Catalytic reduction of dioxygen to water with a monomeric manganese complex at room temperature.
about
Preparation and Structural Properties of In(III)-H Complexes.Spectroscopic characterization and reactivity studies of a mononuclear nonheme Mn(III)-hydroperoxo complex.Geometric and electronic structure of a peroxomanganese(III) complex supported by a scorpionate ligand.Reaction landscape of a pentadentate N5-ligated Mn(II) complex with O2˙- and H2O2 includes conversion of a peroxomanganese(III) adduct to a bis(μ-oxo)dimanganese(III,IV) species.Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water.Synthesis, structure, and physical properties for a series of trigonal bipyramidal M(II)-Cl complexes with intramolecular hydrogen bondsInsights into metalloenzyme microenvironments: biomimetic metal complexes with a functional second coordination sphere.Peroxomanganese complexes as an aid to understanding redox-active manganese enzymes.Structural and spectroscopic characterization of metastable thiolate-ligated manganese(III)-alkylperoxo species.Proton-Coupled Electron Transfer in Organic Synthesis: Fundamentals, Applications, and Opportunities.Oxygen activation by mononuclear Mn, Co, and Ni centers in biology and synthetic complexes.Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective.Isolation and characterization of a dihydroxo-bridged iron(III,III)(μ-OH)2 diamond core derived from dioxygen.Preparation and structures of dinuclear complexes containing M(II)-OH centers.Hydrogen-Bonding Interactions Trigger a Spin-Flip in Iron(III) Porphyrin ComplexesTetranuclear Manganese Models of the OEC Displaying Hydrogen Bonding Interactions: Application to Electrocatalytic Water Oxidation to Hydrogen Peroxide.Characterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes.Molecular designs for controlling the local environments around metal ionsCorrelation between structural, spectroscopic, and reactivity properties within a series of structurally analogous metastable manganese(III)-alkylperoxo complexesHydrogen-bonding interactions trigger a spin-flip in iron(III) porphyrin complexes.The effects of redox-inactive metal ions on the activation of dioxygen: isolation and characterization of a heterobimetallic complex containing a Mn(III)-(μ-OH)-Ca(II) core.Characterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species.Theoretical studies on concerted versus two steps hydrogen atom transfer reaction by non-heme Mn(IV/III)=O complexes: how important is the oxo ligand basicity in the C-H activation step?Modulating the Primary and Secondary Coordination Spheres within a Series of CoII-OH Complexes.Synthesis and characterization of M(II) (M = Mn, Fe and Co) azafulvene complexes and their X3(-) derivatives.Exploring Mn-O bonding in the context of an electronically flexible secondary coordination sphere: synthesis of a Mn(III)-oxo.Oxygen Evolution Catalyzed by a Mononuclear Ruthenium Complex Bearing Pendant SO3(-) Groups.A structurally-characterized peroxomanganese(iv) porphyrin from reversible O2 binding within a metal-organic framework.Remarkable Anion-Dependent Spin-State Switching in Diiron(III) μ-Hydroxo Bisporphyrins: What Role do Counterions Play?Oxygen activation and catalytic aerobic oxidation by Mo(iv)/(vi) complexes with functionalized iminophenolate ligands.A bioinspired iron catalyst for nitrate and perchlorate reduction.O2 Activation and Double C-H Oxidation by a Mononuclear Manganese(II) Complex.Incorporation of redox-inactive cations promotes iron catalyzed aerobic C-H oxidation at mild potentials.Redox flexibility of iron complexes supported by sulfur-based tris(o-methylenethiophenolato)amine relative to its tripodal oxygen-based congenerProton-Coupled Electron Transfer Reactions Catalysed by 3 d Metal Complexes
P2860
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P2860
Catalytic reduction of dioxygen to water with a monomeric manganese complex at room temperature.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Catalytic reduction of dioxyge ...... e complex at room temperature.
@en
Catalytic reduction of dioxyge ...... e complex at room temperature.
@nl
type
label
Catalytic reduction of dioxyge ...... e complex at room temperature.
@en
Catalytic reduction of dioxyge ...... e complex at room temperature.
@nl
prefLabel
Catalytic reduction of dioxyge ...... e complex at room temperature.
@en
Catalytic reduction of dioxyge ...... e complex at room temperature.
@nl
P2093
P2860
P356
P1476
Catalytic reduction of dioxyge ...... e complex at room temperature.
@en
P2093
A S Borovik
Arnold L Rheingold
Curtis Moore
John Greaves
Ryan L Shook
Sonja M Peterson
P2860
P304
P356
10.1021/JA106564A
P407
P577
2011-03-22T00:00:00Z