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Computing Free Energy Landscapes: Application to Ni-based Electrocatalysts with Pendant Amines for H2Production and OxidationWater-assisted proton delivery and removal in bio-inspired hydrogen production catalysts.Carbon-to-metal hydrogen atom transfer: direct observation using time-resolved infrared spectroscopy.Moving protons with pendant amines: proton mobility in a nickel catalyst for oxidation of hydrogen.Acidic ionic liquid/water solution as both medium and proton source for electrocatalytic H2 evolution by [Ni(P2N2)2]2+ complexes.Toward molecular catalysts by computer.Surface Immobilization of Molecular Electrocatalysts for Energy Conversion.Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes.Proton delivery and removal in [Ni(P(R)2N(R')2)2]2+ hydrogen production and oxidation catalysts.Evaluation of the Role of Water in the H2 Bond Formation by Ni(II)-Based Electrocatalysts.Hydrogen oxidation catalysis by a nickel diphosphine complex with pendant tert-butyl amines.Thermochemical and mechanistic studies of electrocatalytic hydrogen production by cobalt complexes containing pendant amines.Isolation of two agostic isomers of an organometallic cation: different structures and colors.Direct determination of equilibrium potentials for hydrogen oxidation/production by open circuit potential measurements in acetonitrile.Rapid, reversible heterolytic cleavage of bound H2.Heterolytic cleavage of hydrogen by an iron hydrogenase model: an Fe-H⋅⋅⋅H-N dihydrogen bond characterized by neutron diffraction.The electrode as organolithium reagent: catalyst-free covalent attachment of electrochemically active species to an azide-terminated glassy carbon electrode surface.A hydrogen-evolving Ni(P2N2)2 electrocatalyst covalently attached to a glassy carbon electrode: preparation, characterization, and catalysis. comparisons with the homogeneous analogue.Synthesis of ruthenium carbonyl complexes with phosphine or substituted Cp ligands, and their activity in the catalytic deoxygenation of 1,2-propanediol.Mechanistic insights into catalytic h(2) oxidation by ni complexes containing a diphosphine ligand with a positioned amine base.Layer-by-Layer Molecular Assemblies for Dye-Sensitized Photoelectrosynthesis Cells Prepared by Atomic Layer Deposition.Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production.Experimental and Computational Mechanistic Studies Guiding the Rational Design of Molecular Electrocatalysts for Production and Oxidation of Hydrogen.Molecular electrocatalysts for oxidation of hydrogen using earth-abundant metals: shoving protons around with proton relays.Increasing the rate of hydrogen oxidation without increasing the overpotential: a bio-inspired iron molecular electrocatalyst with an outer coordination sphere proton relay.Modulating Hole Transport in Multilayered Photocathodes with Derivatized p-Type Nickel Oxide and Molecular Assemblies for Solar-Driven Water Splitting.Catalytic N2 Reduction to Silylamines and Thermodynamics of N2 Binding at Square Planar Fe.Reversible Heterolytic Cleavage of the H-H Bond by Molybdenum Complexes: Controlling the Dynamics of Exchange Between Proton and Hydride.Ammonia Oxidation by Abstraction of Three Hydrogen Atoms from a Mo-NH3 Complex.6-(alkylamino)-9-alkylpurines. A new class of potential antipsychotic agents.Catalytic Silylation of N2 and Synthesis of NH3 and N2H4 by Net Hydrogen Atom Transfer Reactions Using a Chromium P4 Macrocycle.Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni(II).Controlling Proton Delivery through Catalyst Structural Dynamics.Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic.Synthesis, characterization, and reactivity of Fe complexes containing cyclic diazadiphosphine ligands: the role of the pendant base in heterolytic cleavage of H2.Thermodynamic Hydricity of Transition Metal Hydrides.Kinetic and mechanistic studies of carbon-to-metal hydrogen atom transfer involving Os-centered radicals: evidence for tunneling.An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen.The role of pendant amines in the breaking and forming of molecular hydrogen catalyzed by nickel complexes.Studies of a series of [Ni(P(R)2N(Ph)2)2(CH3CN)]2+ complexes as electrocatalysts for H2 production: substituent variation at the phosphorus atom of the P2N2 ligand.
P50
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P50
description
Amerikaans onderzoeker
@nl
researcher
@en
հետազոտող
@hy
name
R. Morris Bullock
@ast
R. Morris Bullock
@en
R. Morris Bullock
@es
R. Morris Bullock
@nl
R. Morris Bullock
@sl
type
label
R. Morris Bullock
@ast
R. Morris Bullock
@en
R. Morris Bullock
@es
R. Morris Bullock
@nl
R. Morris Bullock
@sl
prefLabel
R. Morris Bullock
@ast
R. Morris Bullock
@en
R. Morris Bullock
@es
R. Morris Bullock
@nl
R. Morris Bullock
@sl
P1053
L-6802-2016
P106
P31
P3829
P496
0000-0001-6306-4851