Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
about
Radicals: Reactive Intermediates with Translational PotentialInnate and Guided C–H Functionalization LogicMetal-free C-H alkylation of heteroarenes with alkyltrifluoroborates: a general protocol for 1°, 2° and 3° alkylation.Profound methyl effects in drug discovery and a call for new C-H methylation reactions.Late-stage functionalization of biologically active heterocycles through photoredox catalysis.Cross-coupling of mesylated phenol derivatives with potassium alkoxymethyltrifluoroborates.Expanded substrate scope and improved reactivity of ether-forming cross-coupling reactions of organotrifluoroborates and acetals.Synthesis and cross-coupling reactions of imidomethyltrifluoroborates with aryl chlorides.Organocatalyzed, Photoredox Heteroarylation of 2-Trifluoroboratochromanones via C-H Functionalization.Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers.Direct Assembly of Prenylated Heteroarenes through a Cascade Minisci Reaction/Dehydration Sequence.Copper-catalyzed oxidative Heck reactions between alkyltrifluoroborates and vinyl arenes.Synthetic applications of arylboronic acid via an aryl radical transfer pathway.Metal-free chlorodeboronation of organotrifluoroborates.Practical radical cyclizations with arylboronic acids and trifluoroborates.Combination of organotrifluoroborates with photoredox catalysis marking a new phase in organic radical chemistry.Hypervalent iodine reagents enable chemoselective deboronative/decarboxylative alkenylation by photoredox catalysis.Boron chemistry in a new light.Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations.Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis.Mild palladium-catalyzed C-H alkylation using potassium alkyltrifluoroborates in combination with MnF3Copper-mediated radical trifluoromethylation of unsaturated potassium organotrifluoroborates.Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones.Synthesis and applications of α-trifluoromethylated alkylboron compoundsPhotoredox-mediated Minisci C-H alkylation of N-heteroarenes using boronic acids and hypervalent iodineRadical-based regioselective C-H functionalization of electron-deficient heteroarenes: scope, tunability, and predictability.Synthesis and minisci reactions of organotrifluoroborato building blocks.Practical and innate carbon-hydrogen functionalization of heterocycles.Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp(3)-sp(2) Cross-Coupling.An efficient palladium-catalyzed C-H alkoxylation of unactivated methylene and methyl groups with cyclic hypervalent iodine (i(3+) ) oxidants.Simple sulfinate synthesis enables C-H trifluoromethylcyclopropanation.Alcohols as alkylating agents in heteroarene C-H functionalization.Direct α-arylation of ethers through the combination of photoredox-mediated C-H functionalization and the Minisci reaction.The photochemical alkylation and reduction of heteroarenes.Stereoselective C-H borylations of cyclopropanes and cyclobutanes with silica-supported monophosphane-Ir catalysts.Late-Stage C-H Alkylation of Heterocycles and 1,4-Quinones via Oxidative Homolysis of 1,4-Dihydropyridines.Visible-Light-Initiated Manganese Catalysis for C-H Alkylation of Heteroarenes: Applications and Mechanistic Studies.Versatile cross-dehydrogenative coupling of heteroaromatics and hydrogen donors via decatungstate photocatalysis.The acid promoted Petasis reaction of organotrifluoroborates with imines and enamines.Direct construction of 2-alkylbenzo-1,3-azoles via C-H activation of alkanes for C-C and C-X (X = O, S) bond formation.
P2860
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P2860
Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
@en
Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
@nl
type
label
Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
@en
Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
@nl
prefLabel
Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
@en
Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
@nl
P2860
P356
P1433
P1476
Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
@en
P2093
Valerie A Braz
Virginie Colombel
P2860
P304
P356
10.1021/OL2003572
P407
P577
2011-03-10T00:00:00Z