about
Transition metal catalyzed borylation of functional π-systemsPorphyrin synthesis in water provides new expanded porphyrins with direct bipyrrole linkages: isolation and characterization of two heptaphyrins.Stacked antiaromatic porphyrins.Synthesis and Functionalization of Porphyrins through Organometallic Methodologies.Highly-conducting molecular circuits based on antiaromaticity.Nitrogen-embedded buckybowl and its assembly with C60.Directly Pd(II)-bridged porphyrin belts with remarkable curvatures.Large porphyrin squares from the self-assembly of meso-triazole-appended L-shaped meso-meso-linked Zn(II)-triporphyrins: synthesis and efficient energy transfer.Excess polarizability reveals exciton localization/delocalization controlled by linking positions on porphyrin rings in butadiyne-bridged porphyrin dimers.Triethylborane-induced bromine atom-transfer radical addition in aqueous media: study of the solvent effect on radical addition reactions.Conversion of acid chloride into homoallylic alcohol via allylic C [bond] H bond activation of alkene with a zirconocene complex.Facile synthesis of ketones from 1,1-disilylethenes via oxidation of gem-disilylalkanes.Reaction of alpha,alpha-dibromo oxime ethers with Grignard reagents: alkylative annulation providing a pyrimidine core.Unambiguous identification of Möbius aromaticity for meso-aryl-substituted [28]hexaphyrins(1.1.1.1.1.1).Highly diastereoselective addition of silyldihalomethyllithiums to chiral alkyl esters.Et3B-induced radical addition of N,N-dichlorosulfonamide to alkenes and pyrrolidine formation via radical annulation.Selective synthesis of a [32]octaphyrin(1.0.1.0.1.0.1.0) bis(palladium) complex by a metal-templated strategy.Synthesis of highly distorted π-extended [2.2]metacyclophanes by intermolecular double oxidative coupling.Carbolithiation of meso-aryl-substituted 5,15-diazaporphyrin selectively provides 3-alkylated diazachlorins.Triethylborane-mediated hydrogallation and hydroindation: novel access to organogalliums and organoindiums.Reaction of silyldihalomethyllithiums with nitriles: formation of alpha-keto acylsilanes via azirines and 1,3-rearrangement of silyl group from C to N.Post-modification of meso-meso-linked porphyrin arrays by iridium and rhodium catalyses for tuning of energy gap.Metathesis-like splitting reactions of metallated [36]octaphyrins(1.1.1.1.1.1.1.1): experimental and computational investigations.Unusual interchromophoric interactions in beta,beta' directly and doubly linked corrole dimers: prohibited electronic communication and abnormal singlet ground states.Conformational changes of meso-aryl substituted expanded porphyrins upon protonation: effects on photophysical properties and aromaticity.Synthesis of a pyridine-fused porphyrinoid: oxopyridochlorin.Zwitterionic corroles: regioselective nucleophilic pyridination of a doubly linked biscorrole.Synthesis of directly and doubly linked dioxoisobacteriochlorin dimers.Pt(II)- and Pt(IV)-bridged cofacial diporphyrins via carbon-transition metal sigma-bonds.Enhancing the low-energy absorption band and charge mobility of antiaromatic NiII norcorroles by their substituent effects.Functionalization of hexa-peri-hexabenzocoronenes: investigation of the substituent effects on a superbenzene.A new method for the synthesis of acyltitanium complexes and their application to copper-mediated acylmetallation of carbon-carbon multiple bonds in aqueous media.Efficient rhodium-catalyzed installation of unsaturated ester functions onto porphyrins: site-specific Heck-type addition versus conjugate addition.Synthesis of corrole derivatives through regioselective Ir-catalyzed direct borylation.meso-Aryl substituted rubyrin and its higher homologues: structural characterization and chemical properties.Nickel (II) pyrrocorphin: Enhanced binding ability in a highly reduced porphyrin complex.Structures of the Heme Acquisition Protein HasA with Iron(III)-5,15-Diphenylporphyrin and Derivatives Thereof as an Artificial Prosthetic Group.Acid-Mediated Migration of Bromide in an Antiaromatic Porphyrinoid: Preparation of Two Regioisomeric Ni(II) Bromonorcorroles.Selective α-arylation of α,β-unsaturated imides mediated by a visible light photoredox catalyst.Shaping Antiaromatic π-Systems by Metalation: Synthesis of a Bowl-Shaped Antiaromatic Palladium Norcorrole.
P50
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P50
description
researcher
@en
wetenschapper
@nl
հետազոտող
@hy
name
Hiroshi Shinokubo
@ast
Hiroshi Shinokubo
@en
Hiroshi Shinokubo
@es
Hiroshi Shinokubo
@nl
Hiroshi Shinokubo
@sl
type
label
Hiroshi Shinokubo
@ast
Hiroshi Shinokubo
@en
Hiroshi Shinokubo
@es
Hiroshi Shinokubo
@nl
Hiroshi Shinokubo
@sl
prefLabel
Hiroshi Shinokubo
@ast
Hiroshi Shinokubo
@en
Hiroshi Shinokubo
@es
Hiroshi Shinokubo
@nl
Hiroshi Shinokubo
@sl
P1053
C-5080-2009
P106
P31
P3829
P496
0000-0002-5321-2205