Visible light-promoted metal-free C-H activation: diarylketone-catalyzed selective benzylic mono- and difluorination.
about
A convenient photocatalytic fluorination of unactivated C-H bonds.Hydrogen abstraction by photoexcited benzophenone: consequences for DNA photosensitization.A Visible-Light-Mediated Radical Smiles Rearrangement and its Application to the Synthesis of a Difluoro-Substituted Spirocyclic ORL-1 AntagonistBeyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation.Utilization of methylarenes as versatile building blocks in organic synthesis.Photocatalytic fluoroalkylation reactions of organic compounds.Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones.The past, present, and future of the Yang reaction.Photocatalysis in organic and polymer synthesis.Functionalization of C-H Bonds by Photoredox Catalysis.Photochemical proton-coupled C-H activation: an example using aliphatic fluorination.Vanadium-Catalyzed C(sp(3))-H Fluorination Reactions.A visible-light-promoted radical reaction system for azidation and halogenation of tertiary aliphatic C-H bondsIron(II)-Catalyzed Intermolecular Aminofluorination of Unfunctionalized Olefins Using Fluoride Ion.Photochemical Nickel-Catalyzed C-H Arylation: Synthetic Scope and Mechanistic Investigations.Mild silver-mediated geminal difluorination of styrenes using an air- and moisture-stable fluoroiodane reagent.The Uranyl Cation as a Visible-Light Photocatalyst for C(sp(3) )-H Fluorination.Palladium-catalyzed difluoromethylation of heteroaryl chlorides, bromides and iodides.A simple method for the electrophilic cyanation of secondary aminesPd-catalyzed α-arylation of trimethylsilyl enolates of α,α-difluoroacetamides.Photoredox ketone catalysis for the direct C-H imidation and acyloxylation of arenes.Visible light-promoted metal-free sp(3)-C-H fluorination.Enantioselective Palladium-Catalyzed Oxidative β,β-Fluoroarylation of α,β-Unsaturated Carbonyl Derivatives.Ketones as directing groups in photocatalytic sp3 C-H fluorination.Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF2 CH3 ).Monofluoromethyl-Substituted Sulfonium Ylides: Electrophilic Monofluoromethylating Reagents with Broad Substrate Scopes.Copper-Catalyzed Bromination of C(sp3 )-H Bonds Distal to Functional Groups.Intermolecular Palladium-Catalyzed Oxidative Fluorocarbonylation of Unactivated Alkenes: Efficient Access to β-Fluorocarboxylic Esters.Denitrogenative hydrofluorination of aromatic aldehyde hydrazones using (difluoroiodo)toluene.Radical fluorination reactions by thermal and photoinduced methods.Unstrained C-C bond activation and directed fluorination through photocatalytically-generated radical cations.Light-promoted metal-free cross dehydrogenative couplings on ethers mediated by NFSI: reactivity and mechanistic studies.Natural products as inspiration for the development of new synthetic methods.Visible-light-promoted selective C-H amination of heteroarenes with heteroaromatic amines under metal-free conditions.Catalytic Asymmetric Synthesis of Fluoroalkyl-Containing Compounds by Three-Component Photoredox Chemistry.Synthesis of stilbene derivatives via visible-light-induced cross-coupling of aryl diazonium salts with nitroalkenes using -NO2 as a leaving group.Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes.Selective fluorination of alkyl C-H bonds via photocatalysis.Photo-induced Substitutive Introduction of the Aldoxime Functional Group to Carbon Chains: A Formal Formylation of Non-Acidic C(sp(3) )-H Bonds.Visible-light-initiated difluoromethylation of arene diazonium tetrafluoroborates.
P2860
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P2860
Visible light-promoted metal-free C-H activation: diarylketone-catalyzed selective benzylic mono- and difluorination.
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年論文
@yue
2013年論文
@zh-hant
2013年論文
@zh-hk
2013年論文
@zh-mo
2013年論文
@zh-tw
2013年论文
@wuu
2013年论文
@zh
2013年论文
@zh-cn
name
Visible light-promoted metal-f ...... ylic mono- and difluorination.
@en
Visible light-promoted metal-f ...... ylic mono- and difluorination.
@nl
type
label
Visible light-promoted metal-f ...... ylic mono- and difluorination.
@en
Visible light-promoted metal-f ...... ylic mono- and difluorination.
@nl
prefLabel
Visible light-promoted metal-f ...... ylic mono- and difluorination.
@en
Visible light-promoted metal-f ...... ylic mono- and difluorination.
@nl
P2860
P356
P1476
Visible light-promoted metal-f ...... ylic mono- and difluorination.
@en
P2093
P2860
P304
17494-17500
P356
10.1021/JA410815U
P407
P50
P577
2013-11-12T00:00:00Z