase.The radical-SAM enzyme Viperin catalyzes reductive addition of a 5'-deoxyadenosyl radical to UDP-glucose in vitro.Direct observation of a deoxyadenosyl radical in an active enzyme environment.Expanding Radical SAM Chemistry by Using Radical Addition Reactions and SAM Analogues.Radical Breakthroughs in Natural Product and Cofactor Biosynthesis.C-C bond forming radical SAM enzymes involved in the construction of carbon skeletons of cofactors and natural products.Organometallic and radical intermediates reveal mechanism of diphthamide biosynthesis.Substrate specificity of radical S-adenosyl-l-methionine dehydratase AprD4 and its partner reductase AprD3 in the C3'-deoxygenation of aminoglycoside antibiotics.
P2860
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P2860
Radical SAM catalysis via an organometallic intermediate with an Fe-[5'-C]-deoxyadenosyl bond.
description
2016 nî lūn-bûn
@nan
2016年の論文
@ja
2016年学术文章
@wuu
2016年学术文章
@zh-cn
2016年学术文章
@zh-hans
2016年学术文章
@zh-my
2016年学术文章
@zh-sg
2016年學術文章
@yue
2016年學術文章
@zh
2016年學術文章
@zh-hant
name
Radical SAM catalysis via an o ...... Fe-[5'-C]-deoxyadenosyl bond.
@en
Radical SAM catalysis via an o ...... Fe-[5'-C]-deoxyadenosyl bond.
@nl
type
label
Radical SAM catalysis via an o ...... Fe-[5'-C]-deoxyadenosyl bond.
@en
Radical SAM catalysis via an o ...... Fe-[5'-C]-deoxyadenosyl bond.
@nl
prefLabel
Radical SAM catalysis via an o ...... Fe-[5'-C]-deoxyadenosyl bond.
@en
Radical SAM catalysis via an o ...... Fe-[5'-C]-deoxyadenosyl bond.
@nl
P2093
P2860
P356
P1433
P1476
Radical SAM catalysis via an o ...... Fe-[5'-C]-deoxyadenosyl bond.
@en
P2093
Amy R Marts
Brian M Hoffman
Joan B Broderick
Kaitlin S Duschene
Krista Shisler
Rachel U Hutcheson
William E Broderick
P2860
P304
P356
10.1126/SCIENCE.AAF5327
P407
P577
2016-05-12T00:00:00Z